6

REDOX TITRATION AND

ITS APPLICATION

REDOX TITRATION
Permanganometry
Dichromatometry
Cerimetry
Iodo-iodimetry
Bromatometry

Permanganometry
Permanganometry: redox titration on

using KMnO4 as a titrant.
Potassium permanganate:
*) strong oxidator
*) can easily find, cheap
*) no need indicator to observe
end point.
*) purple color
*) can be oxidized by light
use of KMnO4 in daily life:
anti bacteria (PK)
Oxidation number of Manganese:

+2, +3+, +4, +6, dan +7.
MnO4- + e- MnO42MnO4- + 4H+ + 3e- MnO2 + 2H2O
MnO4- + 8H+ + 4e- Mn3+ + 4H2O
MnO4- + 8H+ + 5e- Mn2+ + 4H2O
Common reaction in lab:

MnO4- + 8H+ + 5e- Mn2+ + 4H2O
Acid can be used: dilute H2SO4
reaction need to be heat and catalyst
Standard primary for KMnO4:

1. Arsen (III) Oksida, As2O3
2. Sodium Oxalic Na2C2O4
REACTIONS:
5 C2O42- + 2 MnO4- + 16 H+ 2 Mn2+
+ 10 CO2+ 8H2O
5 HAsO2 + 2 MnO4- + 6 H+ + 2 H2O

2 Mn2+ + 5 H3AsO4
The use of Permanganometry:

a. Determination of Iron in minerals : solve
the minerals in acid (HCl), ttrate with
permanganate
5Fe2+ + MnO4- + 8H+ -- 5Fe3+ + Mn2+ +
4H2O
b. Determination of Hydrogen peroxyde
2 MnO4- + 5 H2O2 + 6 H+ 2 Mn2+ + 5
O2(g) + 8 H2O
Hydrogen peroxyde in daily life: ear drops
medicine (3%)
Standarisasi larutan permanganat
Larutan kalium permanganat bukan

larutan standar primer karena sukar
mendapatkan yang murni, selain itu
sifatnya mudah terurai oleh cahaya, suhu
tinggi, asam/basa dan zat organik
Larutan permanganat dapat
distandarisasi antara lain dengan:
Arsen (III) Oksida
Natrium Oksalat
Exercise-1
Iron (II) is titrated with potassium

permanganate 0,0206 M, in acid
media. It is used 40,20 mL of KMnO4
solution to react with. Determine mg
of iron in the solution.
Solution:
In acid solution:
MnO4- + 8H+ + 5e - Mn2+ + 4H2O X1
Fe2+ --
Fe3+ + e
X5
MnO4- + 8H+ + 5Fe2+- Mn2+ + 4H2O + 5Fe3+
In equivalent point:
Mol KMnO4
= M.V
Mol KMnO4
= M.V
= 0,0206 M x 40,2 mL
= 0,828 mmol
5 mol Fe 1 mol KMnO4
mol Fe yang diperlukan = 5 x 0,828 mmol
= 4,14 mmol
Fe needed:
= 4,14 mmol Ar.Fe.
= 231,8 mgram
Exercise - 2
0,2121 gram sampel natrium oksalat
murni dititrasi dengan 43,31 ml
kalium permanganat. Hitunglah
normalitas kalium permanganat
Dichromatometry
Dichromate as strong oxidator

(but less than permanganate)
Ion dichromate is reduced into
Cr3+ ion (green color).
Cheap, easily found in pure grade
Cr2O72- + 14H+ + 6e- 2Cr3+ +

7H2O
Application
Determine Fe(II) in acidic (HCl)

media.
Write the complete reaction
TITRATION WITH IODIUM
Iodimetri (cara langsung)
adalah titrasi yang dilakukan

langsung dengan larutan standar
iodium sebagai pengoksid, dilakukan
dalam suasana netral atau sedikit
asam.
Beberapa Penggunaan Iodimetri
Some reactions
Arsen (III)
HAsO2 + I2 + 2H2O - H3AsO4 + 2H+ + 2IFerosianida
2Fe(CN)64- + I22Fe(CN)63- + 2IBelerang (sulfida)
H2S + I2 - 2H+ + 2I- + S
Belerang (sulfit)
H2SO3 + I2 + H2O - H2SO4 + 2H+ + 2ITiosulfat
2S2O32- + I2 - S4O62- + 2I-
Some reactions:
Bromate
BrO3- + 6H+ + 6I- - Br- + 3I2 + 3H2O
Klorine
CI2 + 2I- - 2CI- + I2
copper (II)
2Cu2+ + 4I-- 2CuI(s) + I2
Dichromate
Cr2O72- + 6I- + 14H+ 2Cr3+ + 3I2 + 7H2O
Hydrogen peroxyde
H2O2 + 2H+ + 2I- I2 + 2H2O
Natrium tiosulfat umumnya dibeli sebagai pentrahidrat.

Na2S2O3.5H2O, dan larutan-larutannya distandarisasi oleh
standar primer.
Larutan tiosulfat tidak stabil pada jangka waktu yang lama,
sehingga boraks atau natrium karbonat seringkali
ditambahkan sebagai bahan pengawet. Selain itu larutan ini
sifatnya tidak stabil terhadap oksidasi dari udara, asam dan
adanya bakteri pemakan belerang yang terdapat dalam
pelarut.
Larutan Na2S2O3 harus disimpan pada tempat yang tidak

kena langsung matahari.
Example:
Sodium thiosulphate is standardized

on using methods : 0,1210 g of KIO3
is dissolved in water (214,00 g/mol) ,
the excess of KI is added and
acidified with HCl. The free Iodine
need 41,64 mL of thiosulphate
solution to reacted. Ditermine the
molarity of Na2S2O3.
Solution:
mmol Na2S2O3
= 0,1210 g KIO3 x ..
= 3,3925 mmol Na2S2O3
Molarity of sodium thiosulphate:
= 0,0815 M

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REDOX TITRATION AND

Permanganometry: redox titration on

Oxidation number of Manganese:

Common reaction in lab:

Acid can be used: dilute H2SO4

reaction need to be heat and catalyst

Standard primary for KMnO4:

5 HAsO2 + 2 MnO4- + 6 H+ + 2 H2O

The use of Permanganometry:

Standarisasi larutan permanganat

Larutan kalium permanganat bukan

Iron (II) is titrated with potassium

MnO4- + 8H+ + 5Fe2+- Mn2+ + 4H2O + 5Fe3+

Dichromate as strong oxidator

Cr2O72- + 14H+ + 6e- 2Cr3+ +

Determine Fe(II) in acidic (HCl)

Write the complete reaction

TITRATION WITH IODIUM

Iodimetri (cara langsung)

adalah titrasi yang dilakukan

Natrium tiosulfat umumnya dibeli sebagai pentrahidrat.

Larutan Na2S2O3 harus disimpan pada tempat yang tidak

Sodium thiosulphate is standardized

Molarity of sodium thiosulphate:

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