OVERVIEW UNIT PROPYLENE RECOVERY (104)

I. FUNGSI PROPYLENE RECOVERY UNIT

Fungsi
Memisahkan dan mengolah stream mixed C3/C4 yang berasal
unit LPG Merox 103 untuk menghasilkan propylene grade
polymer (minimum purity 99.5 %-wt) dan mixed LPG.

II. SPESIFIKASI FEED & PRODUK

Spesifikasi Feed
MIXED C3/C4
DESCRIPTION
KMOL/HR
Comp Component Name
1 H2O 1.59
4 =C2 0.00045
5 C2 0.073
6 MEAC 0.14
7 PD 0.016
8 =C3 431.57
9 C3 120.22
10 =IC4 117.54
11 =N1C4 99.81
12 =T2C4 122.86
13 =C2C4 85.2
14 IC4 194.8
15 NC4 58.41
16 =IC5 5.72
17 IC5 6.59
18 NC5 0.14
19 C6+ 0.00041
TOTALS 1244.70
WEIGHT FLOW, KG/H 62973
MOLE WEIGHT, KG/KG MOLE 50.59
LIQ VOL FLOW, STD M3/H 112.0
LIQ DENSITY, KG/STD M3 562.4
VAP VOL FLOW, NRML M3/H 0
VAP DENSITY, KG/NRML M3 0

UNIT PROPYLENE RECOVERY (104) 1

Spesifikasi Produk Propylene
Analysis Method Min Max
Propylene, mole% UOP-539 99.6 -
Total Paraffines, mol% UOP-539 - 0.4
Methane, wt-ppm UOP899 or UOP-542 Mod. - 20
Ethylene, wt-ppm UOP899 or UOP-542 Mod. - 25
Ethane, wt-ppm UOP899 or UOP-542 Mod. - 200
Cyclopropane, wt-ppm UOP899 or UOP-542 Mod. - 10
C4 Hydrocarbons, wt-ppm UOP-899 - 5
Pentane, vol-ppm UOP-899 - 100
Acetylene, wt-ppm UOP899 or UOP-542 Mod. - 1
Methyl Acetylene, wt-ppm UOP899 or UOP-542 Mod. - 2
Propadiene, wt-ppm UOP899 or UOP-542 Mod. - 2
1, 3 Butadienes, wt-ppm UOP899 or UOP-542 Mod. - 2
Total Butenes, vol-ppm UOP899 or UOP-542 Mod. - 100
Hydrogen, wt-ppm ASTM D-2504 - 20
Nitrogen, wt-ppm ASTM D-2504 - 100
Carbon Monoxide, wt-ppm UOP-603 Mod. - 0.1
Carbon Dioxide, wt-ppm UOP-603 Mod. - 1
Oxygen, wt-ppm ASTM D-2504 - 1
Water, wt-ppm Panametric - 2.5
Methanol(+Isopropyl
UOP-757 - 5
Alcohol) , wt-ppm
Chloride, wt-ppm UOP-606 - 1
Total Sulfur, wt-ppm ASTM D-4468 - 1
Total Carbonyl as MEK, vol-
UOP-496 - 10
ppm
COS, wt.ppb ASTM D-4468 Mod. - 30
Arsine, wt-ppb UOP-834 Mod. - 30
Phosphine, wt-ppm GC FPD - 0.03
Ammonia, wt-ppm UOP-430 - 5
Antimony, wt-ppb AAS GF - 30
Pentene, vol-ppm UOP-899 - 10

UNIT PROPYLENE RECOVERY (104) 2

Spesifikasi Produk Mixed LPG
Analysis Method Min. Max.
ASTM D-2163
Composition
or UOP-539
C2, vol-% - 0.2
C3 + C4, vol-% 97.5 -
C5+ (C5 and heavier), vol-% - 2
Mercaptan Sulfur in Treated
UOP-212 - 5
LPG, wt-ppm
Total Sulfur, grains/100 cu.ft ASTM D-2784 - 15
Weathering Test at 36℉,
ASTM D-1837 95
vol%
Water Content Visual No free water
Copper Strip Corrosion Test ASTM D-1838 No.1

Battery Limit Condition

Process In
Operating Pressure Operating
(kg/cm2(g)) Temperature (℃)
Treated LPG 21.1 38.0
Circulating Heavy
7.4 161
Naphtha

Process Out
Operating Pressure Operating
(kg/cm2(g)) Temperature (℃)
Circulating Heavy
6.9 138
Naphtha
Off- gas 18.6 48.0
LPG 14.6 38.0
Sour Water 6.0 38.0
Propylene 23.4 29.0

