CDI 6 - Fire Technology
CDI 6 - Fire Technology
FIRE
The heat and light energy that produced by the combustion of substances.
COMBUSTION
Burning is also called Combustion
Rapid Oxidation of material
OXIDATION
The chemical reaction in which oxygen chemically combines with the organic elements of combustible
substances.
Flash point
The temperature at which substance give off vapor that burns momentarily when a flame of spark is
adopted.
Fire point
The temperature at which the material will give off ample vapors to keep burning.
Auto Ignition or Self Ignition Point
The temperature at which the substance can be heated to release vapors that will ignite without the
application of flame or spark.
1. Friction
2. Percussion
1. JOHN WALKER
He was the English Pharmacist who invented the first match in 1827. The tip of this match was
coated a mixture of antimony sulfide and potassium chlorate that was held on the wooden
matchstick by gum Arabic and starch.
2. Antoine Laurent Lavoisier
A French Chemist who proved in 1777 that burning is the result of rapid union of oxygen with
other substances. As substances burn, heat and light are produced. He was the Father of Modern
Chemistry. He named both oxygen and hydrogen.
FIRE TRIANGLE - the graphical representation of the three elements of fire. (Fuel, Heat and Oxygen)
a. Oxygen
Composition of Air: Oxygen Requirements
Oxygen- 21% 12% -No fire
Nitrogen-78% 14%-Flash Point
Inert gases-1% 21%- Fire Point
b. Heat
A form of energy generated by the transmission of some other form of energy, as in
combustion or burning.
c. Fuel
Any substance (Combustible Materials) which reacts chemically with oxygen and flames.
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Technically speaking, flammable and combustible liquids do not cause fire. It is the vapors they produce
which burn or explode when exposed to air under the influence of heat. Gasoline is the most widely used
flammable liquid.
FIRE TETRAHEDRON
A four sided representation of causes of fire. The fourth element that is added is the Chemical
reaction.
PROPERTIES OF FIRE
A. Physical Properties
1. Specific Gravity
2. Vapor Density
3. Vapor Pressure
4. Temperature
5. Boiling Point
6. Ignition temperature or Kindling temperature
7. Fire point
8. Flash point
B. Chemical Properties
1. Endothermic reaction
-These are changes whereby energy (heat) is absorbed or added before the reaction takes place.
2. Exothermic Reaction
-Reactions or changes that release or gives off energy thus they produced substances with less energy
than the reactants.
3. Oxidation
4. Combustion flame
-The manifestation of fire when the fire is in its gas-phased combustion. A matter that is produced by
fire.
PYROLYSIS
It refers to the chemical process whereby fire consumes the most solid part of the fuel. It is the
thermal decomposition of a solid fuel through the action of heat.
PRODUCTS OF COMBUSTION
1. FIRE GASES
Are those that remain when other products of combustion cool to its normal temperature. The fire gases
formed depends on
Carbon Monoxide burns rapidly when combined with the oxygen at high temperature which caused
backdraft explosions. Carbon Monoxide which is also produced by slow oxidation, is found in sewers,
caves, wells, mines, stoves, and automobile exhaust.
TYPES OF POISONOUS GAS
A. Hydrogen Sulfide ( H2S )- a fire gas formed during fires involving organic material containing
sulfurs, It is colorless, highly toxic gas with the strong odor of rotten eggs.
B. Hydrogen Cyanide ( HCN ) a toxic fire gas found in oxygen-starved fires involving nitrogen
containing materials such as:
The gas is also used as a fumigant which can pose serious danger to firefighters
working in recently fumigated buildings. It smells like bitter almonds.
C. Hydrogen Chloride ( HCl )
A gas which can be fatal after a few breaths. It is commonly produced in fires involving
Chloride containing plastics. Plastics can be found to electrical insulations, conduit and
piping’s.
2. FLAME
It is the luminous body of a burning gas which gets hotter and less luminous when mixed with more
oxygen. Flame fades when carbon burns completely, therefore flame is somewhat a product of
incomplete combustion.
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TYPES OF FLAME
A. According to Color and Completeness of Combustion
1. Luminous Flame
A reddish-orange or yellow in color; it deposits soot because it is a product of incomplete combustion; it
has a lower temperature and takes time to heat another objects because it is cooler than the non-
luminous flame. Carbon dioxide is present.
2. Non- luminous flame
Bluish in color; it does not deposit soot because it is a product of complete combustion; it has a higher
temperature than luminous flame. Oxygen is present.
