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Topic-wise Questions
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Expressing Concentrations of Solutions 12. The equivalent weight of Mohr’s salt during redox reaction
is equal to its
1. The density of a solution prepared by dissolving 120 g of a. Molecular weight / 2
urea (molecular mass = 60 g ) in 1000 g of water is 1.15 g/ml.
b. Atomic weight / 2
The molarity of this solution is:
a. 1.78 M b. 1.02 M c. Molecular weight / 3
c. 2.05 M d. 0.50 d. Molecular weight
13. The equivalent weight of MnSO4 is half its molecular weight,
2. When the volume of the solution is doubled, the following
becomes exactly half when it is converted to
a. Molality b. Mole-fraction a. Mn2O3 b. MnO2
c. Molarity d. Weight percent c. MnO4 d. MnO4–2
3. A semi molar solution is the one, which contains 14. 2.5 cm3 of 0.2 M H2SO4 solution is diluted to 0.5 dm3. Find
a. One mole solute in 2 litres normality of the diluted solution:
b. 2 moles solute in 2 litres a. 0.2 N b. 0.02 N
c. 0.1 mole solute in 1 litre c. 0.002 N d. 0.04 N
d. 0.2 moles solute in 2 litres 15. Number of moles of solute dissolved in 1000g. of the solvent
4. 1 kg of NaOH is added to 10 ml of 0.1N HCl, the resulting is called
solution will a. Molarity b. Molality
a. Turn blue litmus red c. Formality d. Normality
b. Turn phenolphthalein solution pink 16. Which of the following has no units?
c. Turn methyl orange red a. Molarity b. Normality
d. Will have no effect on red or blue litmus paper c. Molality d. Mole fraction
5. What is the mole fraction of glucose in 10% w/w glucose 17. Molarity of 4% (w/v) solution of NaOH is
solution?
a. 0.1 b. 0.5
a. 0.01 b. 0.02
c. 0.03 d. 0.04 c. 0.001 d. 1.0
6. Normality of 0.1M H3PO3 is 18. The number of moles of solute present in 2.0 lits of 0.5M
a. 0.2N b. 0.30N NaOH solution is
c. 0.033N d. 0.05N a. 2 b. 1
7. In a normal solution of BaCl2, normalities of Ba2+ and Cl– are c. 4 d. 0.1
in the ratio 19. What is the molarity of 0.2 N Na2CO3 solution?
a. 2:1 b. 1:2 a. 0.1 M b. 0 M
c. 1:1 d. 2:3 c. 0.4 M d. 0.2 M
8. Molarity of 0.1N oxalic acid is 20. 10 millimoles of solute is present in the following volume of
a. 0.05 M b. 0.1 M 0.08M solution
c. 0.2 M d. 0.3M a. 125ml b. 625ml
9. 138 g ethyl alcohol is mixed with 72 g of water. The ratio of c. 500 ml d. 1000ml
mole fraction of alcohol to water is: 21. The concentration of a 100 ml solution containing X grams of
a. 3 : 4 b. 1 : 2 Na2CO3 (mol. wt. = 106) is Y M. The values of X and Y are
c. 1 : 4 d. 1 : 1 respectively:
10. When an oxide M2O3 is oxidised to M2O5 its equivalent a. 2.12, 0.05 b. 1.06, 0.2
weight is
c. 1.06, 0.1 d. 2.12, 0.1
a. M. w/1 b. M. w/2
22. Zinc reacts with CuSO4 according to the equation Zn +
c. M. w/4 d. M. w/8
CuSO4 → ZnSO4 + Cu. If excess of zinc is added to 100ml,
11. The equivalent weight of H2SO4 in the following reaction is 0.05M CuSO4, the amount of copper formed in moles will be
a. 98 b. 49 a. 5 b. 0.5
c. 32.66 d. 40 c. 0.05 d. 0.005
NEET Full Course Material
23. How many milli litres of 1M H2SO4 will be neutralised by 36. Mole fraction of a solute in benzene is 0.2, then find molality