UNIT PROPYLENE RECOVERY (104) 3

III. DESKRIPSI PROSES
1. Mixed C3/C4 dialirkan menuju C3/C4 splitter (104-C-501)
untuk dipisahkan butane/butylene (C4) dan
propane/propylene (C3)  menggunakan sistem kolom
distilasi konvensional.
2. Propylene dipisahkan dari propane di C3 Splitter (104-C-502)
 menggunakan modified distilation system dengan
penerapan tiga teknologi : (1) Heat pump compressor untuk
penyedia reboiler heating medium dan refluks, (2) UOP MD
distillation trays sebagai internal kolom, (3) UOP high flux
tube pada reboiler
3. Butane/butylene sebagai bottom product 104-C-501 dan
propane sebagai bottom product 104-C-502 dialirkan
menuju tanki LPG 47-T-501A~C
4. Propylene ex-104-C-502 yang masih mengandung air dalam
konsentrasi jenuh dihilangkan di propylene drier (104-V-
504A/B) sedangkan metal content dihilangkan di propylene
treater (104-V-505A/B)
5. Treated propylene yang telah memenuhi spec grade
polyemer dialirkan menuju tanki Propylene 47-T-511A~F

IV. PROSES VARIABEL

Feed Quality
 Reaktor RFCC dioperasikan pada severitas tinggi 
kandungan olefin meningkat
 Semakin banyak feed RFCC yang berasal dari hydrotreated
material, maka semakin menurun kandungan olefin
 C3 splitter (104-C-502) dilengkapi dengan multiple feed nozzle
untuk menjaga kualitas produk yang diinginkan ketika
konsentrasi olefin di feed PRU berubah
Feed Rate
 Perubahan kapasitas feed menuju unit akan mengubah beban
HE dan vapor/liquid loading di kolom fraksinasi
 Pengoperasian unit pada feed rate (LHSV) yang tinggi di atas
desain akan menyebabkan propylene drier (104-V-504) dan
propylene treater (104-V-503) mengalami overload proses
sehingga dapat menyebabkan produk propylene
terkontaminasi (off-spec).

UNIT PROPYLENE RECOVERY (104) 4

Pemisahan C3/C4 (C3/C4 Splitter)
 Pemisahan C3/C4 ditentukan oleh pengontrolan temperature
tray atas dengan aliran sejumlah refluks yang dikirim ke kolom
 Tujuan dari pengontrolan ini adalah meminimalkan loss C3s
(top fraction) menuju stream C4 (bottom fraction) karena
merupakan loss yield
 Biasanya ada sebagian kecil fraksi iso-butene dan n-butane di
fraksi overhead.
Propylene purity
 Target tingkat kemurnian produk propylene tergantung dari
aplikasi; chemical grade : min. 95%-wt, polymer grade : min.
99.5 %-wt.
 Kemurnian produk dimonitor dengan pengecekan kemurnian
overhead product C3 splitter (104-C-502) dengan online
analyzer (104-AIC-001).
 Untuk menjaga tingkat kemurnian produk, jumlah pemanasan
di kolom diatur dengan mengalirkan sejumlah overhead gas
yang panas ex-discharge heat pump compressor (104-K-501)
yang akan dikirimkan melalui reboiler

KONDISI OPERASI
C3/C4 Splitter (104-C-501)
Variable Control
Feed Inlet Temp. 66 C
Tower Ovhd Press 19.2 kg/cm2g
Reboiler Return Temp. 109 C
Reflux/ Feed Ratio 1.25-1.50 (typical)
As necessary to obtain the desired split of
Tray Temp. for Cut
C3 from C3

C3 Splitter (104-C-502)
Variable Control
Overhead Temp. 29 C
Compressor Suction Press. 12 kg/cm2g
Reflux/ Feed Ratio 12.5 (typical)
Reboiler Return Temp. 47 C

UNIT PROPYLENE RECOVERY (104) 5

V. PERFORMANCE MONITORING
DESCRIPTION TAG NO. UNIT VALUE
C3/C4 Splitter Feed Inlet Temperature 104-TI-004 ℃ 68
C3/C4 Splitter Overhead Pressure 104-PI-003 kg/cm2(g) 19.2
C3/C4 Splitter Reflux/ Feed Ratio - - 1.25-1.5
C3/C4 Splitter Tray Temperature for Cut 104-TI-005 ℃ 50
C3 Splitter Overhead Temperature 104-TI-012 ℃ 29
Compressor Suction Pressure 104-PIC-013 kg/cm2(g) 12.1
C3 Splitter Reflux/Feed Ratio - - 12.5
C3 Splitter Reboiler Return Temperature 104-TI-013 ℃ 41
Propane content 104-AIC-001 %-wt 0.5
Propylene Lead Drier Outlet Moisture
104-AI-002 ppm.wt max. 1
Content

VI. INTERKONEKSI DENGAN UNIT LAIN

Unit 103 (LPG Merox)
Stream mixed C3/C4 (LPG) dari Water Wash Vessel (103-V-504)
menuju C3/C4 Splitter Feed-Bottom Exchanger (104-E-501A/B).
Laju alir LPG dikontrol oleh LPG pressure controller (103-PIC-
001).
Unit 101 (RFCC)
Pemanasan di C3/C4 Splitter (104-C-501) berasal dari sirkulasi
heavy naphtha menuju C3/C4 Splitter Reboiler (104-E-503) dan
kembali ke Main Column (101-C-521). Jumlah aliran sirkulasi
heavy naphtha dikontrol oleh 104-FIC-003.
Unit 102 (Gas Concentration)
Fraksi offgas (C3-) akan menuju High Pressure Trim Condenser
(102-E-502A~D).
Unit 107 (Sour Water Stripping)
Sour water dari C3/C4 Splitter Receiver (104-V-501) dan
Regenerant Surge Drum (104-V-503) mengalir menuju Sour
Water Surge Drum (107-V-501). Masing-masing stream
dikontrol oleh LIC bootleg (104-LIC-003/011).

