Poc 2 Questions

UNIT I

 Benzene and its derivatives  Reactions of benzene

2 MARKS

1. Give the structure and general uses of Saccharin.
2. Define aromatic electrophilic substitution reactions.
3. Explain resonance effect.
4. Aromaticity of benzene?
5. What is aromoticity? Why benzene is called as an aromatic compound?
6. Give the structure and general uses of DDT.
7. Give the structure and general uses of Benzene hexachloride (BHC).
8. What are activating and deactivating groups?
9. Give the structure and general uses of Chloramine.
10. Outline the general mechanism of aromatic electrophilic substitution reactions.
5 MARKS
1. Explain the facts supporting kekule structure of Benzene.
2. Explain the Huckel’s rule.
3. Describe the mechanism of Acylation and nitration of benzene.
4. Give the structure and general uses of DDT and BHC.
5. Discuss the theory of reactivity in aromatic rings.
6. Discuss the stability of benzyl radical.
7. Explain the mechanism of halogenation of benzene.
8. Halogens are deactivating group but ortho & para director. Give reasons.
9. Outline the nomenclature steps involved in the naming of aromatic compounds.
10. Add a note on effects of substituents on reactivity of mono substituted benzene compounds
towards electrophilic substitution reaction.
10 MARKS
1. Discuss the reaction and mechanism of nitration, sulphonation, and friedel-craft reaction.
2. Discuss nitration, sulphonation and halogenation of benzene with examples and mechanism.
3. Discuss Friedel Craft’s alkylations with examples and mechanism. Mention any two of its
limitations.
4. Explain Friedel Craft’s reactions with examples and mechanism.

5. Add a note on effects of substituents on reactivity and orientation of mono substituted benzene
compounds towards electrophilic substitution reaction.
UNIT II
 Phenols, Aromatic amines  Effect of substituents on acidity & basicity  Preparation and uses of
few derivatives
2 MARKS
1. Write the structure of ortho- hydroxy benzoic acid.
2. Arrange the order of acid strength: phenol, o-cresol, o- Nitrophenol.
3. Define amines. Give the reason why amines are basic in nature
4. Compare the basicity of any two aromatic amines.
5. Describe any two methods for the preparation of phenol.
6. What is the diazonium reaction?
7. Give the structure of resorcinol.
8. Define phenols. Give its medicinal uses
9. What are aromatic amines and its uses?
5 MARKS
1. Explain the effect of substituents on acidity of benzoic acid.
2. Give the structure and uses of some important phenolic compounds.
3. Write about Kolbe’s reaction
4. Explain the effect of substituents on acidity of phenols.
5. Write the preparation and synthetic utility of diazanium salts.
6. Discuss the basicity of aromatic amines.
7. What is the diazonium reaction? Explain the general reaction?
8. Discuss the orientation effect of i) Hydroxyl group in phenol ii) Nitro group in Benzene
10 MARKS
1. Discuss the synthesis, uses and important reactions of benzoic acid (aromatic acids).
2. Discuss the effect of various substituents on the acidity of phenol with examples.
3. Discuss the effect of substituents on the basicity of aromatic amines and acidity of aromatic acids.
4. Discuss the method of preparation and uses of phenol, cresol and naphthol.
UNIT III
 Fats and Oils  Fatty acids reactions  Analytical constants and its significances
2 MARKS
1. What is saponification value and give its significances.
2. Give the difference between iodine value and acetyl value
3. What is rancidity of oils?
4. Classify fatty acids with examples.
5. What is hydrolysis of fatty acids and its importance
6. Define acid value. Give its significance.
7. Define saponification value. Give its significance.
8. Define iodine value. Give its significance.
9. Define drying, semidrying and non drying of oils.
10. What is hydrogenation of oils? Give examples.
11. Distinguish between fats and oils. Give examples
12. Define saturated and unsaturated fatty acids. Give examples.
13. What is unsaponifiable matter and give its significance.
14. Give the chemical composition of fats, oils & waxs.
15. Mention the analytical constants of fats and oils.
5 MARKS
1. Explain the principle involved in the determination of acid value of oil sample.
2. Discuss the rancidity of oils.
3. Explain hydrogenation and saponification of fatty acids
4. With example explain saponification reaction of fatty acid.
5. Give the principle in involved in the hydrolysis reaction of fatty acid.
6. Add a note on drying of oils.
7. Explain the principle involved in the determination of Iodine value of oil sample.
8. Give the principle involved in the determination of saponification value of oil sample.
9. Explain the chemistry of fats, oils and waxes.
10. Write a note on hardening of oils.
11. Write a note on drying, semidrying & nondrying of oils.
12. Define and give methods of determination & significance of acid value.
13. Define saponification value. Give a method of determination and its significance.
14. Explain hardening of oils & hydrogenation of oils.
10 MARKS
1. Explain the principle & procedure involved in the determination of acid value of oil sample.
2. Discuss a) Acid value b) Ester value c) RM value d) Acetyl value
3. Define iodine value. Give a method of determination and its significance.
4. Discuss any two analytical constants of fats & oils. Give its significance.
UNIT IV
 Polynuclear hydrocarbons  Synthesis, reactions structure and medicinal uses of Naphthalene,