B. According to Burning Fuel and Air mixture
1. Premixed Flame
Exemplified by the Bunsen burner. The oxidizer are mixed before the combustion zone occurs.
2. Diffusion Flame
Diffused or disperse flame; widely spread type of flame. It is a type of flame in which the oxidizer
combines with the fuel by diffusion. As a result, the flame speed is limited by the rate of diffusion.
Diffusion flames tend to burn slower and to produce more soot because there may not be sufficient
oxidizer for the reaction to go to completion.
PLASTICS
Plastics are included as ordinary fuels under class A except those materials composed of or containing
cellulose nitrate. Cellulose nitrate is a chemical (powder) used in bombs. Materials that use cellulose
nitrate are also called PYROXYLIN.
LATENT HEAT
The quantity of heat absorbed by a substance from a solid to a liquid, and from a liquid to a gas.
Conversely, heat is released during conversion of gas to liquid or liquid to gas.
EXPLOSION
A violent effect of chemical reaction when combustion process is confined so that appreciable
pressure occurs.
DETONATION
A violent reaction beginning with a very simple ignition that initiates a chain reaction; a rapid and
confined combustion process that produces energy waves that propagates (spreads) in supersonic
(very fast) speed; energy waves develop into “shock front” that results to a very strong explosion
CHEMICAL FUELS
Chemical fuels, which are produced in solid and liquid form, create great amounts of heat and
power. They are used chiefly in rocket engines. Chemical rocket propellants consist of both fuel and
an oxidizer. A common rocket fuel is the chemical hydrazine. The oxidizer is a substance, such as
nitrogen tetroxide, that contains oxygen. When the propellant is ignited, the oxidizer provides the
oxygen the fuel needs to burn. Chemical fuels are also used in some racing cars.
NUCLEAR FUELS
Nuclear fuels provide energy through the fission or fusion of their atoms.
Uranium is the most commonly used nuclear fuel, though plutonium also provides nuclear energy.
When the atoms of these elements undergo fission, they release tremendous amounts of heat.
Nuclear fuels are used mainly o generate electricity. They also power some submarines and ships.
Nuclear energy can also be produced through the fusion of hydrogen atoms.
Nuclear Fission- split of the nucleus of the atoms
Nuclear Fusion- combination two light nuclei of atom
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FIRE BEHAVIOR
1.THERMAL BALANCE
Refers to the rising movement or pattern of the fire; the normal behavior when the fire is undisturbed.
2.THERMAL IMBALANCE
On the other hand is the abnormal movement of fire due to interference of foreign matter. Thermal
imbalance often confuses the fire investigator in determining the exact point where the fire originated.
CLASSIFICATION OF FIRES
A. Based on Cause:
1. Natural fire
2. Accidental fire
3. Intentional fire
1. CLASS A FIRES
2. CLASS B FIRES
3. CLASS C FIRES
4. CLASS D FIRES
5. CLASS E FIRES
6. CLASS K FIRES
PROPAGATION OF FIRE
It simply define how the fire being spread and propagate to different size. It is the transmission of heat
by the nearby materials.
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INTENSITY OF FIRE
It determines how hot the fire is burning. Some types of fuels naturally burn hotter than other.
Take Note: Fire suppression is the process of slowing the rate of burning, while Fire control is the process of
holding the fire in spreading and Fire Extinguishment is putting the fire completely out.
2. CARBON DIOXIDE
It is non combustible and non reactive with most substances. Due to its non-conductivity, CO2
is very effective on Class C fires. It is also used on Class B fires.
3. DRY CHEMICAL- There are two basic types of Dry chemicals extinguishing agent:
a. Ordinary and Regular Dry Chemicals- generally refer to those powders that are listed
for use on Class B or Class C fires.
b. Multi- Purpose Dry Chemical- refers to the powders listed for use on Class A, B, C,
fires.
4. DRY POWDER
Generally accepted term for agents used to extinguish combustible metal fires. It should not be
used on other types of fire due to its limited value on Class D fires.
6. HALONS
Halogenated agents work chemically to extinguish fire. It stops the combustion process by
breaking the fire chain reaction and prevents further fire propagation. Halons can be applied by
locally by using non combustible gas similar to Carbon Dioxide.This type of agent is effective
in controlling or extinguishing surface fires involving flammable liquid, solids or gases such as
dip tanks, spray booths, oil filled transformers, or vapor vents. Halons are effective on Class B
and Class C fires.