UNIT PROPYLENE RECOVERY (104) 6

Unit 47 (Tankage)
 Treated LPG dari bottom C3/C4 Splitter (104-C-501) dan
bottom C3 Splitter (104-C-502) akan bercampur dan
dikirimkan menuju Mixed LPG Storage Tank (47-T-501A~C).
Produk LPG dikontrol oleh 104-PIC-016.
 Propylene dari Propylene Treater (104-V-505A/B) akan
dikirimkan menuju Propylene Tank (47-T-511A~F) dan
dikontrol oleh 104-PIC-010.

UNIT PROPYLENE RECOVERY (104) 7

VII. DATA SHEET EQUIPMENT
Vessel
Type Design Condition Operating Condition
Tag
Description Press Temp Press Temp Internal
Number Vert / Hor
(kg/cm2.g) (oC) (kg/cm2.g) (oC)
104-V-501 C3/C4 SPLITTER RECEIVER Hor w/ Boot 22 120 18.6 45 -
104-V-502 COMPRESSOR SUCTION DRUM Vert 14 120 12.1 29 Mesh Blanket
104-V-503 REGENERANT SURGE DRUM Hor w/ Boot 18 120 16 38 -
104-V-504 PROPYLENE DRIERS Vert 30.5 260 24 30 - 20 Mesh Screen
A/B - Molecular Sieve
- Ceramic Balls 3, 6, 19 mm
104-V-505 PROPYLENE TREATERS Vert 30.5 345 24 29 - 20 Mesh Screen
A/B - Molecular Sieve
- Ceramic Balls 3, 6, 19 mm

Kolom
Design Condition Operating Condition
Type Internal
Tag Internal Top Bottom Tray /
Description
Number Vert / Press Temp Press Temp Press Temp Tray / Bed
Hor (kg/cm2.g) (oC) (kg/cm2.g) (oC) (kg/cm2.g) (oC) Packing
104-C-501 C3/C4 SPLITTER Vert 21.5 140 19.2 48 19.6 109 Tray #48
104-C-502 C3 SPLITTER Vert 14 120 12.1 28.9 13 40.6 Tray #190

UNIT PROPYLENE RECOVERY (104) 8

Kompresor
Operating Condition
Tag
Description Type Cap. Rated Press (kg/cm2.g) Temp (oC)
Number
(Nm3/hr) Suction Discharge Suction Discharge
104-K-501 HEAT PUMP COMPRESSOR Centrifugal 211.02 13.03 20.41 29 55.3

Pompa
Design Condition
Capacity Min. Pumping Rated
Tag Number Description Type Disch Press dP
Rated Flow Temp Power
(kg/cm2.g) (kg/cm2)
(m3/h) (m3/h) (oC) (kW)
104-P-501 A/B C3/C4 SPLITTER REFLUX PUMPS Centrifugal 245 128 23.35 4.29 45 37.7
104-P-502 A/B C3/C4 SPLITTER BOTTOM PUMPS Centrifugal 13.1 6.85 19.1 5.65 41 5.4
104-P-503 A/B C3/C4 SPLITTER OVERHEAD PUMPS Centrifugal 70.6 36.9 26.3 13.9 29 63.9
104-P-504 A/B SPENT REGENERANT PUMPS Centrifugal 4.48 - 25.75 14.8 38 10.4
HEAT PUMP SURFACE CONDENSER
104-P-505 A/B Centrifugal 18.5 - - 8.43 - 18.5
CONDENSATE PUMPS