10ml of 1M NaOH solution? of solution:
a. 10 b. 20 a. 3.2 b. 2
c. 2.5 d. 5 c. 4 d. 3.6
24. The normality of orthophosphoric acid having purity of 70% 37. How much volume of 1 M H2SO4 is required to neutralise
by weight and specific gravity 1.54 gm/ml is: 20 ml of 1 M NaOH?
a. 11 N b. 22 N a. 10 ml b. 20 ml
c. 33 N d. 44 N c. 5 ml d. 15 ml
25. The volume of water that must be added to a mixture of 250ml Solubility
of 6M HCl and 650ml of 3M HCl to obtain 3M solution is
a. 75ml b. 150ml 38. How many grams of CO2 gas is dissolved in a 1 L bottle of
c. 300ml d. 250ml carbonated water if the manufacturer uses a pressure of 2.4
atmosphere in the bottling process at 25°C Given KH of CO2
26. If 36.0 g of glucose is present in 400 ml of solution, molarity water = 29.76 atm/mole/L at 25°C
of the solution is
a. 3.52 b. 4.2
a. 0.05M b. 11.0 M
c. 3.1 d. 2.5
c. 0.5M d. 2.0 M
39. H2S is a toxic gas used in qualitative analysis. If solubility of
27. What volume of 0.8M solution contains 0.1 mole of the solute?
H2S in water at STP is 0.195 m, what is the value of KH?
a. 100 ml b. 125 ml
a. 0.0263 bar b. 69.16 bar
c. 500 ml d. 62.5 ml c. 192 bar d. 282 bar
28. If 0.01 mole of solute is present in 500 ml of solution, its
40. The law which indicates the relationship between solubility
molarity is
of a gas in liquid and pressure is:
a. 0.01 M b. 0.005M a. Raoult’s law
c. 0.02 M d. 0.1M b. Henry’s law
29. Number of milli equivalents of solute in 0.5 litres of 0.2N c. Lowering of Vapour pressure
solution is
d. Van’t Hoff’s law
a. 10 b. 1
41. Among the following substance the lowest vapour pressure is
c. 100 d. 1000 exerted by:
30. 0.126 g of an acid is titrated with 0.1 N 20 ml of a base. The a. Water b. Alcohol
equivalent weight of the acid is:
c. Ether d. Mercury
a. 63 b. 50
42. Partial pressure of a solution component is directly
c. 53 d. 23
proportional to its mole fraction. This is known as:
31. 250 ml of a solution contains 6.3 grams of oxalic acid
a. Henry’s law b. Raoult’s law
(mol. wt. =126 g/mol). What is the volume (in litres) of water
to be added to this solution to make it a 0.1 N solution? c. Distribution law d. Ostwald’s dilution law
a. 750 b. 7.5 43. 3 moles of ‘P’ and 2 moles of “Q” are mixed, what will
be their total vapour pressure in the solution if their partial
c. 0.075 d. 0.75
vapour pressures in pure state are 80 and 60 torr respectively:
32. Volume of 0.1 M K2Cr2O7 required to oxidise 35ml of 0.5 M a. 80 torr b. 140 torr
FeSO4 solution is
c. 72 torr d. 70 torr
a. 35ml b. 29ml
44. Which of these curves represents Henry’s Law?
c. 17.5ml d. 175ml
33. The weight of H2C2O4.2H2O required to prepare 500ml of
0.2N solution is a. b.
a. 1.26g b. 6.3g
c. 1.575g d. 3.15g
34. 3.42 g of a substance of molecular weight 342 g is present in
250g of water. Molality of this solution is
c. d.
a. 0.4m b. 0.04 m
c. 0.8 m d. 4m
35. 3g of a salt [mol. wt. 30 g/mol] is dissolved in 250 g of water
the molality of the solution is 45. In which case Raoult’s law is not applicable?
a. 0.4 b. 0.2 a. 1 m NaCl b. 1 m urea
c. 0.6 d. 0.8 c. 1 m glucose d. 1 m sucrose

