Schottky defect

Not to be confused with Schottky effect.

A Schottky defect is an excitation of the site occupations in a crystal lattice leading to point defects named after Walter H. Schottky. In ionic crystals, this defect forms when oppositely charged ions leave their lattice sites and become incorporated for instance at the surface, creating oppositely charged vacancies. These vacancies are formed in stoichiometric units, to maintain an overall neutral charge in the ionic solid.

Definition

Schottky defects consist of unoccupied anion and cation sites in a stoichiometric ratio. For a simple ionic crystal of type A⁻B⁺, a Schottky defect consists of a single anion vacancy (A) and a single cation vacancy (B), or v^•
_A + v^{⁠$\prime$⁠}
_B following Kröger–Vink notation. For a more general crystal with formula A_xB_y, a Schottky cluster is formed of x vacancies of A and y vacancies of B, thus the overall stoichiometry and charge neutrality are conserved. Conceptually, a Schottky defect is generated if the crystal is expanded by one unit cell, whose a prior empty sites are filled by atoms that diffused out of the interior, thus creating vacancies in the crystal.

Schottky defects are observed most frequently when there is a small difference in size between the cations and anions that make up a material.

Illustration

Chemical equations in Kröger–Vink notation for the formation of Schottky defects in TiO₂ and BaTiO₃.

∅ ⇌ v^{⁠$\prime \prime \prime \prime$⁠}
_Ti + 2 v^••
_O

∅ ⇌ v^{⁠$\prime \prime$⁠}
_Ba + v^{⁠$\prime \prime \prime \prime$⁠}
_Ti + 3 v^••
_O

This can be illustrated schematically with a two-dimensional diagram of a sodium chloride crystal lattice:

The defect-free NaCl structure

Schottky defects within the NaCl structure

Bound and dilute defects

Three bound configurations of Schottky defects in an oxide with Fluorite structure. Spheres represent atoms, cubes represent vacancies.

The vacancies that make up the Schottky defects have opposite charge, thus they experience a mutually attractive Coulomb force. At low temperature, they may form bound clusters. The degree at which the Schottky defect affects the lattice is dependent on temperature where the higher temperatures around a cation vacancy multiple anion vacancies can also be observed. When there are anion vacancies located near a cation vacancy this will hinder the displacement of cation energy.

The bound clusters are typically less mobile than the dilute counterparts, as multiple species need to move in a concerted motion for the whole cluster to migrate. This has important implications for numerous functional ceramics used in a wide range of applications, including ion conductors, Solid oxide fuel cells and nuclear fuel.

Examples

This type of defect is typically observed in highly ionic compounds, highly coordinated compounds, and where there is only a small difference in sizes of cations and anions of which the compound lattice is composed. Typical salts where Schottky disorder is observed are NaCl, KCl, KBr, CsCl and AgBr. For engineering applications, Schottky defects are important in oxides with Fluorite structure, such as CeO₂, cubic ZrO₂, UO₂, ThO₂ and PuO₂.

Effect on density

Typically, the formation volume of a vacancy is positive: the lattice contraction due to the strains around the defect does not make up for the expansion of the crystal due to the additional number of sites. Thus, the density of the solid crystal is less than the theoretical density of the material.

See also

• Frenkel defect
• Wigner effect
• Crystallographic defects

References

• Kittel, Charles (2005). Introduction to Solid State Physics (8th ed.). Wiley. pp. 585–588. ISBN 978-0-471-41526-8.
• Kovalenko, M.A, and A. Ya Kupryazhkin. “States of the Schottky Defect in Uranium Dioxide and Other Fluorite Type Crystals: Molecular Dynamics Study.” Journal of Alloys and Compounds, vol. 645, no. 0925-8388, 1 Oct. 2015, pp. 405–413, https://doi.org/10.1016/j.jallcom.2015.05.111. Accessed 30 Apr. 2024.