UNIT PROPYLENE RECOVERY (104) 9

Exchanger
Operating Condition
SHELL SIDE TUBE SIDE
Tag TEMA Duty
Description Temp Temp Press Temp Temp Press
Number Type (MMkcal/h) Service
Service Fluid Inlet Outlet Inlet / Inlet Outlet Inlet /
o o Fluid
( C) ( C) dP (oC) (oC) dP
104-E-501 C3/C4 SPLITTER 21.62 / Splitter 19.87
AES 1.319 LPG 38 68 109 61
A/B FEED - BOTTOM 0.70 Bottom C4 / 1.05
C4 PRODUCT 18.69 / Cooling 3.2 /
104-E-502 AES 0.566 Hydrocarbon 61 38 33 38
COOLER 0.35 Water 0.70
C3/C4 SPLITTER C3/C4 Splitter 19.87 / Heavy 8.10 /
104-E-503 AJS 7.777 109 109 161 138
REBOILER Bottom 0.09 Naphta 0.70
C3/C4 SPLITTER C3/C4 Splitter 19.86 / 2.31 /
104-E-504 BJU 4.67 109 109 LP Steam 157 137
AUX REBOILER Bottom 0.08 nil
C3 Splitter
C3 SPLITTER C3 Splitter 13.32 / 19.23
104-E-505 BHM 22.34 41 41 Ovhd fm 55 47
REBOILER Bottom 0.11 / 0.32
104K-501
104-E-506 C3 SPLITTER TRIM 19.06 / Cooling 3.2 /
AES 2.659 C3 Vapor 55 47 33 46
A/B CONDENSER 0.35 Water 0.70
REGENERANT C3 Regenerant 16.47 / Cooling 3.2 /
104-E-507 AES 0.392 232 38 33 38
CONDENSER & Water 0.35 Water 0.70
DRIER REGENERANT 17.37 / 1.96 /
104-E-508 SPECIAL 0.186 Hydrocarbon 29 51 LP Steam 141 133
VAPORIZER 0.35 nil

UNIT PROPYLENE RECOVERY (104) 10

Exchanger (cont’d)
Operating Condition
SHELL SIDE TUBE SIDE
Tag TEMA Duty
Description Temp Temp Press Temp Temp Press
Number Type (MMkcal/h) Service
Service Fluid Inlet Outlet Inlet / Inlet Outlet Inlet /
o o Fluid
( C) ( C) dP (oC) (oC) dP
Surface Cooling
9.607 Steam 121* 1.05* - 120* 6.5* -
Cond Water
HEAT PUMP BEM
Cooling
COMPRESSOR (Inter 0.052 Hydrocarbon 172.8 0.279 43 -
104-E-510 Water
SURFACE Cond)
CONDENSER BEM
Cooling
(After 0.046 Hydrocarbon 213.3 1.07 50 -
Water
Cond)

Air Cooler
Operating Condition
Tag Duty
Description Type Temp Temp Press Inlet /
Number (MMkcal/h) Service Fluid
Inlet (oC) Outlet (oC) dP
104-E-509 C3/C4 SPLITTER CONDENSER 5 BAY 7.00 C3/C4 Splitter Ovhd 48 45 18.99 / 0.352

UNIT PROPYLENE RECOVERY (104) 11

Electric Heater
Operating Condition Design Condition
Heat
Tag Temp Temp Press
Description Type Process Req. Power Temp No. ef
Number Service Fluid Inlet Outlet Outlet /
(kW) (kW) (oC) Elements
(oC) (oC) dP
17.07 /
C3 Drier 231.3 Hydrocarbon 51 232
REGENERANT ELECTRIC 0.211
104-E-511 254.4 485 2
SUPERHEATER HEATER C3 1.102 /
90.8
Treater Nitrogen 36 260 0.211

Mixer
Design Condition Operating Condition
Tag
Description Service Press Temp Flow Press Temp Max. dP
Number
(kg/cm2.g) (oC) (m3/h) (kg/cm2.g) (oC) (kg/cm2)
Hydrocarbon C3 11.38 - 40.5
104-M-501 STATIC MIXER Hydrocarbon C4 20.5 120 69.38 - 37.8 0.35
Mix C3/C4 80.38 15.7 37.8

UNIT PROPYLENE RECOVERY (104) 12

VIII. MATERIAL BALANCE
Stream Index 100
C3/C4 SPLITTER
FEED FROM LPG
Description
MEROX UNIT
KMOL/HR
Comp Component Name
1 H2O 1.59
4 =C2 0.00045
5 C2 0.073
6 MEAC 0.14
7 PD 0.016
8 =C3 431.57
9 C3 120.22
10 =IC4 117.54
11 =N1C4 99.81
12 =T2C4 122.86
13 =C2C4 85.2
14 IC4 194.8
15 NC4 58.41
16 =IC5 5.72
17 IC5 6.59
18 NC5 0.14
19 C6+ 0.00041

TOTALS 1244.70
MOLE FLOW, KG MOLE/H 1244.70
WEIGHT FLOW, KG/H 62973
MOLE WEIGHT, KG/KG MOLE 50.59
LIQ VOL FLOW, STD M3/H 112.0
LIQ DENSITY, KG/STD M3 562.4
VAP VOL FLOW, NRML M3/H 0
VAP DENSITY, KG/NRML M3 0

UNIT PROPYLENE RECOVERY (104) 13

Stream Index 378
MIXED LPG PRODUCT
Description TO STORAGE
KMOL/HR
Comp Component Name
1 H2O 8.2E-10
4 =C2 9.7E-14
5 C2 8.6E-10
6 MEAC 0.14
7 PD 0.016
8 =C3 3.06
9 C3 118.57
10 =IC4 117.54
11 =N1C4 99.81
12 =T2C4 122.86
13 =C2C4 85.20
14 IC4 194.80
15 NC4 58.41
16 =IC5 5.72
17 IC5 6.59
18 NC5 0.14
19 C6+ 0.00041
20 HVY_NAP 0.00

