Kalaj(IV) jodid

Kalaj(IV) jodid
Photograph of a sample of tin tetraiodide	Ball-and-stick model of the unit cell of tin tetraiodide
Structure and dimensions of the tin(IV) iodide molecule	Ball-and-stick model of the tin(IV) iodide molecule
	Kalaj(IV) jodid
Drugi nazivi	Kalaj tetrajodid; stani jodid
Identifikacija
CAS registarski broj	7790-47-8
PubChem	11490544
ChemSpider	23033
EINECS broj	232-208-4
Jmol-3D slike	Slika 1
SMILES
	[Sn](I)(I)(I)I
InChI
	InChI=1S/4HI.Sn/h41H;/q;;;;+4/p-4 ; Kod: QPBYLOWPSRZOFX-UHFFFAOYSA-J InChI=1/4HI.Sn/h41H;/q;;;;+4/p-4; Kod: QPBYLOWPSRZOFX-XBHQNQODAO
Svojstva
Molekulska formula	SnI4
Molarna masa	626.328 g mol−1
Agregatno stanje	crveno-narandžasti prah
Gustina	4.56 g cm−3
Tačka topljenja	144 °C
Tačka ključanja	348 °C
Struktura
Kristalna rešetka/struktura	Kubna, cP40
Kristalografska grupa	P-43m, No. 205
	(šta je ovo?) (verifikuj) ; Ukoliko nije drugačije napomenuto, podaci se odnose na standardno stanje (25 °C, 100 kPa) materijala
	Infobox references

Kalaj(IV) jodid (stani jodid) je hemijsko jedinjenje sa formulom SnI₄. Ovaj tetraedralni molekul se kristališe kao svetlo narandžasti prah. On se lako rastvara u nepolarnim rastvaračima kao što je benzen.^[5]

Ovo jedinjenje se obično priprema reakcijom joda i kalaja:^[6]

Sn + 2 I₂ → SnI₄

SnI₄ se hidrolizuje u vodi.^[7] U vodenom rastvoru jodovodonične kiseline, on reaguje da formira retki primer metalnog heksajodida:^[6]

SnI₄ + 2 I⁻ → [SnI₆]²⁻

Povezano

Reference

↑ Li Q, Cheng T, Wang Y, Bryant SH (2010). „PubChem as a public resource for drug discovery.”. Drug Discov Today 15 (23-24): 1052-7. DOI:10.1016/j.drudis.2010.10.003. PMID 20970519. edit
↑ Evan E. Bolton, Yanli Wang, Paul A. Thiessen, Stephen H. Bryant (2008). „Chapter 12 PubChem: Integrated Platform of Small Molecules and Biological Activities”. Annual Reports in Computational Chemistry 4: 217-241. DOI:10.1016/S1574-1400(08)00012-1.
↑ Hettne KM, Williams AJ, van Mulligen EM, Kleinjans J, Tkachenko V, Kors JA. (2010). „Automatic vs. manual curation of a multi-source chemical dictionary: the impact on text mining”. J Cheminform 2 (1): 3. DOI:10.1186/1758-2946-2-3. PMID 20331846. edit
↑ Greenwood, Norman N.; Earnshaw, A. (1984). Chemistry of the Elements. Oxford: Pergamon. DOI:10.1002/crat.2170200510. ISBN 0-08-022057-6.
↑ Tin : compound data [tin (IV) iodide
↑ ^6,0 ^6,1 Moeller, T., Edwards, D. C., Brandt, R. L. and Kleinberg, J. (1953). „Tin(IV) Iodide (Stannic Iodide)”. Inorganic Syntheses. Inorganic Syntheses 4: 119–121. DOI:10.1002/9780470132357.ch40. ISBN 9780470132357.
↑ Hickling, G. G. (1990). „Gravimetric analysis: The synthesis of tin iodide”. J. Chem. Educ. 67 (8): 702–703. DOI:10.1021/ed067p702.

Literatura

Spoljašnje veze

Portal Hemija

[1] Li Q, Cheng T, Wang Y, Bryant SH (2010). „PubChem as a public resource for drug discovery.”. Drug Discov Today 15 (23-24): 1052-7. DOI:10.1016/j.drudis.2010.10.003. PMID 20970519. edit

[2] Evan E. Bolton, Yanli Wang, Paul A. Thiessen, Stephen H. Bryant (2008). „Chapter 12 PubChem: Integrated Platform of Small Molecules and Biological Activities”. Annual Reports in Computational Chemistry 4: 217-241. DOI:10.1016/S1574-1400(08)00012-1.

[3] Hettne KM, Williams AJ, van Mulligen EM, Kleinjans J, Tkachenko V, Kors JA. (2010). „Automatic vs. manual curation of a multi-source chemical dictionary: the impact on text mining”. J Cheminform 2 (1): 3. DOI:10.1186/1758-2946-2-3. PMID 20331846. edit

[4] Greenwood, Norman N.; Earnshaw, A. (1984). Chemistry of the Elements. Oxford: Pergamon. DOI:10.1002/crat.2170200510. ISBN 0-08-022057-6.

[5] Tin : compound data [tin (IV) iodide

[Moeller-6] 6,0 ^6,1 Moeller, T., Edwards, D. C., Brandt, R. L. and Kleinberg, J. (1953). „Tin(IV) Iodide (Stannic Iodide)”. Inorganic Syntheses. Inorganic Syntheses 4: 119–121. DOI:10.1002/9780470132357.ch40. ISBN 9780470132357.

[7] Hickling, G. G. (1990). „Gravimetric analysis: The synthesis of tin iodide”. J. Chem. Educ. 67 (8): 702–703. DOI:10.1021/ed067p702.

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p • r • u Jodidi
HI																	He
LiI	BeI₂											BI₃	CI₄	NI₃	I₂O₄, I₂O₅, I₄O₉	IF, IF₃, IF₅, IF₇	Ne
NaI	MgI₂											AlI₃	SiI₄	PI₃, P₂I₄	S	ICl, ICl₃	Ar
KI	CaI₂	Sc	TiI₄	VI₃	Cr	MnI₂	Fe	CoI₂	NiI₂	CuI	ZnI₂	Ga₂I₆	GeI₂, GeI₄	AsI₃	Se	IBr	Kr
RbI	SrI₂	Y	ZrI₄	Nb	Mo	Tc	Ru	Rh	Pd	AgI	CdI₂	InI₃	SnI₄, SnI₂	SbI₃	TeI₄	I	Xe
CsI	BaI₂		Hf	Ta	W	Re	Os	Ir	Pt	AuI	Hg₂I₂, HgI₂	TlI	PbI₂	BiI₃	Po	At	Rn
Fr	Ra		Rf	Db	Sg	Bh	Hs	Mt	Ds	Rg	Cn	Uut	Uuq	Uup	Uuh	Uus	Uuo
		↓
		La	Ce	Pr	Nd	Pm	SmI₂	Eu	Gd	TbI₃	Dy	Ho	Er	Tm	Yb	Lu
		Ac	ThI₄	Pa	U	Np	Pu	Am	Cm	Bk	Cf	Es	Fm	Md	No	Lr