(Ethyl-Benzene Recovery) : Major Equipment Design
(Ethyl-Benzene Recovery) : Major Equipment Design
(Ethyl-Benzene Recovery) : Major Equipment Design
DISTILLATION COLUMN
(ETHYL-BENZENE RECOVERY)
Process Design
For calculation simplification let us assume the feed entering the distillation or E-B
recovery column in binary mixture.
Mol. Wt. of E-B = 106
Mol. Wt. of styrene = 104
i.e. xF = 0.267 ; xD = 0.495 ; xW = 0.049
CALCULATION FOR q :-
The benzene toluene tower is been operated under 160 mm Hg pressure. (from Dryden)
So the reboiler must be operated at an equilibrium temperature. Assuming the reboiler
acts as an ideal stage.
i.e. PT = x1*P1° + x2*P2°
where x1 and x2 are the mole fraction of styrene and EB recovery tower.
Hence, feed temperature calculated = 95.0°C
And T* = 63.138°C
VW = 36275 J/mol
(% -PRO
Now, in gaseous state2 Cp = 138.737 kJ/kmol°k(styrene)
At 70°C Cp = 151.745 kJ/kmol°k ( EB )
_
= 36698.19 kJ/kmol
_
Cp = 142.21 kJ/kmol°k
q = 0.876
So, slope of the q line = q/(q-1)
= -7.0645
So, from the graph reflux ratio is calculated.
Intercept: 0.13 = xD/(R+1)
Rmin = 2.81
Let, the reflux ratio be maintained 1.4 times the minimum,
i.e. R = 3.93
So, the conditions of the distillation column are specified.
ENRICHING SECTION
Tray spacing
ts = 500 mm
Hole diameter
dh = 10 mm.
Tray thickness
Tt = 0.6dh = 9 mm.
Active area
Aa = Ac – 2Ad = 12.34 m2.
Acz = 2 ( Lw x 0.2 ) = 1.35 m2.
. = 82.8° and = 97.2°
Awz = 0.635 m2.
Ap = Aa – Acz – Awz
= 10.355 m2.
Weir height
hw = 8 mm.
ρg
= k1 + k2 v 2h
ρ1
k1 = 0
k2 = 50.8/Cv2
Ah Tt
= 0.1 :
Aa d h = 0.5
From pg. 18-5 fig. 18-14 Perry
cv = 0.74 * ( Ah/Aa ) + exp (0.29 (Tt/Dh)-0.56)
= 1.03
k2 = 47.88
hd = 75.16 mm
how = Height of liquid crest formed
2
3
q
how = 664 * Fw where q = 16.5 x 10-03 m3/s.
Lw
Fw = 1.01
how = 19.31 mm
hσ = (409σ)/ ρ1dh = 1.452 mm.
hd + hσ = 76.612 mm.
hw + how = 27.32 mm.
Ah/Aa = 0.1
From Perry fig. 18-11 pg. 18-7
hd + hσ > graphical value.
∴ weeping does not occur.
q
hda = 162.5
Ada
hap = hds – c
c= 14 mm.
hap = 13 mm.
Ada = Lwhap = 0.04387 m2
hda = 23.42 mm.
Column efficiency
Eog Æ Emv Æ E oc
Eog = 1 – exp( - Nog)
1
N og =
1 λ
+
Ng Nl
where, P*P/P
(
k1a = 3.875 × 10 D1
8
) (0.40Uaρ
0.5 0.5
g + 0.17 )
= 1.434 m/s [Dl= 3.08*109 m/s]
Residence time
θ1 = (1-ε)*hf*Aa/1000q
= 20.23 s
∴, Nl =29.017 m
In Enriching section
mL
λ top =
G top
= 2.041
The very high value of Emv (over 1 )suggest there is high liquid entrapment takes place
under such high vacuum. While the previous calculation suggest the liquid hold up
and point efficiency, under such situation for safe design we made an assumption, i.e.,
Eog ≈ Emv .