Phenanthrene, Anthracene, Diphenylmethane, Triphenylmethane and their derivatives
2 MARKS
1. What are polynuclear aromatic hydrocarbons?
2. Give the medicinal uses of (a) Anthracene (b) Triphenylmethane
3. Write the structure and medicinal uses of Naphthalene.
4. Write the structure and medicinal uses of Phenanthrene.
5. Write the structure and medicinal uses of Anthracene.
6. Write the structure and medicinal uses of Diphenylmethane
7. Write the structure and medicinal uses of Triphenylmethane.
8. List the sources of polycyclic aromatic hydrocarbons.
9. What are some advantages and disadvantages of polycyclic aromatic hydrocarbons?
5 MARKS
1. Outline the synthesis of Phenathrene
2. Discuss the general reactions of polynuclear aromatic hydrocarbons.
3. Name two derivatives of polynuclear aromatic hydrocarbons and give the synthesis of any one.
4. Add a note on the preparation of Anthracene.
5. Give the method of preparation of triphenylmethane.
10 MARKS
1. Write the synthesis, properties and uses of Diphenyl methane and Phenanthrene.
2. Give the method of preparation, reactions and uses of Naphthalene.
3. What are polynuclear aromatic hydrocarbons? Give the synthesis of any two polynuclear
aromatic hydrocarbons.
4. What are some sources, medicinal uses and disadvantages of polynuclear aromatic hydrocarbons?
UNIT V
 Baeyer’s strain theory,  Coulson and Moffitt’s modification,  Sachse Mohr’s theory  Reactions of
cyclopropane and cyclobutane only.
2 MARKS
1. Define Baeyer’s strain theory
2. What is Sachse Mohr’s theory
3. What are some limitations of baeyer’s strain theory.
4. What is Coulson and moffitt’s modification.
5 MARKS
1. Discuss Bayer’s strain theory with suitable examples.
2. Give the structure, nomenclature and reaction of Cycloalkanes.
3. Write the synthesis and properties of cyclopropane.
4. What are cycloalkanes? Write any three methods of preparation.
5. Discuss with example the Coulson and Moffitt’s modification.
6. Discuss any two general reactions of cycloalkanes.
7. Discuss any one theory of stability of cycloalkane.
10 MARKS
1. Distinguish between cyclopropane and cyclobutane give the method of synthesis and reactions of
any one.
2. Discuss Sachse Mohr’s theory with suitable examples.
3. Explain a) Bayer’s strain theory b) Sachse Mohr’s theory with example.
4. Discuss the method of synthesis of cyclopropane and cyclobutane.

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UNIT I

 Benzene and its derivatives  Reactions of benzene

1. Give the structure and general uses of Saccharin.

2. Define aromatic electrophilic substitution reactions.

3. Explain resonance effect.

5. What is aromoticity? Why benzene is called as an aromatic compound?

6. Give the structure and general uses of DDT.

7. Give the structure and general uses of Benzene hexachloride (BHC).

8. What are activating and deactivating groups?

9. Give the structure and general uses of Chloramine.

10. Outline the general mechanism of aromatic electrophilic substitution reactions.

1. Explain the facts supporting kekule structure of Benzene.

2. Explain the Huckel’s rule.

3. Describe the mechanism of Acylation and nitration of benzene.

4. Give the structure and general uses of DDT and BHC.

5. Discuss the theory of reactivity in aromatic rings.

6. Discuss the stability of benzyl radical.

7. Explain the mechanism of halogenation of benzene.

9. Outline the nomenclature steps involved in the naming of aromatic compounds.

4. Explain Friedel Craft’s reactions with examples and mechanism.

1. Write the structure of ortho- hydroxy benzoic acid.

2. Arrange the order of acid strength: phenol, o-cresol, o- Nitrophenol.

4. Compare the basicity of any two aromatic amines.

5. Describe any two methods for the preparation of phenol.

6. What is the diazonium reaction?

7. Give the structure of resorcinol.

8. Define phenols. Give its medicinal uses

9. What are aromatic amines and its uses?

1. Explain the effect of substituents on acidity of benzoic acid.

2. Give the structure and uses of some important phenolic compounds.

3. Write about Kolbe’s reaction

4. Explain the effect of substituents on acidity of phenols.

5. Write the preparation and synthetic utility of diazanium salts.

6. Discuss the basicity of aromatic amines.

7. What is the diazonium reaction? Explain the general reaction?

2. Give the difference between iodine value and acetyl value

3. What is rancidity of oils?

4. Classify fatty acids with examples.

5. What is hydrolysis of fatty acids and its importance

6. Define acid value. Give its significance.

7. Define saponification value. Give its significance.

8. Define iodine value. Give its significance.

9. Define drying, semidrying and non drying of oils.

10. What is hydrogenation of oils? Give examples.

11. Distinguish between fats and oils. Give examples

12. Define saturated and unsaturated fatty acids. Give examples.

13. What is unsaponifiable matter and give its significance.

14. Give the chemical composition of fats, oils & waxs.

15. Mention the analytical constants of fats and oils.

2. Discuss the rancidity of oils.

3. Explain hydrogenation and saponification of fatty acids

4. With example explain saponification reaction of fatty acid.

5. Give the principle in involved in the hydrolysis reaction of fatty acid.

6. Add a note on drying of oils.

9. Explain the chemistry of fats, oils and waxes.

10. Write a note on hardening of oils.

11. Write a note on drying, semidrying & nondrying of oils.

14. Explain hardening of oils & hydrogenation of oils.

2. Discuss a) Acid value b) Ester value c) RM value d) Acetyl value

3. Define iodine value. Give a method of determination and its significance.