Physics Wallah 38
Solutions

46. Which one of the following gases has the lowest value of 55. Two liquids X and Y form an ideal solution. At 300 K, vapour
Henry’s law constant? pressure of the solution containing 1 mol of X and 3 mol of
a. N2 b. He Y is 550 mm Hg. At the same temperature if 1 mol of Y is
c. CO2 d. O2 further added to this solution, vapour pressure of the solution
increases by 10 mm Hg. Vapour pressure (in mm Hg) of
47. If two components A and B have PA0 :PB0 = 1 : 2 and have mole
X and Y in their pure states will be respectively
fraction in solution 1 : 2 then mole fraction of A in vapour is:
a. 200 and 300 b. 300 and 400
a. 0.33 b. 0.25
c. 400 and 600 d. 500 and 600
c. 0.52 d. 0.2
56. A solution is obtained by dissolving 0.2 moles of urea in
48. Henry’s law constant of oxygen is 1.4 × 10–3 mol l–1 atm–1 at
298 K. How much of oxygen is dissolved in 100 ml at 298 K a litre of water. Another solution is obtained by dissolving
when the partial pressure of oxygen is 0.5 atm? 0.4 moles of cane-sugar in a litre of water at the same
temperature. The lowering of vapour pressure to the first
a. 1.4 g b. 3.2 g
solution is.
c. 2.24 mg d. 3.2 g
a. Same as that of the second solution
49. Vapour pressure of chloroform (CHCl3) and dichloromethane
b. Half to that of the second solution
(CH2Cl2) at 25°C are 200 mmHg and 41.5 mmHg respectively.
Vapour pressure of the solution obtained by mixing 25.5 g of c. Double to that of the second solution
CHCl3 and 40 g of CH2Cl2 at the same temperature will be d. None
(Molecular mass of CHCl3 = 119.5 u and molecular mass of 57. At a certain temperature, the vapour pressure of water is
CH2Cl2 = 85 u): 90 mm. At the same temperature the vapour pressure of a
a. 173.9 mmHg b. 615.0 mmHg solution containing a non-volatile solute is 81mm. The
c. 347.9 mmHg d. 90.63 mmHg relative lowering of vapour pressure is
a. 9 b. 0.9
Vapour Pressure of Liquid Solutions
c. 10 d. 0.1
50. The amount of solute (molar mass 60 g mol–1) that must be 58. 3 gms of urea is added to 36 gms of boiling water. How much
added to 180 g of water so that the vapour pressure of water lowering in its vapour pressure is noticed?
is lowered by 10% is: a. 19 mm b. 38 mm
a. 30 g b. 60 g c. 760 mm d. 76 mm
c. 120 g d. 12 g 59. Two liquids X and Y form an ideal solution. The mixture has
51. The boiling point of C6H6,CH3OH, C6H5NH2 and C6H5NO2 a vapour pressure of 400 mm at 300 K when mixed in the
are 80°C, 65°C, 184°C and 212°C. Respectively. Which will molar ratio of 1 : 1 and a vapour pressure of 350 mm when
show highest vapour pressure at room temperature? mixed in the molar ratio of 1 : 2 at the same temperature. The
vapour pressures of the two pure liquids X and Y respectively
a. C4H6 b. CH3OH
are:
c. C6H5NH2 d. C6H5NO2
a. 250 mm, 550 mm b. 350 mm, 450 mm
52. 12g of urea is present in 1 litre of solution and 68.4 g of c. 350 mm, 700 mm d. 550 mm, 250 mm
sucrose is separately dissolved in 1 litre of another sample of
solution. The lowering of vapour pressure of first solution is Ideal and Non-Ideal Solutions
a. Equal to second
60. The system that forms maximum boiling azeotrope is:
b. Greater than second
a. Carbon disulphide - acetone
c. Less than second
b. Benzene - toluene
d. Double that of second
c. Acetone - chloroform
53. Lowering of vapour pressures of equimolar solution of d. n - hexane - n heptane
glucose, sodium chloride and barium nitrate are in the order.
61. A non-ideal solution was prepared by mixing 30 ml
a. Glucose > NaCl > Ba (NO3)2
chloroform and 50 ml acetone. The volume of mixture will
b. Glucose = NaCl = Ba (NO3)2 be:
c. Ba(NO3)2 > NaCl > Glucose a. > 80 ml b. < 80 ml
d. NaCl > Ba(NO3)2 > Glucose c. = 80 ml d. ≥ 80 ml
54. The vapour pressure of water depends upon 62. A solution of acetone in ethanol:
a. Surface area of container a. Shows a negative deviation from Raoult’s law
b. Volume of container b. Shows a positive deviation from Raoult’s law
c. Temperature c. Behaves like a near ideal solution
d. All d. Obey Raoult’s law

