Limiting Reactants and Percent Yield: Physical Science

Download as pptx, pdf, or txt
Download as pptx, pdf, or txt
You are on page 1of 18

LIMITING

REACTANTS AND
PERCENT YIELD
PHYSICAL SCIENCE

Integrated School of Lawa CS_RS11 – Research in Daily Life I


Excellence Leads to Success
1
LIMITING REACTANTS

Integrated School of Lawa Physical Science


Excellence Leads to Success
2
LIMITING REACTANTS

Integrated School of Lawa Physical Science


Excellence Leads to Success
3
LIMITING REACTANTS

Integrated School of Lawa Physical Science


Excellence Leads to Success
4
LIMITING REACTANTS
 When two substances are allowed to react,
one of them usually reacts completely, while
the other is not all used up because it is
present in excess.
 The reactant that is completely used up in
the reaction is the limiting reactant.
 Limiting reactant determines the
amount of products formed.
Integrated School of Lawa Physical Science
Excellence Leads to Success
5
EXCESS REACTANTS

 The other reactant that is not completely


consumed in the reaction

Integrated School of Lawa Physical Science


Excellence Leads to Success
6
 
Consider the reaction between aluminum and
chlorine

2 Al + 3 Cl
 It indicates that 2 mol of Al reacts with 3
mol of Cl.
 The mole ratio of Al to is 2:3

Integrated School of Lawa Physical Science


Excellence Leads to Success
7
 If the mole ratio is changed, one substance
 

will be completely consumed and the other


will have some left not reacted
3 Al + 3
Mole Reactants available : 3 mol Al 3 mol
Mole Reactants consumed : 2 mol Al 3 mol
 Mole Reactants not reacted : 1 mol Al 0 mol

Integrated School of Lawa Physical Science


Excellence Leads to Success
8
 In order to determine which reactants is
limiting, the amount of product from each of
the given amount of reactants is calculated.
 The reactant that gives the smaller yield is
the limiting reactant.

Integrated School of Lawa Physical Science


Excellence Leads to Success
9
 
Sample Problem
In an experiment, 5.00 g of aluminum is
heated with 25.0 g of sulfur to form aluminum
sulfide. The equation for the reaction is:
+
a. How many grams of aluminum sulfide will
be formed?
b. How many grams of excess reactant will
remain?
Integrated School of Lawa Physical Science
Excellence Leads to Success
10
 
Step 1 : Write the given facts and unknown
Given: mass Al = 5.00 g
mass S = 25.0 g
Unknown: a. mass
b. mass of excess reactant
Step 2: Balance the chemical equation

+
Integrated School of Lawa Physical Science
Excellence Leads to Success
11
Step 3
Identify the limiting reactant by calculating the
amount of product formed from each other of
the given amounts of reactants
a. Solve for the molar mass of the first reactant
b. Solve for the mole of first reactant
c. Solve for the mole of the product using mole of the first reactant
multiplied by the conversion factor of mole
number of the first reactant and the mole of the product
d. Solve for the molar mass of the second reactant
e. Solve for the mole of the product using the mole of the second
reactant multiplied by the conversion factor of the mole number of the
second reactant and the mole of the product
Integrated School of Lawa Physical Science
Excellence Leads to Success
12
 The other reactant that is not completely
consumed in the reaction

Integrated School of Lawa Physical Science


Excellence Leads to Success
13
PERCENT YIELD
Various factors can affect the amount of
product
1. The limiting reactant in a reaction may
not completely react
2. Some of the product may be lost during
the separation and purification processes
3. Other reactions, called side reactions,
may occur and use some of the limiting
reactants or the product
Integrated School of Lawa Physical Science
Excellence Leads to Success
14
PERCENT YIELD
 
The Percent Yield of the reaction relates the
actual yield to the theoretical yield.
Percent Yield = X 100%
 The actual yield is the amount of product formed from the
actual chemical reaction and usually less than theoretical yield.
 The theoretical yield is the amount of product formed from
the calculation of the complete reaction of the limiting reactant

Integrated School of Lawa Physical Science


Excellence Leads to Success
15
PERCENT YIELD
 Sample Problem
1. Wine is produced by the fermentation of fruit sugar
(fructose), to alcohol. The chemical reaction is:

O +

If 938 g of fructose was used in the preparation


of wine, what is the percent yield, if after the
fermentation, 327 g ethanol was produced?

Integrated School of Lawa Physical Science


Excellence Leads to Success
16
PERCENT YIELD
 Step 1
Write the given facts and unknown
Step 2
Determine the theoretical yield
a. Compute the molar mass of the first reactant from unbalanced equation
b. Convert the given mass of the first reactant to its moles

moles of the reactant =

c. calculate moles of the first product


c.1. From the balanced chemical equation, identify the mole
relationship of the first reactant and the first product
c.2. Compute the moles of the first product

moles of the first product = moles of the first reactant x conversion


factor (mole relationship)

Integrated School of Lawa Physical Science


Excellence Leads to Success
17
PERCENT YIELD
c.4. Calculate the theoretical yield
c.4.1. Solve for the molar mass of the first product
c.4.2. Solve for the mass of the theoretical yield by
multiplying moles of the first product with its molar mass
Step 3
Determine the actual yield

 
Percent Yield = X 100%

Integrated School of Lawa Physical Science


Excellence Leads to Success
18

You might also like