TOTALS 812.87
MOLE FLOW, KG MOLE/H 812.87
WEIGHT FLOW, KG/H 44837
MOLE WEIGHT, KG/KG MOLE 55.16
LIQ VOL FLOW, STD M3/H 77.2
LIQ DENSITY, KG/STD M3 581.2
VAP VOL FLOW, NRML M3/H 0
VAP DENSITY, KG/NRML M3 0

UNIT PROPYLENE RECOVERY (104) 14

Stream Index 403 404
CIRCULATING CIRCULATING HEAVY
HEAVY NAPHTHA NAPHTHA RETURN TO
Description FROM RFCC RFCC
KMOL/HR KMOL/HR
Comp Component Name
1 H2O 0.00 0.00
4 =C2 0.00 0.00
5 C2 0.00 0.00
6 MEAC 0.00 0.00
7 PD 0.00 0.00
8 =C3 0.00 0.00
9 C3 0.00 0.00
10 =IC4 0.00 0.00
11 =N1C4 0.00 0.00
12 =T2C4 0.00 0.00
13 =C2C4 0.00 0.00
14 IC4 0.00 0.00
15 NC4 0.00 0.00
16 =IC5 0.00 0.00
17 IC5 0.00 0.00
18 NC5 0.00 0.00
19 C6+ 0.00 0.00
20 HVY_NAP 4395.95 4395.95

TOTALS 4395.95 4395.95

MOLE FLOW, KG MOLE/H 4395.95 4395.95
WEIGHT FLOW, KG/H 636093 636093
MOLE WEIGHT, KG/KG MOLE 144.70 144.70
LIQ VOL FLOW, STD M3/H 754.1 754.1
LIQ DENSITY, KG/STD M3 843.5 843.5
VAP VOL FLOW, NRML M3/H 0 0
VAP DENSITY, KG/NRML M3 0 0

UNIT PROPYLENE RECOVERY (104) 15

Stream Index 642
REGENERANT WATER TO
Description TREATING
KMOL/HR
Comp Component Name
1 H2O 1.46
4 =C2 0.00
5 C2 0.00
8 =C3 0.00
9 C3 0.00

TOTALS 1.46
MOLE FLOW, KG MOLE/H 1.46
WEIGHT FLOW, KG/H 26
MOLE WEIGHT, KG/KG MOLE 18.02
LIQ VOL FLOW, STD M3/H 0.0
LIQ DENSITY, KG/STD M3 999.0
VAP VOL FLOW, NRML M3/H 0
VAP DENSITY, KG/NRML M3 0

Stream Index 710 840

PROPTLENE TO REGENERATION GAS
Description STORAGE TO RELIEF HEADER
KMOL/HR KMOL/HR
Comp Component Name
1 H2O 0.00 1.55
2 N2 0.00 40.19
4 0 0.00045 0.00
5 C2 0.073 0.00
8 0 428.51 0.00
9 C3 1.65 0.00

TOTALS 430.23 40.19

MOLE FLOW, KG MOLE/H 430.23 40.19
WEIGHT FLOW, KG/H 18107 1126
MOLE WEIGHT, KG/KG MOLE 42.09 28.01
LIQ VOL FLOW, STD M3/H 34.8 0
LIQ DENSITY, KG/STD M3 520.4 0
VAP VOL FLOW, NRML M3/H 0 901
VAP DENSITY, KG/NRML M3 0 1.250

UNIT PROPYLENE RECOVERY (104) 16

IX. PARAMETER NORMAL OPERASI & BATASAN ALARM
TAG NO. SERVICE NORMAL LL L H HH UNIT
104-AIC-001 Propane content Discharge 104-K-501 0.33 %-mol
104-AI-002 Propylene Lead Drier Outlet Moisture Content max. 1 ppm.wt
104-FIC-001 C3/C4 Splitter Bottoms To Mixed LPG Tank 69 76.1 m3/hr
104-FIC-002 LP Condensate from C3/C4 Splitter Reboiler 10 m3/hr
104-FIC-003 Circulating Heavy Naphtha To C3/C4 Splitter Reboiler 850 700 m3/hr
104-FIC-004 Mixed C3 to 104-C-502 51 m3/hr
104-FIC-005 C3/C4 Splitter Reflux 212 170 233 m3/hr
104-FI-006 Offgas Outlet C3/C4 Splitter Receiver 337 Nm3/hr
104-FI-026 C3/C4 Splitter Bottom to LPG Tank 83.1 m3/hr
104-FIC-007 C3 Splitter Bottoms Pump Discharge 7.9 7.63 m3/hr
104-FIC-008 C3 Splitter Net Bottoms To Mixed LPG Tank 11.3 m3/hr
104-FIC-009 Reflux From C3 Splitter Reboiler 660 468 m3/hr
104-FIC-012 Suction Heat Pump Compressor 104-K-501 161607 Nm3/hr
104-FIC-013 Discharge HPC Outlet Trim Condenser 104-E-506A/B 78.5 m3/hr
104-FIC-048 Condensate ex Surface Condenser 104-E-510 13.2 m3/hr
104-FIC-011 Propylene To Propylene Drier 104-V-504A/B 36 m3/hr
104-FI-014 Propylene Driers Moisture Monitor Sample Return 4.2 L/h
104-FAH-015 Propylene Driers Bleed Header To Relief Header 10 Nm3/hr
104-FIC-010 Min Flow Propylene To 104-C-502 25 m3/hr
104-FIK-016 Propylene To Drier Regeneration Vaporizer 4.2 2.2 m3/hr
104-FI-017 Propylene To Drier Regeneration Vaporizer 4.2 1.7 2.2 m3/hr