39 Physics Wallah
NEET Full Course Material
63. Which of the following will show a negative deviation from 70. The vapour pressure of pure solvent is 0.8 mm of Hg at a
Raoult’s law? particular temperature. On addition of a non - volatile solute
a. Acetone - benzene b. Acetone - ethanol ‘A’ the vapour pressure of solution becomes 0.6 mm of Hg.
c. Benzene - methanol d. Acetone - chloroform The mole fraction of component ‘A’ is:
64. A solution containing components A and B follows Raoult’s a. 0.25 b. 0.75
law: c. 0.5 d. 0.35
a. A – B attraction is greater than A – A and B – B 71. Lowering of vapour pressure of an aqueous solution of a non-
b. A – B attraction forces is less than A – A and B – B volatile, non-electrolyte 1 M aqueous solution at 1000C is:
c. A – B attraction forces remains same as A – A and B – B a. 14.12 torr
d. Volume of solution is different from sum of volumes of b. 312 torr
solute and solvent
c. 13.45 torr
65. What are the conditions for an ideal solution which obeys
d. 352 torr
Raoult’s law over the entire range of concentration?
72. A solution of two liquids boils at a temperature more than the
Ptotal PA0 x A + PB0 x B
a. ΔHmix = 0, ΔVmix = 0, =
boiling point of either of them. Hence, the binary solution
Ptotal PA0 x A + PB0 x B
b. ΔHmix = +ve, ΔVmix = 0,= shows:
a. Negative deviation from Raoult’s law
Ptotal PA0 x A + PB0 x B
c. ΔHmix = 0, ΔVmix = +ve,= b. Positive deviation from Raoult’s law
c. No deviation from Raoult’s law
d. ΔHmix = 0, ΔVmix= 0, Ptotal = PB0 x B
d. Positive or negative deviation from Raoult’s law depending
66. For an ideal solution with PA > PB , Which of the following is upon the composition.
true? 73. Out of the compounds given below, the vapour pressure of
a. (xA)liquid = (xA)vapour b. (xA)liquid > (xA)vapour (B) at a particular temperature is:
c. (xA)liquid > (xA)vapour d. (xA)liquid < (xA)vapour

67. Which of the following azeotropes is not correctly matched?

a. HNO3 (68%) + H2O (32%): Maximum boiling azeotrope,
B.P = 393.5 K
b. H2O (43%) + HI (56.7%): Minimum boiling azeotrope,
B.P = 290 K
a. Higher than that of A
c. C2H5OH(95.5%) + H2O(4.5%): Minimum boiling
azeotrope, B.P. = 351.15 K b. Lower than that of B
c. Higher of lower than (A), depending on the size of the
d. Chloroform (93.2%) + C2H5OH (6.8%): Minimum boiling
vessel
azeotrope, B.P. = 332.3 K
d. Same as that of (A)
68. Study the figures given below and mark the correct statement:

Colligative Properties and

Determination of (Molar) Mass
74. Camphor is used as solvent to determine the molecular mass
of non volatile solute by Rast method because for Camphor
a. Molal depression constant is high
b. Melting point is high
a. (i) Nitric acid + water(ii) Acetone + ethyl alcohol c. Being cheap
b. (i) Water + ethyl alcohol(ii) Acetone + Benzene d. All the above
c. (i) Acetone + ethyl alcohol(ii) Acetone + chloroform
75. If the elevation in boiling point of a solution of 10gm of solute
d. (i) Benzene + chloroform(ii) Acetone + chloroform (mol. wt.=100) in 100 gm of water is ΔTb, the ebullioscopic
69. Which of the following gas mixture is used by the divers constant of water is
inside the sea? a. 10 b. 10∆Tb
a. O2 + He b. O2 + Xe ∆Tb
c. O2 + Ar d. O2 + N2 c. ∆Tb d.
10
Physics Wallah 40
Solutions

