JEE (Advanced) 2021 Paper 1

SECTION 1
 This section contains FOUR (04) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct
answer.
 For each question, choose the option corresponding to the correct answer.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : −1 In all other cases.

Q.1 The major product formed in the following reaction is

NaNH2

Na
liq. NH3

(A)

(B)

(C)

(D)

Q.2 Among the following, the conformation that corresponds to the most stable
conformation of meso-butane-2,3-diol is

(A) (B)
OH OH
H Me H OH

Me H H Me
OH Me

(C) (D)
OH OH
Me OH H OH

H Me Me H
H Me

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JEE (Advanced) 2021 Paper 1

Q.3 For the given close packed structure of a salt made of cation X and anion Y shown
below (ions of only one face are shown for clarity), the packing fraction is
packing efficiency
approximately (packing fraction = )
100

(A) 0.74 (B) 0.63 (C) 0.52 (D) 0.48

Q.4 The calculated spin only magnetic moments of [Cr(NH3)6]3+ and [CuF6]3– in BM,
respectively, are

(Atomic numbers of Cr and Cu are 24 and 29, respectively)

(A) 3.87 and 2.84 (B) 4.90 and 1.73

(C) 3.87 and 1.73 (D) 4.90 and 2.84

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SECTION 2

 This section contains THREE (03) question stems.

 There are TWO (02) questions corresponding to each question stem.
 The answer to each question is a NUMERICAL VALUE.
 For each question, enter the correct numerical value corresponding to the answer in the designated place
using the mouse and the on-screen virtual numeric keypad.
 If the numerical value has more than two decimal places, truncate/round-off the value to TWO decimal
places.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +2 If ONLY the correct numerical value is entered at the designated place;
Zero Marks : 0 In all other cases.

Question Stem for Question Nos. 5 and 6

Question Stem

For the following reaction scheme, percentage yields are given along the arrow:

red hot
NaNH2 iron tube
H2O P MeI 873 K
Mg2C3 Q R
(4.0 g) 75% 40% (x g)

Hg2+/H+
100%
333K
Ba(OH)2 NaOCl
S T U (decolourises
heat 80% (y g) Baeyer's reagent)
80%
x g and y g are mass of R and U, respectively.
(Use: Molar mass (in g mol–1) of H, C and O as 1, 12 and 16, respectively)

Q.5 The value of x is ___.

Q.6 The value of y is ___.

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Question Stem for Question Nos. 7 and 8

Question Stem

𝑝𝐙 104
For the reaction, 𝐗(𝑠) ⇌ 𝐘(𝑠) + 𝐙(𝑔), the plot of ln versus is given below (in
𝑝o 𝑇
solid line), where 𝑝𝐙 is the pressure (in bar) of the gas Z at temperature T and
𝑝o = 1 bar.

d (ln 𝐾) ∆𝐻 o 𝑝𝑧
(Given, 1 = − , where the equilibrium constant, 𝐾 = and
d( ) 𝑅 𝑝o
𝑇
the gas constant, R = 8.314 J K–1 mol–1)

Q.7 The value of standard enthalpy, ∆𝐻 o (in kJ mol–1) for the given reaction is ___.

Q.8 The value of ∆𝑆 o (in J K–1 mol–1) for the given reaction, at 1000 K is ___.

Question Stem for Question Nos. 9 and 10

Question Stem

The boiling point of water in a 0.1 molal silver nitrate solution (solution A) is x C.
To this solution A, an equal volume of 0.1 molal aqueous barium chloride solution
is added to make a new solution B. The difference in the boiling points of water in
the two solutions A and B is y × 102 C.

(Assume: Densities of the solutions A and B are the same as that of water and the
soluble salts dissociate completely.
Use: Molal elevation constant (Ebullioscopic Constant), 𝐾𝑏 = 0.5 K kg mol1;
Boiling point of pure water as 100 C.)

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Q.9 The value of x is ___.

Q.10 The value of |y| is ___.

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JEE (Advanced) 2021 Paper 1

SECTION 3

 This section contains SIX (06) questions.