UNIT PROPYLENE RECOVERY (104) 17

TAG NO. SERVICE NORMAL LL L H HH UNIT
104-FIC-018 Spent Regenerant to 104-V-504A/B 4.5 m3/hr
104-FIK-021 Nitrogen To Treater Regeneration Loop 901 480 Nm3/hr
104-FI-020 Nitrogen To Treater Regeneration Loop 901 360 480 Nm3/hr
104-FI-019 Propylene Product To Storage 34.8 28.8 40 m3/hr
104-FAH-022 Propylene Treaters Bleed Header To Relief Header 10 Nm3/hr
104-FI-035 HP Steam From Header 13200 13000 15500 kg/hr
104-FI-023 MP Steam From Header 3200 1680 3300 kg/hr
104-FI-025A LP Steam From Header (Consumption) 9030 280 9420 kg/hr
104-FI-025B LP Steam From Header (Production) 2980 1450 3000 kg/hr
104-FI-027 MP BFW From Header 0.51 m3/hr
104-FI-028 Surface Condensate to Header 13.4 m3/hr
104-FI-029 Cooling Water Supply from Header 1150 m3/hr
104-FI-033 Nitrogen from Header 917 Nm3/hr
104-FI-031 Instrument Air From Header 185 180 210 Nm3/hr
104-FI-032 Plant Air From Header 200 220 Nm3/hr
- C3/C4 Splitter Reflux/ Feed Ratio 1.25 - 1.5 -
- C3 Splitter Reflux/Feed Ratio 12.5 -
104-TI-003 C3/C4 Splitter Bottoms To Mixed LPG Tank 38 43 ℃
104-TI-002 LP Steam From Desuperheater 157 147 167 ℃
104-TIC-001 LP Steam From Desuperheater 157 147 167 ℃
104-TIC-006 C3/C4 Splitter Tray Temperature for Cut 50 ℃
104-TI-004 Treated LPG To C3/C4 Splitter 68 78 ℃

UNIT PROPYLENE RECOVERY (104) 18

TAG NO. SERVICE NORMAL LL L H HH UNIT
104-TI-007 C3/C4 Splitter Overhead Temp 48 ℃
104-TI-049 C3/C4 Splitter Overhead Temp 48 ℃
104-TI-010 C3/C4 Splitter Overhead Outlet Condenser 104-E-509 45 ℃
104-TI-008 C3/C4 Splitter Bottom Temp 109 ℃
104-TI-014 C3 Splitter Bottom Temp 41 ℃
104-TI-009 Heavy Naphta C3 Splitter Reboiler Return Temp 138 ℃
104-TI-030 C3 Splitter Net Bottoms To Mixed LPG Tank 38 43 ℃
104-TI-072 Mixed C3 to 104-C-502 Temp 33 ℃
104-TI-015 Reflux From C3 Splitter Reboiler Temp 29 ℃
104-TI-016 Compressor Suction Drum Temp 29 ℃
104-TI-011 HP Steam To Heat Pump Compressor Turbine 385 375 395 ℃
104-TI-018 Temp Suction Heat Pump Compressor 104-K-501 29 55 ℃
104-TI-017 Temp Discharge Heat Pump Compressor 104-K-501 55 ℃
104-TI-020 Propylene Outlet Vaporizer 104-E-508 51 ℃
104-TI-019 Regenerant Outlet Driers 104-V-504A/B ℃
104-TI-025 Regenerant From Regenerant Superheater 232 ℃
104-TIK-026 Regenerant From Regenerant Superheater 232 250 ℃
104-TXI-021 Regenerant Superheater Inlet Bundle Skin 625 650 ℃
104-TXI-022 Regenerant Superheater Inlet Bundle Skin 625 650 ℃
104-TXI-023 Regenerant Superheater Outlet Bundle Skin 625 650 ℃
104-TXI-024 Regenerant Superheater Outlet Bundle Skin 625 650 ℃
104-TI-027 Regenerant Outlet Treater 104-V-505A/B ℃

