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    Tutorial 2 Carbonyl Compounds

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    The document provides a tutorial on carbonyl compounds (aldehydes and ketones). It includes questions asking to name carbonyl compounds using IUPAC nomenclature, draw structural formulas, and predict products of reactions between carbonyl compounds and various reagents. It also provides sample questions from past exams testing knowledge of carbonyl chemistry.

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    Tutorial 2 Carbonyl Compounds

    Uploaded by

    2022834672
    62 views12 pages
    The document provides a tutorial on carbonyl compounds (aldehydes and ketones). It includes questions asking to name carbonyl compounds using IUPAC nomenclature, draw structural formulas, and predict products of reactions between carbonyl compounds and various reagents. It also provides sample questions from past exams testing knowledge of carbonyl chemistry.

    Original Title

    TUTORIAL 2 CARBONYL COMPOUNDS

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    The document provides a tutorial on carbonyl compounds (aldehydes and ketones). It includes questions asking to name carbonyl compounds using IUPAC nomenclature, draw structural formulas, and predict products of reactions between carbonyl compounds and various reagents. It also provides sample questions from past exams testing knowledge of carbonyl chemistry.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    62 views12 pages

    Tutorial 2 Carbonyl Compounds

    Uploaded by

    2022834672
    The document provides a tutorial on carbonyl compounds (aldehydes and ketones). It includes questions asking to name carbonyl compounds using IUPAC nomenclature, draw structural formulas, and predict products of reactions between carbonyl compounds and various reagents. It also provides sample questions from past exams testing knowledge of carbonyl chemistry.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 12

    TUTORIAL 2: CARBONYL COMPOUNDS (ALDEYDE AND KETONE)

    1. Write the IUPAC names for these carbonyl compounds.


    a) CH3CH(CH3)CH(Cl)CH2CH2CHO

    b) CH3-CH2-CH2-CH=CH-CHO

    c) O O
    CH3 C CH2 CH2 CH2 C H

    d)

    O
    e)
    O

    O
    f)
    O

    g)
    O

    h)

    CHO
    2. Draw the structural formula for the following organic compounds.
    a) 4-methyl-4-pentenal
    b) cis-3-tert-butylcyclohexanecarbaldehyde
    c) 3,5-dinitrobenzaldehyde
    d) 1-chloro-2-hydroxy-3-hexanone
    e) 4-heptene-2-one
    f) phenyl propyl ketone

    3. Give the products formed when propanal and propanone reacts with following
    reagents:
    a) NaBH4
    b) K2Cr2O7/H2SO4
    c) 2,4-dinitrophenylhydrazine
    d) CH3CH2MgBr, then H3O+

    COMPILATION OF QUESTIONS FROM PAST YEAR


    JULY 2023
    QUESTION 8

    Compound O: Propanal
    Compound P: Propanone
    Compound Q: Benzaldehyde

    Predict the expected observation for compound O, P and Q when treated with the following
    chemical reagent.

    a) Tollen’s reagent
    (2 marks)

    b) Fehling’s solution
    (3 marks)
    QUESTION 2

    Consider the following reaction.

    Compound X

    Li+-AlH(O-t-Bu)3

    PCC/ CH2Cl2 O
    Compound W 2,4-DNP
    H Compound Y

    2-cyclohexyl ethanal

    CH3MgBr

    Compound Z

    a) Illustrate the structural formula for compound W and X.


    (2 marks)

    b) Write the balanced chemical equation when 2-cyclohexyl ethanal produces compound Y.

    (3 marks)

    c) Nucleophilic addition reaction of 2-cyclohexyl ethanal produces compound Z. Outline a


    stepwise mechanism for this reaction.
    (5 marks)

    FEBRUARY 2023
    QUESTION 6

    Consider the following compounds.

    a) Give the IUPAC name for compound K and compound L.

    (3 marks)

    b) Predict the product formed when compound L reacts with acidic potassium permanganate.

    (2 marks)
    QUESTION 2

    a) Outline the synthetic pathway to produce aniline from benzaldehyde.

    (6 marks)

    b) Compound T is a ketone with molecular formula of C5H10O can be prepared from oxidation
    of 3-methyl-2-butanol. Compound T will react with hydrogen cyanide to produce compound
    U. Compound U then reacts with water and yield compound V. In other reaction, compound
    T undergoes condensation with hydrazine and produce compound W. Determine the
    structural formula for compound T, U, V and W.
    (4 marks)

    JULY 2022
    QUESTION 2

    a) Suggest the structural formula for the following compounds.

    i) Oct-4-ene-2-one
    ii) 4-benzylcyclohexanecarbaldehyde
    (3 marks)

    b) Explain a chemical test to differentiate 2-propanone and propanal.


    (2 marks)
    QUESTION 1

    Consider the following reaction scheme.

    Compound Q

    phenylhydrazine

    O O O
    Reagent I Reagent II
    Cl H OH
    3-methylbutanal

    Zn/Hg, HCl
    MgBr

    Compound M
    Compound N

    a) Predict suitable reagents for Reagent I and II.


    (2 marks)

    b) Illustrate the chemical structures for compound M, N and Q.


    (6 marks)

    c) Sketch the product formed when 3-methylbutanal reacts with water.


    (2 marks)
    FEBRUARY 2022
    QUESTION 2

    a) Give the IUPAC name for compound A and B.


    O
    NO2
    H

    O
    NO2

    Compound A Compound B
    (3 marks)

    b) Suggest two chemical tests to differentiate propanal and 3-pentanone.


    (2 marks)

    QUESTION 1

    Consider the following scheme

    a) Illustrate the chemical structures for compound R, S and T.


    (6 marks)

    b) Predict the suitable reagents for X and Y.


    (2 marks)

    c) Show a stepwise mechanism for the conversion of compound Q to compound R.

    (2 marks)
    DECEMBER 2019
    DECEMBER 2018
    JUNE 2019
    JUNE 2018
    JAN 2018

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