 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four
option(s) is (are) correct answer(s).
 For each question, choose the option(s) corresponding to (all) the correct answer(s).
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is(are) chosen;
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen, both of
which are correct;
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a
correct option;
Zero Marks : 0 If unanswered;
Negative Marks : −2 In all other cases.
 For example, in a question, if (A), (B) and (D) are the ONLY three options corresponding to correct
answers, then
choosing ONLY (A), (B) and (D) will get +4 marks;
choosing ONLY (A) and (B) will get +2 marks;
choosing ONLY (A) and (D) will get +2marks;
choosing ONLY (B) and (D) will get +2 marks;
choosing ONLY (A) will get +1 mark;
choosing ONLY (B) will get +1 mark;
choosing ONLY (D) will get +1 mark;
choosing no option(s) (i.e. the question is unanswered) will get 0 marks and
choosing any other option(s) will get −2 marks.

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Q.11 Given:
CHO
H OH
HO H HNO3
P
H OH
[]D = +52.7
H OH
CH2OH
D-Glucose

The compound(s), which on reaction with HNO3 will give the product having degree
of rotation, []D = −52.7 is(are)

(A) (B)
CHO CHO
HO H HO H
HO H HO H
H OH H OH
H OH HO H
CH2OH CH2OH

(C) (D)
CHO CHO
HO H H OH
H OH H OH
HO H HO H
HO H H OH
CH2OH CH2OH

Q.12 The reaction of Q with PhSNa yields an organic compound (major product) that
gives positive Carius test on treatment with Na2O2 followed by addition of BaCl2.
The correct option(s) for Q is(are)

(A) (B)
O2N
O2N F
I
NO2
O2N

(C) (D)
MeS
O2N
Br Cl
MeS
O2N

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JEE (Advanced) 2021 Paper 1

Q.13 The correct statement(s) related to colloids is(are)

(A) The process of precipitating colloidal sol by an electrolyte is called peptization.

(B) Colloidal solution freezes at higher temperature than the true solution at the
same concentration.

(C) Surfactants form micelle above critical micelle concentration (CMC). CMC
depends on temperature.

(D) Micelles are macromolecular colloids.

Q.14 An ideal gas undergoes a reversible isothermal expansion from state I to state II
followed by a reversible adiabatic expansion from state II to state III. The correct
plot(s) representing the changes from state I to state III is(are)

(p: pressure, V: volume, T: temperature, H: enthalpy, S: entropy)

(A) (B)

(C) (D)

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Q.15 The correct statement(s) related to the metal extraction processes is(are)

(A) A mixture of PbS and PbO undergoes self-reduction to produce Pb and SO2.

(B) In the extraction process of copper from copper pyrites, silica is added to produce
copper silicate.

(C) Partial oxidation of sulphide ore of copper by roasting, followed by self-reduction

produces blister copper.

(D) In cyanide process, zinc powder is utilized to precipitate gold from Na[Au(CN)2].

Q.16 A mixture of two salts is used to prepare a solution S, which gives the following
results:

Dilute NaOH(aq) S Dilute HCl(aq)

White (aq solution White
precipitate(s) of the salts) precipitate(s)
only Room temperature Room temperature only

The correct option(s) for the salt mixture is(are)

(A) Pb(NO3)2 and Zn(NO3)2 (B) Pb(NO3)2 and Bi(NO3)3

(C) AgNO3 and Bi(NO3)3 (D) Pb(NO3)2 and Hg(NO3)2

SECTION 4

 This section contains THREE (03) questions.

 The answer to each question is a NON-NEGATIVE INTEGER.
 For each question, enter the correct integer corresponding to the answer using the mouse and the
on-screen virtual numeric keypad in the place designated to enter the answer.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If ONLY the correct integer is entered;
Zero Marks : 0 In all other cases.

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Q.17 The maximum number of possible isomers (including stereoisomers) which may be
formed on mono-bromination of 1-methylcyclohex-1-ene using Br2 and UV light
is ___.

Q.18 In the reaction given below, the total number of atoms having sp2 hybridization in
the major product P is ___.

1. O3 (excess)
then Zn/H2O
P
2. NH2OH (excess)

Q.19 The total number of possible isomers for [Pt(NH3)4Cl2]Br2 is ___.

END OF THE QUESTION PAPER

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