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    H NMR Problems: - How Many Unique Proton Environments Are There in

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    Fatima Ahmed
    The document discusses 1H NMR problems involving predicting the number of unique proton environments and splitting patterns in various organic molecules. It provides examples of molecules with different numbers of proton environments, from 2 to 7 environments. It also gives examples of predicting singlet, doublet, triplet, quartet, quintet and septet splitting patterns for protons in different chemical environments.

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    H NMR Problems: - How Many Unique Proton Environments Are There in

    Uploaded by

    Fatima Ahmed
    136 views26 pages
    The document discusses 1H NMR problems involving predicting the number of unique proton environments and splitting patterns in various organic molecules. It provides examples of molecules with different numbers of proton environments, from 2 to 7 environments. It also gives examples of predicting singlet, doublet, triplet, quartet, quintet and septet splitting patterns for protons in different chemical environments.

    Original Title

    Proton NMR_problems

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    The document discusses 1H NMR problems involving predicting the number of unique proton environments and splitting patterns in various organic molecules. It provides examples of molecules with different numbers of proton environments, from 2 to 7 environments. It also gives examples of predicting singlet, doublet, triplet, quartet, quintet and septet splitting patterns for protons in different chemical environments.

    Copyright:

    © All Rights Reserved
    Download as PPT, PDF, TXT or read online from Scribd
    Download as ppt, pdf, or txt
    136 views26 pages

    H NMR Problems: - How Many Unique Proton Environments Are There in

    Uploaded by

    Fatima Ahmed
    The document discusses 1H NMR problems involving predicting the number of unique proton environments and splitting patterns in various organic molecules. It provides examples of molecules with different numbers of proton environments, from 2 to 7 environments. It also gives examples of predicting singlet, doublet, triplet, quartet, quintet and septet splitting patterns for protons in different chemical environments.

    Copyright:

    © All Rights Reserved
    Download as PPT, PDF, TXT or read online from Scribd
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    1

    H NMR Problems
    • How many unique proton environments are there in:

    CH3CH2Br CH3CH2Br 2 environments

    CH3 CH3
    CH3OCH2CH2CHCH3 CH3OCH2CH2CHCH3 5 environments

    CH3 CH3 CH3


    H C H
    C C
    4 environments
    C C
    H C H
    H
    H NMR Problems
    1

    CH3 CH3 CH3 CH3


    C C C C
    CH3 H CH3 H

    4 environments

    CH3CH2 CH2CH3 CH3CH2 CH2CH3


    C C C C
    H H H H

    3 environments

    Symmetry Simplifies Spectra!!!


    O
    CH3CCH3
    OCH3 CH3

    O
    CH3COCH3
    1
    H NMR Problems
    • Predict the splitting patterns (multiplets) for each proton
    environment in the following:
    singlet

    singlet
    CH3CHBr2
    doublet

    doublet

    CH3OCH2CH2Br triplet

    triplet

    triplet
    ClCH2CH2CH2Cl
    triplet

    quartet
    O CH3 quartet
    CH3CH2COCHCH3
    quintet

    septet
    CH3

    CH3
    O
    CH3COCH2CH3 OCH2

    CH3
    (2H) (3H) (3H)
    CH3

    OCH2
    CH3 CH3

    O
    OCH2 CH2
    CH3CH2COCH2CH3

    CH3 CH3

    OCH2 CH2
    .
    ethyl C6H12O2
    butanoate

    O CH3 CH3

    CH3CH2CH2COCH2CH3

    CH2
    OCH2

    CH2
    CH3

    CH3

    O
    CH3CCH2CH3 CH2

    CH3

    CH3

    CH2
    CH3

    H H
    O
    H
    H
    CH3C H

    H
    H H

    CH3

    H
    C H
    C C
    H H C C
    H C H
    H
    H
    CH3
    CH3CH2CH2OH

    CH2

    CH2 O
    OH

    CH3

    CH2

    CH2 O
    OH
    CH3

    CH2
    CH3CH2CH2CH2OH CH2 O
    CH2

    OH

    CH3

    CH2 O CH2
    CH2
    OH
    CH2
    and CH3
    CH2
    CH3CH2CH2CH2CH2OH CH2 O

    CH2

    OH

    CH2 CH3
    and
    CH2
    CH2 O

    CH2
    OH
    CH3

    CH3
    H
    H
    H
    H
    H
    H H H other Hs

    CH3

    HH other Hs
    H
    CH3

    CH2
    CH3CH2CH2Br
    CH2

    CH3

    CH2

    CH2
    H2C=C=CHCH2CH2OH
    CO2H
    H3C O
    N CCH3
    H 3C
    O
    H3C NHCCH3
    C C

    HC H
    O

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