FIRE EXTINGUISHER
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It is a mechanical device usually made of metal, containing chemicals, fluids or gases for stopping fires.
It is used for the purpose of putting out the fire before it propagates.
It is a portable device used to put out fires of limited size. Extinguishers are designed to cope with fires
in their infancy and are not intended to act as substitute for automatic sprinklers, standpipe and hose ,the
fire department. There are classes of extinguishers, each type has different value, but all is not equally
effective upon all causes of fires.
Fire extinguisher classification consists of a letter which indicates the class of fire on which an
extinguisher has been found to be effective, preceded by a rating NUMERAL. Fire extinguishers must
always be fully charged and in condition which will permit efficient operation at any moment without
delay.
CLASSES OF EXTINGUISHER
1. Portable Fire Extinguisher
It offers the greatest potential for immediately controlling workplace fires. It is not a substitute
for sprinkler systems, hose streams or other fire fighting devices.
Steps in using Portable Fire Extinguishers
a. Pull the pin at the top of extinguisher.
b. Point the nozzle or outlet toward the base of the fire
c. Press the handle above the carrying handle to discharge the agent.
d. Sweep the nozzle back and forth or in side to side motion before the flames.
2. Semi Portable / Wheeled Extinguisher
This type of extinguisher provides a way of getting a sizeable amount of extinguishing agent.
Its capacity is ranging from 100 to 350 lbs. of dry chemical agent. The units typically have a
50 ft or 15m hose that allows considerable maneuverability while fighting fires.
Steps in using Semi portable/ Wheeled Extinguisher:
a. Open the compressed gas cylinder to pressurize the agent;
b. Free the hose from its reel and move toward the fire;
c. Point the nozzle toward the base of the fire;
d. Squeeze the nozzle to discharge the agent. To stop the extinguisher from discharging, release
the nozzle action.
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Carbon Dioxide extinguisher works on classes B and C and work by suffocating the fire. Carbon
Dioxide will not burn and displaces air.
5. Wet Chemical
Most Class K extinguishers contain a solution of potassium acetate, sometimes with some
potassium citrate or potassium bicarbonate. The extinguisher sprays the agent out as a fine mist. The
mists act to cool the flame front while the potassium salts saponify the surface of the burning
cooking oil, producing a layer of foam over the surface. This agent producing the same effect
similar to the effect of foam extinguisher, but with greater cooling effect. Saponification works only
on animal fats and vegetable oil.
6. Fire Blanket
Are made of fire resistant materials. They are particularly useful for smothering flammable liquid
fires or for wrapping round a person whose clothing is on fire. Fire blankets conforming to British
Standard. If blanket does not completely cover the fire. It will not be able to extinguished the fire.
1. ADAPTER
A device that converts attributes of one device or system to those of an otherwise incompatible
device or system. It connects two incompatible coupling or hose.
2. Breathing apparatus
It is for general use for the purpose of affording respiratory protection against poisonous or
irrespirable atmospheres.
3. Fire shelter
A safety device of last resort used by wild land firefighters when trapped by wildfires.An
aluminized tent offering protection by means of reflecting radiant heat and providing a volume of
breathable air in a fire entrapment situation.
4. Firefighter flashlight
A flashlight of high quality should include a high intensity halogen or LED bulb, an adjustable
beam that can be used for spot or flood focus, a heavy-duty outer casing, and a comfortable grip.
Because firefighters often work in dark, low-visibility situations it is extremely important for them
to have a FLASHLIGNT.
5. Fire hose
A high-pressure hose used to carry water or other fire retardant (such as foam) to a fire to extinguish it.
Outdoors, it is attached either to a fire engine or a fire hydrant. Indoors, it can be permanently attached
to a building's standpipe or plumbing system. It was invented by Hero of Alexandria in the basis of
Ctesibius' double action piston pump.
6. Hose Jacket
A hollow cylindrical or barrel shaped device that opens lengthwise through the center on a set of
hinges. When the jacket is clamped around the leaking hose connection, the water is confined by the
hose jacket. This tool can prevent the disablement of the entire hose layout.
7. Hose clamp
A tool used to stop the flow of water in a fire hose without shutting off the source of water supply. It
can stop the flow of water through a hose while hose lay is being completed or cut-off the flow of water
in a charged line. Apply the hose clamp to a section of hose approximately 6 feet from the coupling.
