No.
Portrait
Governor
From
Until
Monarch
1
Antonio de Mendoza
14 November 1535
25 November 1550
Charles I
2
Luís de Velasco
25 November 1550
31 July 1564
3
Gastón Carrillo de Peralta y Bosquete , 3rd Marquess of Falces
19 October 1566
11 November 1567
Philip II
4
Martín Enríquez de Almanza
5 November 1568
4 October 1580
5
Lorenzo Suárez de Mendoza , 4th Count of La Coruña
4 October 1580
19 June 1583
6
Pedro de Moya y Contrerás (Archbishop of Mexico )
25 September 1584
17 October 1585
7
Álvaro Manrique de Zúñiga 1st Marquess of Villamanrique
17 October 1585
27 January 1590
8
Luís de Velasco Marquess of Salinas
27 January 1590
5 November 1595
9
Gaspar de Zúñiga Acevedo y Fonseca , 5th Count of Monterrey
5 November 1595
27 October 1603
10
Juan de Mendoza y Luna , Marquess of Montesclaros
27 October 1603
2 July 1607
Philip III
11
Luís de Velasco , Marquess of Salinas
2 July 1607
19 June 1611
12
García Guerra , O.P. (Archbishop of Mexico )
19 June 1611
22 February 1612
Int.
Pedro Otárola , Dean of the Audiencia
22 February 1612
18 October 1612
13
Diego Fernández de Córdoba , Marquess of Guadalcázar and Count of Posadas
18 October 1612
14 March 1621
Int.
Paz de Valecillo , Dean of the Audiencia
14 March 1621
11 September 1621
14
Diego Carrillo de Mendoza y Pimentel , 1st Marquess of Gélves
21 September 1621
1 November 1624
Philip IV
Vacant Due to the discrepancy on the arrival of successor Viceroy from 1 to 3 November 1624.
15
Rodrigo Pacheco y Osorio de Toledo , 3rd Marquess of Cerralvo
3 November 1624
16 September 1635
16
Lope Díez de Aux de Armendáriz , Marquess of Cadreita
16 September 1635
28 August 1640
17
Diego Roque López Pacheco Cabrera y Bobadilla , 7th Duke of Escalona, 7th Marquess of Villena and 7th Count of Xiquena
28 August 1640
10 June 1642
18
Juan de Palafox y Mendoza (Bishop of Puebla )
10 June 1642
23 November 1642
19
García Sarmiento de Sotomayor , 2nd Count of Salvatierra and Marquess of Sobroso
23 November 1642
14 May 1648
20
Marcos de Torres y Rueda (Bishop of Yucatan )
15 May 1648
22 April 1649
Int.
Matías de Peralta , Dean of the Audiencia
22 April 1649
28 June 1650
21
Luis Enríquez de Guzmán , 9th Count of Alba de Liste and Marquess of Villaflor
28 June 1650
15 August 1653
22
Francisco Fernández de la Cueva, 8th Duke of Alburquerque, Marquess of Cuéllar, Count of Ledesma and of Huelma
15 August 1653
16 September 1660
23
Juan de Leyva de la Cerda , Marquess of Adrada
16 September 1660
29 June 1664
24
Diego Osorio de Escobar y Llamas (Bishop of Puebla )
29 June 1664
15 October 1664
25
Antonio Sebastián de Toledo Molina y Salazar , 2nd Marquess of Mancera
16 October 1664
20 November 1673
26
Pedro Nuño Colón de Portugal y Castro , 6th Duke of Veragua, 6th Marquess of Jamaica and 6th Count of Gelves
20 November 1673
13 December 1673
Charles II
27
Payo Enríquez de Rivera Manrique , O.S.A. (Bishop of Guatemala and Archbishop of Mexico )
13 December 1673
7 November 1680
28
Tomás Antonio Manuel Lorenzo de la Cerda y Aragón 3rd Marquess of La Laguna de Camero Viejo
7 November 1680
16 June 1686
29
Melchor Portocarrero y Lasso de la Vega , 3rd Count of Monclova
16 June 1686
20 November 1688
30
Gaspar Melchor Baltasar de la Cerda Silva Sandoval y Mendoza , 8th Count of Galve, Lord of Salcedón and Tortola
20 November 1688
27 February 1696
31
Juan de Ortega Cano Montañez y Patiño (Bishop of Durango , Guatemala , Michoacán and Archbishop of Mexico )
27 February 1696
18 December 1696
32
José Sarmiento Valladares Arines de Romay , 1st Duke of Atrisco, Count of Moctezuma and of Tula
18 December 1696
4 November 1701
33
Juan de Ortega Cano Montañez y Patiño (Archbishop of Mexico )
4 November 1701
27 November 1702
Philip V
34
Francisco V Fernández de la Cueva Enríquez y Fernández de la Cueva , 10th Duke of Alburquerque and Marquess of Cuéllar
27 November 1702
13 November 1710
35
Fernando de Alencastre Noroña y Silva , 1st Duke of Linares and Marquess of Valdefuentes
13 November 1710
16 July 1716
36
Baltasar de Zúñiga Guzmán Sotomayor y Mendoza , 1st Duke of Arión and Marquess of Valero
16 July 1716
15 October 1722
37
Juan de Acuña y Bejarano , 2nd Marquess of Casa Fuerte
15 October 1722
17 March 1734
Louis I From 1700 to 1724, Philip V was the king; then from 1724 to 1746. Louis I only reigned in 1724.