∴, Emv= 0.998
now,
Ea 1
=
Emv 1+ Emv*[ψ /(1-ψ)]
log{1 + E a (λ − 1)}
Eoc =
log λ
Eoc = 0.80
Ideal no. of trays
Again, by definition Eoc =
Stripping section
Tray spacing
ts = 500 mm
Hole diameter
dh = 15 mm.
Tray thickness
Tt = 0.6dh = 9 mm.
Plate diameter
Active area
Aa = Ac – 2Ad = 13.174 m2.
Acz = 2 ( Lw x 0.25 ) = 1.86 m2.
. = 82.8° and = 97.2°
Awz = 0.66 m2.
Ap = Aa – Acz – Awz
= 10.654 m2.
Total hole area
( Ah/Ap) = 0.1
Ah = 1.0654 m2.
No. of holes = 13565
Weir height
hw = 6 mm.
ρg
= k1 + k2 v 2h
ρ1
k1 = 0
k2 = 50.8/Cv2
Ah Tt
= 0.1 : = 0.5
Aa dh
From pg. 18-5 fig. 18-14 Perry
cv = 0.74 * ( Ah/Aa ) + exp (0.29 (Tt/Dh)-0.56)
= 1.03
k2 = 47.85
hd = 55.32 mm
how = Height of liquid crest formed
2
3
q
how = 664 * Fw where q = 23.8 x 10-03 m3/s.
Lw
Fw = 1.01
how = 24.12 mm
hσ = (409σ)/ ρ1dh = 1.5 mm.
hd + hσ = 56.82 mm.
hw + how = 30.12 mm.
Ah/Aa = 0.1
From Perry fig. 18-11 pg. 18-7
hd + hσ > graphical value.
∴ weeping does not occur.
1000fu f2 L f
hhg =
grh
h f Df
rh =
h f + Df
again f is a function of Reynold’s number.
Where,
rh u f ρ1
Nreh. =
µ1
Where,
1000q
uf =
h 1D f
.Df = (Dc+Lw)/2 = 4.07 m
Fga = Ua(ρg)0.5
hf = hl / 3 = 148.0 mm.
3= exp(-12.55 Ks0.91)
Ks= Ua>!g/(!l-!g)]0.5
=0.0869 [Ua= gas vel. Through active area= 5.70 m/s]
Hence,3=0.2567
And
hl 3>Kw
&
T32/3]
where, C = 0.0327+ 0.0286*exp[-0.1378*hw]
= 0.0327+ 0.0286*exp[-0.1378*6]
= 0.04521
hl = 37.38 mm of clear liquid
Uf = 0.1539 m/s
Rh = 0.1379 m
l = [Σxi
i1/3]3
= 0.482 cp
Nreh. = 37534
From PERRY fig 14.34( 7th ed)
f= 0.02
Lf = 3.057 m
hhg= 1.1 mm of clear liq
hds = 30.67 mm
ht = 65.72 mm clear liq
q
hda = 162.5
Ada
hap = 14 mm.
Ada = Lwhap = 0.04886 m2
hda = 39.2 mm.
Column efficiency
Eog Æ Emv Æ E oc
Eog = 1 – exp( - Nog)
1
N og =
1 λ
+
Ng Nl
where, P*P/P
(
Kla = 3.875 × 10 8 D1 ) (0.40Uaρ
0.5 0.5
g + 0.17 )
= 1.314 m/s [Dl= 3.1624*10-9 m/s]
Residence time
θl = (1-ε)*hf*Aa/1000q
= 21.02 s
∴, Nl = 27.62 m
mL
λ top =
G top
The condenser to be designed over here is been placed after the reactor in the process.
The stream coming out of the reactor contains steam as well as some non-condensable
gases (like hydrogen) and organic vapors.
The gas out of the reactor is passed through the vaporizer where the gas temperature falls
from 600 to 454oC. Even at this temperature, the load on the condenser is very high, so to
make the process more economical a boiler is positioned in between the vaporizer and
condenser in order to recover the waste heat from the flue gas stream.