8. Hydrant wrench
A tool used to remove fire hydrant caps and open the valve of the hydrant. They are usually adjustable
so as to fit different sized hydrant nuts.
9. Spanner wrench
A tool used to tighten leaking connections and to loosen connections that are too tight.
10. Hose strap (also known as a rope hose tool)
A piece of firefighting equipment. It can be "a short length of rope with an eye loop at one end and a
metal hook at the other “or a piece of "flat nylon webbing sewn into a four-foot loop". They share a
wide variety of established uses, including carrying un-charged fire hose, opening doors, closing doors,
securing hose lines, dragging victims, and even carrying boots. The use that gives the tool its name,
however, is securing a charged hose line, allowing a firefighter to better control and maneuver the line
while flowing water.
11. Rope
A length of fibres, twisted or braided together to improve strength for pulling and connecting. It has
tensile strength but is too flexible to provide compressive strength (i.e. it can be used for pulling, but
not pushing). Rope is thicker and stronger than similarly constructed cord, line, string, and twine.
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LADDER TERMINOLOGY
a. Bed Ladder- the lowest section of an extension ladder
b. Fly Ladder- the top section of an extension ladder
c. Butt- the bottom end of a ladder
d. Heel- the part of the ladder that touches the ground.
e. Halyard- a rope or cable used to raise the fly ladder
f. Pawl or Dog- the mechanism on the end of the fly ladder that locks to the bed ladder.
g. Rung- the cross member used in climbing
h. Top or Tip- the top of the ladder
i. Hooks- used to hook over a roof peak, sills, or walls where the heel does not rest on a foundation.
j. Stops- wood or metal blocks used to prevent the fly of the ladder from extending out further from the
ladder.
k. Guides- light metal strips of an extension ladder while it is being raised or lowered.
TYPES OF LADDERS:
A. Ground ladders
Its sizes vary from 3.1 to 17 meters (10-55 feet) long. It is being carried on a pumper or fire
trucks.
Forms of Ground Ladders:
1. Straight ladder
This is a type of ladder that contains only one section. It ranges in length from 12 to 16 feet.
The most common size is the 14 foot straight ladder. The roof or hook ladder is a straight
ladder adapter for a special purpose. Hooks are mounted on a movable socket that permits
them to fold inward when not in use.
2. Extension ladder
Consists of a bed and one or more fly ladders. The fly ladder slides through guides on the
upper end of the bed ladder. It contains locks (pawls or dogs) which hook over a rung of the
bed ladder. This secures it in a designated position, dependent upon the desired length of the
ladder. The fly ladder is usually raised by a halyard fastened to the lower rung and operated
over a pulley on the upper end of the bed ladder. The 24, 35, or 36 foot ladders are the types
commonly found on the pumpers.
3. Attic Ladders
It provides means of reaching through an opening into attics, lofts, and other areas that are
somewhat difficult to reach without a special ladder. It can be folded or collapsed for a small
room or closet works. They are usually short because they are required to reach only a short
distance.
4. Wall Ladders
Types of ladder best used in rescue where a ladder in place already falls short of the
endangered person. It allows the user to climb up or down, one storey at a time.
B. AERIAL LADDERS
Are mounted on a turntable, capable of extending up to 30.5 meters ( 100 feet ), have three or
four metal sections of ladder, that can be raised or lowered by hydraulically controlled cables.
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LADDER CARRIES
1. One –man carry
Remove the ladder from the apparatus and pass either arm through the ladder at the middle of
its length. Carry it with the hooks forward and lowered.
2. Two-man carry
Normally extension ladders from 24 to 36 feet in length require at least two men. To remove
the ladder from the apparatus, place one man near each end. Each man then passes one arm
through the ladder, grasps the second rung forward. Both men should be in the same side of the
ladder.
3. Four-man carry
The four men should be positioned in at least two men in each end.
4. Six-man carry
This type of carry is used for very large or heavy ladders and is the same as the four man carry,
except that two additional men are laced in the middle on the opposite sides of the ladder.
LADDER RAISES
Ladder rising requires practice and cooperation. Before raising a ladder, you must know how far
you should place the heel of the ladder from the building.
Ways or methods to determine how far is the heel from the building
Arson investigation
ARSON
It is the malicious destruction of property by means of fire.
Section 1: arson
Any person who burns or sets fire to the property of another shall be punished by prison mayor.
