"Revealing the role of orgfanic cations in hybrid halide perovskite CH3NH3PbI3" C. Motta, F. El-Mellouhi, S. Kais, N. Tabet, F. Alharbi and S. Sanvito, Nature Commun., 6, 7026 (2015). è¿å¹´ï¼å¤ªé½é»æ± ã®åéã«ããã¦ææ©-ç¡æ©ãããã¹ã«ã¤ãã¨å¼ã°ããç©è³ªã注ç®ããã¦ããï¼æãåç´ãªçµæã§ã¯AMX3ã¨ãªããã®ç©è³ªã¯ï¼éãã¹ãºãªã©ã®éå±ã¤ãªã³ï¼Mï¼ã6ã¤ã®ããã²ã³ã¤ãªã³ï¼Xï¼ãåãå²ã¿å «é¢ä½ãå½¢æãï¼ãããé ç¹å ±æãã¦ç¡æ°ã«ã¤ãªãããã¨ã§3次å æ§é ãã¤ããï¼ææ©ç©ã®æ£ã¤ãªã³ï¼A+ï¼ãé£ãªã£ãå «é¢ä½ã®ééãåãããããªæ§é ãã¨ã£ã¦ããï¼ ãªããã®ç©è³ªã注ç®ããã¦ããã®ãã¨ããã°ï¼å¤ªé½å ã®é»åã¸ã®å¤æå¹çãé«ãï¼ããã製
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