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    Chem 31 Probset First Exam

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    Nat Dabuét
    This document contains 8 chemistry problems involving the identification of hybridization states, resonance structures, relative stability of conformers, naming of stereoisomers using R/S and E/Z notation, and classification of isomers. The problems cover topics such as Lewis structures, VSEPR theory, resonance, conformational analysis, stereochemistry and isomerism.

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    Chem 31 Probset First Exam

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    Nat Dabuét
    364 views2 pages
    This document contains 8 chemistry problems involving the identification of hybridization states, resonance structures, relative stability of conformers, naming of stereoisomers using R/S and E/Z notation, and classification of isomers. The problems cover topics such as Lewis structures, VSEPR theory, resonance, conformational analysis, stereochemistry and isomerism.

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    Chem 31 probset, 1st exam AY 2013-2014

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    Chem 31 Probset first exam

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    This document contains 8 chemistry problems involving the identification of hybridization states, resonance structures, relative stability of conformers, naming of stereoisomers using R/S and E/Z notation, and classification of isomers. The problems cover topics such as Lewis structures, VSEPR theory, resonance, conformational analysis, stereochemistry and isomerism.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    364 views2 pages

    Chem 31 Probset First Exam

    Uploaded by

    Nat Dabuét
    This document contains 8 chemistry problems involving the identification of hybridization states, resonance structures, relative stability of conformers, naming of stereoisomers using R/S and E/Z notation, and classification of isomers. The problems cover topics such as Lewis structures, VSEPR theory, resonance, conformational analysis, stereochemistry and isomerism.

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    of 2

    CHEM 31 PROBLEM SET 1 1.

    For the following molecule: H H H N C 6 8 C N 4 C H 1 C N 7 2 H 5 O


    3

    a) Identify the hybridization of each numbered atom. b) Identify the orbital location of each lone pair of atoms 1, 3, 5 and 6. c) Which N is in plane with C-4? 2. For the following molecule: H H N

    H N

    C C

    C C

    H H O a) Draw all acceptable resonance structures. b) Draw the hybrid structure. c) Identify the most and least stable resonance structure.
    3. For the following pairs of molecules: H H H O C S H C C C 2 H 1 1 H O H H O 2 a) or H H H H H H C C H H C C H Cl C C 1 1 Cl H H H 2 2 H H b) or H H H H H H C H C C H C H H C H C C H H C H 1 H C C C 1 H 2 H C H 2 H C C H H H c) or A) Identify which molecule is more polar. B) Identify which molecule is longer. C) Identify which molecule has greater bond strength. 4. Predict the indicated bond angle (either very close to, less than or greater than a certain ) + a) the C-N-C bond angle in (CH3)2NH2 b) the C-O-C bond angle in CH3OCH3 c) the C-C-N bond angle in CH3CN

    5. Draw all possible conformations of isobutyl chloride using Newman Projection and identify the most stable and least stable conformer. 6. Draw the most stable chair conformer of glucose O H H

    H H H H H O O C C C H C

    C H O C H O O H

    H 7. Name the following compounds using the R,S or E,Z designations where necessary:

    a)

    b)

    c) 8. Indicate whether each of the following pairs of compounds are identical or are enantiomers, diastereomers or constitutional isomers

    a)

    b)

    c)

    d)

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