The same penalty shall be imposed when a person sets fire to his own property under circumstances
which expose to danger the life or property of another.
The offense is committed by a syndicate if it is plan or carried out by a group of three or or more
persons
Section 5.Where death results from arson
If by reason of or on occasion of arson death results, the penalty of reclusion perpetua shall be imposed
to death shall be imposed.
LAWS RELATED WITH FIRE PREVENTION AND FIRE PROTECTION IN THE PHILIPPINE
SETTING INCLUDES THE FALLOWING.
1. P.D. NO. 1185 Fire Code of the Philippines
Date of effectively- August 1977
CLASSIFICATION OF ARSON
1. Attempted arson
If a person intended to burn a wooden house, collected rags soaked in gasoline and placed it beside
the wall, but when he was about to light it he was seen by another who ran after him. The crime is
attempted arson .If the person was able to light the rags but the fire was put out before any part of
the building was burn then it is frustrated arson but if before the fire was put out ,part of the
building was burned then it is consummated arson.
In arson, it is not necessary that there be flame or that the structure be consumed or materially
damage .Ignition satisfies the requirement in burning.
Malicious intent of the offender must be proven in arson, otherwise no crime exist. The law
presumes that a fire accidental in origin, hence the criminal design must be shown .fire caused by
accident or negligence does not constitute arson. The intent can be inferred from the facts of the
case, like application for fire insurance, threat, quarrels, etc.
After corpus delicti has been established, any evidence direct or circumstantial may be introduced to
show that the act was committed by the accused and that it was done with criminal intent.
Clue material such as tools, matches, and articles of clothing’s may be found at the scene of the
crime and sometimes traced to the suspect ,or the suspect may have carried on his person or
clothing’s traces which link him to the scene of the crime.
2. Evidence showing intent
Removal of valuable articles substitution of interior articles, ill feeling, unfriendly relations
between the accused and occupants of the burn building, absence of effort to extinguish the fire
or to turn the fire alarm may prove intent.
1. Origin of fires
2. Motive
3. Prima facie evidence and prime suspects
4. Tell tale signs
MOTIVES OF ARSONIST
Motive is not necessary to be proven in a criminal proceeding but once motive is shown, then intent
can easily be established .Motive therefore can be established by:
1. Economic gain
1. Abnormal Youth
Epileptics, imbeciles and morons may set fire without knowing the seriousness of the act.
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7. Diversionary tactics-
The arsonist sometimes will devise ways and means to distract the attention of law enforcement
officers from the actual commission of crime
b. White smoke
It indicates the presence of phosphorous.
c. Grayish smoke
It may be caused of flying ashes or soot of loosely packed substances such as straw or hay.
d. Black smoke
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It may be produced in the burning material of a product or the preponderance in the burning
material of a product with petroleum based such as rubber, tar coal turpentine or petroleum.
e. Reddish brown or yellow smoke
It may indicate the presence of nitrates or substances which are compounded with nitrates it
may be observed in burning nitric acid, plastics, film or smokeless gun powder.
f. Setting smokes, irritating the nose and throat, causing lacrymation and coughing indicates presence of
chlorine
If the fire has been promptly reported and extinguished, the discovery of incriminating evidence may be
simple, but if the area has been reduced to ashes, recovery of traces of evidence will be a difficult
matter. Whatever is the condition of the scene, a patient or perseverance, methodical study of the area
may reveal the criminal design and the method of operation of the arsonist.
In this connection, the following are the procedure that may guide any arson investigator in its investigation
after the fire.
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as peculiarly colored materials should be collected for laboratory examination .Peculiar odor
should be noted.
5. Traces of accelerants attention should be focused for the presence of traces of the accelerants like
kerosene, gasoline, or turpentine .A study of the manner in which wood are charred sometimes
reveal indication as to an accelerant .if a wood is soaked with a petroleum product, such as
gasoline or kerosene, prior to burning it, it will acquire a distinctive appearance in charring.
6. Altered protective devices
To insure destruction, the arsonist sometimes tampers the alarm device. The Water flow may be
examined for sign of tampering .abnormal condition of the fire doors, transoms and window
should be observed.
A valuable information may be obtained by arson investigator thru the process of careful
questioning the various persons associated with the discovery and control of the fire ,the
occupants of the building ,including its watchmen ,if any .evidences tending to establish intent
and motive as well as the location and identification of the perpetrator.
a. By witnesses
the first who discovered the fire
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