Therefore, after the super heat recovery the stream is entering the reactor at its normal
boiling point temperature. The condenser is operated under atmospheric pressure. Hence,
the normal boiling point of the mixture is calculated 90oC.
To perform the given operation the load is very high for a single condenser, so to avoid
overloading of the condenser two condenser of identical performance are put in series.
condenser
• Hot condensing gases enters at 100oC temperature and leaves at 90oC (I.e.,
effective boiling condensing gases)
• Cold fluid enters at 25oC and leaves at 40oC.
INITIAL CALCULATION:
Average latent heat of condensation of the condensing vapor = 1299.24 kJ/kg
Total mass of the condensing vapour feed into each condenser=9.27 kg/s.
Specific heat of water at 300C =4.184 kJ/kg
Mass of process water required=
9.27*1299.24/(4.184*(45-25)) kg/s.
= 190.68 kg/s
FILM COEFFICIENT
Shell side - Condensate
The heat transfer coefficient for the shell side given as:
hs = 1.51*[k3*ρ2*g/µ2]1/3 *Nre-1/3
Reynolds number ( NRe )= 4*Γ/µ
Where, Γ= W/(N1/3*L)
W= condensation rate
N= total no of tubes
L= length of each tubes
∴, Γ= 0.02062
Again, µ= 0.347 cp
N.B., all the properties been evaluated at the condensate average temperature.i.e, at
75.62oC.
Therefore, the Reynolds no is calculated= 237.72
Properties are evaluated at 75.62oC.
K = Thermal conductivity = 0.398 w/m.K.
µ = Viscosity = 0.347 x 10-3 cp.
ρ = Density = 892 kg/m3.
hs= 3897 W/m2.K.
TUBE SIDE
Nre= v*ρ*d/µ
ρ = 994 kg/m3
Therefore, velocity of the fluid on the tube side=1.948 m/s
diameter of each tube= 13.51 mm
Reynold’s number (NRe) = 33438
k = 0.61 W/mK
µ = 0.78 cp
cp = 4.184 KJ/kgK
Prandtl number (NPr) = 5.35
For turbulent condition Dittus Bolter equation.
hide
= 0.023 (NRe )0.8 ( NPr )0.33 ( φ )0.14
k
φ = µl/µw
hi = 5996 W/m2K
∴, Ud > Ucorrected
∴ Design is okay.
PRESSURE DROP CALCULATION
SHELL SIDE
2f ( N b + 1)D s G s
∆Ps = x 0.5 = 1.369 kPa.(KERN’s method)
gρ g d e
since the shell side pressure drop is less than 14 kPa , the design is satisfactory.
TUBE SIDE
NRe = 33438
F = 0.0791 ( NRe )-1/4 = 0.00584
∆Pl = 4*f*L*v2*ρl/2di = 11.82 kPa
∆Pe = 2.5*v2*ρl/2 = 4.700kPa
∆PTotal = 2*(∆Pl + ∆Pe )= 33.04 kPa.
which is very less than permissible value(70 kPa), therefore design is satisfies all the
necessary condition.
MECHANICAL DESIGN OF
DISTILLATION COLUMN
(REF: BROWNELL & YOUNG,CH:10)
a) SPECIFICATION:
1. inside diameter : 4.65 m ( design with the maximum dia for safety)
2. height of disengaging section: 40 cm
3. design pressure: 50 mmHg
4. (since the vessel operated under vacuum, subjected to external
pressure)external pressure: 0.965 kgf/cm2
5. design pressure: 1.033 kgf/cm2
6. design temperature: 70oC
7. shell material: carbon steel(sp. Gr.=7.7) (IS:2002-1962, GRADE I)
8. permissible tensile stress: 950 kgf/cm2
9. insulation material: asbestos
10. density of insulation: 2700 kg/m3
11. insulation thickness: 50 mm
12. tray spacing: 500 mm
13. down comer plate material: stainless steel(sp. Gr.: 7.8)
SHELL THICKNESS CALCULATION:
∴, Do = 4.67 m
L = 0.5 m
∴, L/Do = 0.11
&, Do/t = 467 ∴, B= 12000
∴, pallowable= B/( 14.22*( Do/t)), t= 5.71 mm ≈ 6 mm
Which, suggest the thickness is allowable under the operating condition.