UNIT PROPYLENE RECOVERY (104) 19

TAG NO. SERVICE NORMAL LL L H HH UNIT
104-TI-029 Regenerant From Regenerant Condenser 38 48 ℃
104-TI-028 Propylene Product To Propylene Tank 29 34 ℃
104-TI-041 HP Steam From Header 385 350 410 ℃
104-TI-043 MP Steam From Header 320 300 360 ℃
104-TI-046 LP Steam From Header 210 160 220 ℃
104-TI-005 C3/C4 Splitter Tray Temperature for Cut 50 ℃
104-TI-012 C3 Splitter Overhead Temperature 29 ℃
104-TI-013 C3 Splitter Reboiler Return Temperature 41 ℃
104-LIC-001 C3/C4 Splitter Bottoms 50 20 80 20.5 %
104-LIC-002 C3/C4 Splitter Receiver 50 20 80 %
104-LIC-003 C3/C4 Splitter Receiver Interface 50 10 90 %
104-LIC-004 C3 Splitter Bottoms 50 20 80 %
104-LIC-005 Compressor Suction Drum 50 20 80 %
104-LI-006A/B/C Compressor Suction Drum 20 40 50 %
104-LI-007 Drier Regenerant Vaporizer 80 %
104-LI-008 Drier Regenerant Vaporizer (High Tapping Level) 40 55 %
104-LI-010 Regenerant Surge Drum 15 20 80 85 %
104-LIC-011 Regenerant Surge Drum Interface 50 10 90 %
104-PI-027 C3/C4 Splitter Overhead Press 19.2 20 kg/cm2(g)
104-PI-003 C3/C4 Splitter Overhead Press 19.2 kg/cm2(g)
104-PI-001 C3/C4 Splitter Bottom Press 19.5 kg/cm2(g)
104-PDI-002 C3/C4 Splitter dP kg/cm2

UNIT PROPYLENE RECOVERY (104) 20

TAG NO. SERVICE NORMAL LL L H HH UNIT
104-PIC-004 C3/C4 Splitter Overhead Press 19.2 kg/cm2(g)
104-PIC-016 C3/C4 Splitter Bottom to LPG Tank (after Mixer) 14.6 kg/cm2(g)
104-PDIC-005 C3/C4 Splitter Condenser Hot Vapor Bypass 0.2 0.6 kg/cm2
104-PI-028 C3 Splitter Overhead Press 12.1 12.5 12.8 kg/cm2(g)
104-PI-064 Mixed C3 to 104-C-502 Press 12.7 kg/cm2(g)
104-PI-008 C3 Splitter Overhead Press 12.1 kg/cm2(g)
104-PI-006 C3 Splitter Bottom Press 13 kg/cm2(g)
104-PDI-007 C3 Splitter dP kg/cm2
104-PIC-013 Compressor Suction Drum Press 12.1 12.8 kg/cm2(g)
104-PI-029 HP Steam To Heat Pump Compressor Turbine 42 39 44 kg/cm2(g)
104-PI-127 Press Suction Heat Pump Compressor 104-K-501 12 kg/cm2(g)
104-PI-128 Press Discharge Heat Pump Compressor 104-K-501 19.3 kg/cm2(g)
104-PI-014 Propylene outlet 1st Drier 104-V-504A kg/cm2(g)
104-PI-015 Propylene outlet 2nd Drier 104-V-504B 22.8 kg/cm2(g)
104-PDI-018 Regenerant Outlet Driers 104-V-504A/B dP kg/cm2
104-PIK-009 LP Steam Inlet Vaporizer 104-E-508 3.5 kg/cm2(g)
104-PI-011 Propylene outlet 1st Treater 104-V-505A kg/cm2(g)
104-PI-012 Propylene outlet 2nd Treater 104-V-505B 21 kg/cm2(g)
104-PIC-010 Propylene Product To Propylene Tank 21.8 kg/cm2(g)
104-PI-066 NITROGEN FOR RE-START & BACK-UP 17 kg/cm2(g)
104-PI-045 HP Steam From Header 42 39 44 kg/cm2(g)
104-PI-047 MP Steam From Header 18.5 16 20 kg/cm2(g)
104-PI-051 LP Steam From Header 3.5 2.8 4.5 kg/cm2(g)

UNIT PROPYLENE RECOVERY (104) 21

X. ADSORBENT REQUIREMENT
No. Deskripsi Catalyst/Chemical Kuantitas, m3
Propylene Drier UOP Molsiv Adsorbent
1 6.78 x 2
(104-V-504) Type ODG-442
Inert Ceramic Balls 19 mm : 1.47
6 mm : 0.34
3 mm : 0.34
Propylene Treater UOP Molsiv Adsorbent
2 10.06 x 2
(104-V-505) Type GB-238
Inert Ceramic Balls 19 mm : 1.47
6 mm : 0.34
3 mm : 0.34

Propylene Drier Propylene Treater

XI. START-UP PROCEDURE

A. Purging unit
1. Unit dianggap air-free bila O2 < 0.5 %-mole
2. Purging dilakukan dengan steam diikuti fuel gas/nitrogen,
kecuali seksi tertentu yang sensitif terhadap air (water),
purging dilakukan dengan vacuum (600 mmHg) dan break
nitrogen (0.35 kg/cm2g).