76. In a 0.2 molal aqueous solution of a weak acid HX, the degree 85. Which among the following will show maximum osmotic
of ionization is 0.3. Taking kf for water as 1.85, the freezing pressure?
point of the solution will be nearest to a. 1M NaCl b. 1M MgCl2
a. -0.360°C b. - 0.260°C c. 1M (NH4)3PO4 d. 1M Na2SO4
c. +0.480°C d. -0.480°C 86. What weight of glycerol should be added to 600 g of water
77. A solution containing 12.5 g of non-electrolyte substance in 185 in order to lower its freezing point by 10°C? (kf = 1.86 K kg
g of water shows boiling point elevation of 0.80 K. Calculate the mol–1)
molar mass of a substance: (kb = 0.52 k kg mol–1) a. 496 g b. 297 g
a. 53.06 g mol–1 b. 25.3 g mol–1 c. 310 g d. 426 g
c. 16.08 g mol–1 d. 43.92 g mol–1 87. If 1 g of solute (molar mass = 50 g mol–1) is dissolved in 50 g
of solvent and the elevation in boiling point is 1 K. The molal
78. 10% solution of urea is isotonic with 6% solution of a non- elevation constant of the solvent is:
volatile solute X, what is the molecular mass of solute X? a. 2 b. 3
a. 6 g mol–1 b. 60 g mol–1 c. 2.5 d. 5
c. 36 g mol–1 d. 32 g mol–1 88. The colligative property is not represented by:
79. Choose the correct statement a. Elevation in boiling point
a. The boiling point of the solution falls on increasing the b. Osmotic pressure
amount of the solute c. Optical activity
b. The freezing point of the solution is lowered on adding d. Relative lowering of vapour pressure
more of solvent 89. Isotonic solutions have
c. The freezing point of the solution is raised on adding more a. Same boiling point
of solute b. Same vapour pressure
d. The freezing point of the solution decreases on increasing c. Same melting point
the amount of the solute
d. Same osmotic pressure
80. Osmotic pressure of a solution containing 2 g dissolved
90. Distribution law was given by:
protein per 300 cm3 of solution is 20 mm of Hg at 27°C.
The molecular mass of protein is: a. Ostwald b. Nernst
c. Henry d. Van’t hoff
a. 6239.3 g mol–1 b. 12315.5 g mol–1
91. If the elevation in boiling point of a solution of 1 g of solute
c. 3692.1 g mol­–1 d. 7368.4 g mol–1
(molecular weight = 100) in 100 g of water is ΔTb, the
81. A solution is made by dissolving 20 g of a substance in 500ml ebullioscopic constant of water is:
of water. Its osmotic pressure was found to be 600 mm of Hg
a. 10 b. 100 Tb
at 15°C. Find the molecular weight of the substance:
a. 1198 g mol–1 b. 500 g mol–1 ∆Tb
c. ΔTb d.
c. 1200 g mol–1 d. 1000 g mol–1 10

82. An aqueous solution of 2% non-volatile solute exerts a 92. The osmotic pressure is expressed in the unit of:
pressure of 1.004 bar at a normal boiling point of the solvent. a. MeV b. Calorie
What is the molecular mass of the solute? c. cm/sec d. atm
a. 23.4 g mol–1 b. 41.35 g mol–1 93. Which of the following will have highest boiling point at 1
c. 10 g mol–1 d. 20.8 g mol–1 atm pressure?
83. Which of the following statement is correct? a. 0.1M NaCl b. 0.1 M Sucrose
a. A saturated solution will remain saturated at all c. 0.1M BaCl2 d. 01. M Glucose
temperatures 94. The freezing point of one molal NaCl, assuming NaCl to be
b. A plant cell swells when placed in hypertonic solution 100% dissociated in water is: (molar depression constant is 1.86)
c. The depression in freezing point is directly proportional to a. – 2.72°C b. – 3.72°C
molality of the solution c. 2.72°C d. 3.72°C
d. Lowering in vapour pressure is a colligative property.
95. What happens to freezing point of benzene when naphthalene
84. A solution containing 10.2 g glycerine per litre is isotonic is added?
with a 2% (w/v)solution of glucose. What is the molecular a. Increases
mass of glycerine? b. Decreases
a. 91.8 g b. 1198 g c. Remain unchanged
c. 83.9 g d. 890.3 g d. First decreases and then increases