38
Juan Antonio de Vizarrón y Eguiarreta (Archbishop of Mexico )
17 March 1734
17 August 1740
Philip V
39
Pedro de Castro Figueroa y Salazar , 1st Duke of La Conquista and 1st Marquess of Gracia Real
17 August 1740
22 August 1741
Int.
Pedro Malo de Villavicencio , President of the Audiencia
23 August 1741
2 November 1742
40
Pedro Cebrián y Agustín , 5th Count of Fuenclara
3 November 1742
9 July 1746
41
Juan Francisco de Güemes y Horcasitas , 1st Count of Revillagigedo
9 July 1746
9 November 1755
Ferdinand VI
42
Agustín de Ahumada y Villalón , Marquess of Amarillas
10 November 1755
5 February 1760
Int.
Francisco Antonio de Echávarri , Dean of the Audiencia
5 February 1760
28 April 1760
43
Francisco Cajigal de la Vega
28 April 1760
5 October 1760
Charles III
44
Joaquín de Montserrat , Marquess of Cruillas
5 October 1760
24 August 1766
45
Carlos Francisco de Croix, Marquess of Croix
24 August 1766
22 September 1771
46
Antonio María de Bucareli y Ursúa
22 September 1771
9 April 1779
Int.
Francisco Romá y Rosell , Regent of the Audiencia
10 April 1779
22 August 1779
47
Martín de Mayorga Ferrer ,Captain General of Guatemala
23 August 1779
28 April 1783
48
Matías de Gálvez y Gallardo ,Captain General of Guatemala
28 April 1783
20 October 1784
Int.
Vicente de Herrera y Rivero , Regent of the Audiencia
20 October 1784
17 June 1785
49
Bernardo de Gálvez y Madrid , 1st Viscount of Galveston and 1st Count of Gálvez
17 June 1785
30 November 1786
Int.
Eusebio Sánchez Pareja y Beleño Regent of the Audiencia
30 November 1786
8 May 1787
50
Alonso Núñez de Haro y Peralta (Archbishop of Mexico )
8 May 1787
16 August 1787
51
Manuel Antonio Flórez Maldonado
16 August 1787
16 October 1789
52
Juan Vicente de Güemes Pacheco de Padilla y Horcasitas , 2nd Count of Revillagigedo
17 October 1789
11 July 1794
Charles IV
53
Miguel de la Grúa Talamanca de Carini y Branciforte , 1st Marquess of Branciforte
12 July 1794
31 May 1798
54
Miguel José de Azanza Alegría , 1st Duke of Santa Fe
31 May 1798
30 April 1800
55
Félix Berenguer de Marquina
30 April 1800
4 January 1803
56
José de Iturrigaray
4 January 1803
16 September 1808
57
Pedro de Garibay
16 September 1808
19 July 1809
Joseph I
58
Francisco Javier de Lizana y Beaumont (Archbishop of Mexico )
19 July 1809
8 May 1810
Ferdinand VII
59
Pedro Catani
8 May 1810
14 September 1810
60
Francisco Javier Venegas , 1st Marquess of Reunión and of New Spain
14 September 1810
4 March 1813
61
Félix María Calleja del Rey , 1st Count of Calderón
4 March 1813
20 September 1816
62
Juan Ruiz de Apodaca , 1st Count of Venadito
20 September 1816
5 July 1821
63
Francisco Novella Azabal Pérez y Sicardo
15 July 1821
21 July 1821
64
Juan O'Donojú
21 July 1821
28 September 1821