UNIT PROPYLENE RECOVERY (104) 22

No. Seksi Medium Catatan
C3/C4 Splitter Steam --> Fuel Effluent menuju vent
1
(104-C-501) gas/nitrogen dan drain point
2 C3 Splitter (104-C-502) Vacuum --> Nitrogen Exclude 104-K-501;
Effluent menuju
ejector system
Heat pump compressor
3 Nitrogen Effluent menuju flare
(104-K-501)
Propylene Dryer Effluent menuju
4 Vacuum --> Nitrogen
(104-V-504) ejector system
Propylene Treater Effluent menuju
5 Vacuum --> Nitrogen
(104-V-504) ejector system

B. Pengaliran Cooling Water

Mulai alirkan cooling water menuju semua cooler di PRU

C. Pengaliran treated LPG menuju C3/C4 Splitter (104-C-501)

1. C3/C4 Splitter (104-C-501) diisi dengan treated LPG dari
unit 103 via 103-PV-001
2. Penyiapan C3/C4 Splitter Reboiler(104-E-503), C3/C4
Splitter Auxiliary Reboiler(104-E-504) dan C3/C4 Splitter
condenser(104-E-509) dengan menormalkan aliran utilities
(steam dan sirkulasi heavy naphtha dari unit 101)
3. Pemanasan kolom 104-C-501 perlahan dilakukan hingga
tercapai kondisi total refluks.
4. Jaga kondisi operasional kolom dengan mengacu pada
kontroller berikut :
Service Tag Auto/Manual Set point
Heat Flow to FIC-003 To give Design
Auto
Reboilers FIC-002 Reflux rate
To give Design
Reflux Rate TIC-006 Auto
Purity
Pressure PIC-004 Auto Design

D. Pengaliran mixed C3 menuju C3 Splitter (104-C-502)

1. C3 Splitter (104-C-502) diisi dengan mixed C3 dari
overhead C3/C4 Splitter (104-C-501); Jika pressure (104-
PIC-013) naik, maka venting nitrogen di sistem melalui
bypass line di 104-PSV-503A/B menuju flare.

UNIT PROPYLENE RECOVERY (104) 23

2. Inventori mixed C3 di Compressor Suction Drum (104-V-
502) via start-up filling line dari C3/C4 Splitter Reflux
Pumps(104-P-501A/B). Proses pengisian dilakukan hingga
pressure mencapai 12 kg/cm2g.
3. Lakukan depresure hingga 6 kg/cm2g dan pengisian
kembali hingga sample vapor menunjukkan kandungan
nitrogen < 0.5 %-mole.

E. Penyiapan Heat Pump Compressor (104-K-501)

Sebelum menjalankan compressor pastikan spillback control
loop telah disiapkan. Spillback valve (104-FV-012) harus dalam
posisi bukaan dan flow control valve outlet reboiler untuk
material overhead harus dalam posisi tutupan. Jalankan
compressor sesuai dengan rekomendasi manufaktur.

F. Pemanasan C3 Splitter (104-C-502) dan Penyiapan C3 Splitter

Trim condenser (104-E-506)
1. Flow control valve untuk overhead material outlet reboiler
ex-104-K-501 mulai dibuka untuk menaikkan tekanan
kolom menuju desain. Bersamaan dengan ini C3 Splitter
Trim condenser (104-E-506) mulai dinormalkan.
2. Jaga inventory di kolom dengan suplai feed dari C3/C4
Splitter (104-C-501).
3. Atur kondisi operasi untuk mendapatkan refluks sesuai
desain

G. Menuju Operasi normal C3 Splitter (104-C-502)

1. Bila refluks 104-C-502 tercapai, alirkan secara kontinyu
mixed C3 dari 104-C-501.
2. Produk bottom (propane) maupun overhead mulai
dialirkan untuk menjaga level.
Service Tag Mode Set Point
Mixed C3 Feed FIC-004 Auto Design
Heat Flow to For Design
FIC-009 Auto
Reboiler Reflux Rate
Comp.Disch. AIC-001/FIC-010 Cascade Per C3= Spec
Pressure AIC-001/FIC-010 Cascade Design
Compressor
PIC-013/FIC-013 Cascade 50%*
Suction Drum
Bottom Level LIC-005/FIC-011 Cascade 50%
Spillback FIC-012 Auto > Surge

UNIT PROPYLENE RECOVERY (104) 24

H. Inventory Propylene Driers and Treaters
1. Lakukan pengisian inventory di vessel secara seri. Laju
pengisian diatur oleh globe valve pada bypass PSV.
2. Persiapkan back pressure controller di outlet treater,
sehingga bila tekanan sistem telah tercapai, propylene
akan dikirimkan menuju off-spec storage.
I. Menuju Operasi Normal
1. Secara perlahan naikkan kapasitas mixed C3 hingga rate
desain.
2. Lakukan pengedrainan air dari semua point di di seksi
propylene drier hingga kering
3. Jika unit telah siap, lakukan regenerasi propylene drier
setiap hari dan propylene treater setiap beberapa hari.

UNIT PROPYLENE RECOVERY (104) 25