41 Physics Wallah
NEET Full Course Material
96. The order of boiling point of four equimolar aqueous solutions 106. An ideal solution was obtained by mixing methanol and
is C< B < A < D. The correct order of their freezing point is: ethanol. If the partial vapour pressure of methanol and
a. D < C < B < A ethanol in solution are 2.619 kPa and 4.556 kPa respectively,
b. D > C < B < A the composition of vapour (in terms of mole fraction) will be:
c. D < A < B < C a. 0.635 MeOH, 0.365 EtOH
d. D > A > B > C b. 0.365 MeOH, 0.635 EtOH
c. 0.574 MeOH, 0.326 EtOH
97. The boiling point of a solution of 0.11g of a substance in 15 g
d. 0.173 MeOH, 0.827 EtOH
of ether was found to be 0.1°C higher than that of pure ether.
The molecular weight of the substance will be (Kb = 2.16 K 107. What is the normal b.p of an aqueous solution whose freezing
kg mol–1). point is –2.48°C ?
a. 148 b. 158 (Kf = 1.86°[Link]/mol, Kb = 0.512°[Link]/mol)
c. 168 d. 178 a. 100.7°C b. 102.5°C
c. 109.0°C d. 99.3°C
98. Dissolution of 1.5 g of a non-volatile solute (molecular
weight = 60) in 250 g of a solvent reduces its freezing point 108. The mass of glucose that should be dissolved in 100 g of
by 0.01°C. Find the molal depression constant of the solvent: water in order to produce same lowering of vapour pressure
as is produced by dissolving 1 g of urea (mol. Mass = 60) in
a. 0.01 b. 0.001 50 g of water is : (Assume dilute solution in both cases)
c. 0.0001 d. 0.1 a. 1 g b. 2 g
99. A solution has higher osmotic pressure than its standard c. 6 g d. 12 g
solution. Which of the following term will be used for this 109. The osmotic pressure of a decimolar solution of urea at 27°C is
solution? a. 2.49 bar b. 5 bar
a. Isotonic c. 3.4 bar d. 1.25 bar
b. Hypertonic 110. What is the volume of solution containing 1 gm mole of sugar
c. Dilute that will give rise to an osmotic pressure of 1 atm at 0°C?
d. Hypotonic a. 11.2 lit b. 112 lit
c. 224 lit d. 22.4 lit
100. The boiling point of 0.1molal K4[Fe(CN)6] solution will be
(Given Kb for water = 0.52 K kg mol–1. Abnormal Molar Mass
a. 100.52°C b. 100.104°C
111. Which of following representations of i (van’t hoff factor) is
c. 100.26°C d. 102.6°C
not correct?
101. 20 g of an non-volatile solute is added to 500 g of solvent, Observed colligative property
a. i =
freezing point of pure solvent = 5.48°C and that of solution is Expected colligative property
4.47°C, Kf = 1.93 k kg mol–1 molecular mass of solute is:
Normal molecular mass
a. 77.2 b. 76.4 b. i =
Observed molecular mass
c. 73.2 d. 70.6
[Link] molecules actually present
102. Which has the least freezing point? c. i =
Observed of molecules expected to be present
a. 1% sucrose b. 1% NaCl
d. i =
c. 1% CaCl2 d. 1% glucose
Total number of particles taken before association / dissociation
103. Which of the following solutions will have the highest boiling
Total number of particles taken after association / dissociation
point
a. 0.1M Al2(SO4)3 b. 0.1M FeCl3 112. Which of the following will have same value of Van’t Hoff
c. 0.1M NaCl d. 0.1 M Urea factor as that of K4 [Fe(CN)6]?
104. The molality of the solution prepared by dissolving 125 mL a. Al2 (SO4)3 b. AlCl3
of pure methanol (d = 0.8gmL–1) in 375 g of ethanol is : c. Al (NO3)3 d. Al(OH)3
a. 10.8 b. 11.2 113. What will be the degree of dissociation of 0.1 M Mg(NO3)2
c. 8.33 d. 10.4 solution if Van’t Hoff factor is 2.74?
105. A compound MX2 has observed and normal molar masses a. 75% b. 87%
65.6 and 164 respectively. Calculate the apparent degree of c. 100% d. 92%
ionization of MX2 : 114. Which of the following has the highest freezing point?
a. 75% b. 85% a. 1m NaCl solution b. 1m KCl solution
c. 65% d. 25% c. 1m AlCl3 solution d. 1m C6H12O6 solution
Physics Wallah 42
Solutions

115. If α is the degree of dissociation of Na2SO4, the van’t Hoff’s 118. Van’t Hoff factor more than unity indicates that the solute in
factor (i) used for calculating the molecular mass is: solution is:
a. 1 + α b. 1 - α a. Dissociated b. Associated
c. 1+ 2 α c. 1 - 2α c. Both (a) and (b) d. Cannot say anything
116. The Van’t Hoff factor of 0.005 M aqueous solution of KCl is 119. KBr is 80% dissociated in aqueous solution of 0.5 m
1.95. The degree of ionisation of KCl is: concentration (given, Kf for water = 1.86 K Kg mol–1). The
a. 0.95 b. 0.97 solution freezes at:
c. 0.94 d. 0.96 a. 271.326 K b. 272 K
117. 0.2 molal aq. HA acid ionises to the extent of 20%. Kf for acid c. 270.5 K d. 268.5 K
is 1.86, then calculate the freezing point of the solution: 120. Van’t Hoff factor of Ca(NO3)2 is:
a. –0.45°C b. –0.50°C a. One b. Two
c. –0.31°C d. –0.53°C c. Three d. Four

43 Physics Wallah
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