Therefore, allowing corrosion correction, thickness choose= 12 mm
HEAD:
i) Dead wt calculation:
Further, the wt of the insulation and shell also exerts a compressive stress:
π*di*X*t*ρs + π/4*(D0,ins2 – d02)*X*ρins = 3126.8X kg
Where, deff= effective outer diameter of the vessel including insulation= 4.77 m
Therefore the force balance at the bottom of the tower gives: ft,max=( fwb or fsb) - fdb
(upwind side)
since, fwb > fsb , for safe design we will consider fwb in consideration.
η= ES/EC
where, Es= modulus of steel
Ec= modulus of concrete
Let, η= 10.
∴, let, fs= 20000 psi
fc= 1200 psi (from table: 10.1, BROWNELL & YOUNG)
1
∴, k= = 0.375
1 + fs/(η fc)
Where, d= 184 in
fc,bolt= 1104 psi
∴,k= 0.2036
thus iterating with new values finally we get,
k= 0.269
Cc= 1.340
Ct= 2.571
Z= 0.450
J= 0.778
∴, the max compressive stress in bolt & concrete
fs,compression= η*fc = 305.8 psi
Where, fc,max induced= 34.286 psi
This is a safe value.
⇒ t4 = l*√( 3*fc,max/fallowable) = 1 in
SHELL SIDE:
MATERIAL :
Carbon steel (corrosion allowance= 3 mm)
Permissible strength for carbon steel= 95 N/mm2
Number of shell= 1
Number of tube passes= 2
Condensing fluid type: Mixed vapor
Working pressure= 1 atm
= 0.101 N/mm2
Design pressure= 0.11 N/mm2
Temperature of inlet= 1000C
Temperature of outlet= 900C
Design temperature= 950C
TUBE SIDE:
Number of tubes= 1378
Out side diameter= 19.05 mm
Inside diameter= 13.51 mm
Length of each pipe= 3.63 m
Pitch ∆lar = 1”
Feed= water
Working pressure= 1 atm
Design pressure= 0.11 N/mm2
Inlet temperature= 250C
Outlet temperature= 400C
SINCE THERE IS NO BAFFLE IS USED TIE RODS AND SPACERS ARE NOT
REQUIRED.
FLANGES:
Loose type except lap joint flange is designed.
Design pressure= 10N/mm2
Flange material: IS:2004-1962 class2
Bolting steel= 5% Cr Mo steel
Gasket material= asbestos composition
Shell inside diameter=1067 mm
Shell thickness =10 mm
Shell outside diameter= 1087 mm
∴, Mo = 4.18* 10-4 MJ
Mg =W*a3
Where, W=(Am + Ab)*Sg/2 = (5.308*10-3)*Sg =0.732 Nm
∴, Mg =0.0205 MJ
since, Mg>Mo , Mg is the moment under operating condition.
t2 = M*Cf*Y/(B*ST)
Where, K= A/B =1.103
∴, Y=17
Let, CF =1 (bolt pitch correction factor)
CHANNEL DESIGN
Channel thickness:
Tc= GC (k*p/f)0.5 = 21 mm (k= 0.3 for ring type gasket)
Covers are assumed flat and welded to channel.
SUPPORT DESIGN
Material low carbon steel
Saddle type of support is designed.
Length= 3.63 m
Vessel diameter= 1.067 m
Knuckle radius= 64.02 mm
Total head depth = √(Do*r0/2)
= 185 mm
∴, A= 0.5*R = 267 mm
Maximum weight of shell, attachments and contents = 25543 kg.
A = 0.267 m
L = 3.36 m
H=0
R = 0.5335 m
Q = W/2*( L + 4/3*H)= 49510.84 kg-m.
R = 0.5335 m
t = 0.010 m
M2
f2 = = 0.3849 kg/cm2.
πR t
2