VASANTH KUMAR G AMINES GPUC FOR GIRLS, PUTTUR

PREPARATORY-2024 13. Solubility of C2H5NH2 in water is due to the

[Link] Benzene Diazonium Chloride (BDC) reacts with formation of____ bonding.(Hydrogen)
Aniline in acidic medium at 273-278K to form coupling [Link] Arylamine & ammonia which has higher
compound known as PKb value
a) p-amino azobenzene b)O-amino azobenzene a)Arylamine higher b) Ammonia higher
c) m-amino azobenzene d) all the above c) Arylamine lower d) Nonenof these
[Link] Hybridisation of Nitrogen atom in Tertiary amine is [Link] colour of p-aminobenzene is
a)sp2 b) sp3 d) sp d) sp3d a)Red b) orange c) Green d) yellow
[Link] organic compound ‘A’ on treatment with aqueous 16. Tertiary amine have low boiling point than
ammonia and heating forms compound ‘B’, which on heating primaryamines and secondary amines due to absence
with Br2 and KOH forms a compound ‘C’ of molecular of ____(Hydrogen bonding)
formula C6H7N. Write the names of compound ‘A’, ‘B’, and 17. The gas liberated when aliphatic primary amines
‘C’ (A-Benzoic acid(C6H5COOH), B-C6H5CONH2 reacts with HNO2 is_____(N2/Nitrogen)
(Benzamide), C- C6H5NH2 (Aniline) 18. The final product formed when a primary aliphatic
4. Give reason amine reacts with nitrous acid[HNO2] is__
a) Aliphatic amines of lower molecular mass soluble in water a)Alcohol b)Diazonium salt
(Form hydrogen bond with water) c)Isocyanide d) Amide
b) Dimethylamine is more basic than methyl amine. 19. 3 amine doesn’t answer Hinsberg test,
0

(+I effect in dimethylamine is more than methyl amine) because____

5. Which of the following amines cannot be prepared by a) If forms salt with Hinsberg reagent
Gabriel Synthesis. b) It has no replacable hydrogen
a)methanamine b) Ethanamine c) Propanamine d) Aniline c) It is not reactive d) It has replacable hydrogen
6. During diazotization, the nitrous acid is produced in the 20. Explain Hoffmann bromamide degradation
reaction mixture by the reaction of reaction with equation.
a) NaNO2 & HCI b) NaNO3 & HCI [Link] the product formed when benzene diazonium
c) NaNO3 & HNO3 d) NaNO3 & HNO3 chloride solution is hydrolysed (Phenol)
7. The gas liberated when ethyl amine reacted with HNO3 at 22. How is N-ethyl ethanamine converted to N,N-
low temperature is___(Nitrogen) diethyl ethanamine?
8. Give reason : In the isomeric amines Butanamine has more 23. The amide which gives ethanamine by Hoffmann
boiling point than N, N – dimethylmethanamine(presence of broamide reaction is
H-bonding in Butanamine) a) methanamide b)Ethanamide
9. What is Hinsberg reagent ? c) Propanamide d) butanamide
10. ldentify the products X, Y and Z in the following 24. i)Explain the reaction of ethanamine with
conversion Hinsberg’s reagent.
ii) Why is the product obtained in the above reaction
soluble in alkali? (due to prsence of acidic
Hydrogen)
25. Nitration of aniline in acidic medium will yield
11. Which of the following gives carbylamines reaction significant amount of meta-derivative along with ortho
a)Aniline b)N-methylaniline and para derivatives. Why? (In acidic medium,aniline
c)N,N-dimethylaniline d)dimethylamine is protonated to give Anilinium ion which is meta
[Link] amine have low boiling point than primary amines directing)
and secondary amines due to absence of ____(absence of H- 26. The IUPAC name of CH3-NH-CH2-CH3 is
bonding) a)N-methyl ethanamine b) Methyl ethanamine
c) N,N-methyl ethanamine d) N-ethyl ethanamine

VASANTH KUMAR G
27. Aniline om reaction with excess of bromine water gives [Link] equations for the preparation of
a) p-bromo aniline b)o-bromo aniline methylamine(Methanamine) by Gabriel pthalimide
c)2,4,6-tri bromo aniline d) m-bromo aniline synthesis.
28. Benzene diazonium chloride react with cuprous chloride 47. The formula C3H9N can be represent
in HCl to form chlorobenzene and ______ gas (N2/Nitrogen) a)Primary amine b)Secondary amine
29. How would you convert methyl amine into methyl iso c)Tertiary amine d)All of these
cyanide 48. The general formula of diazonium salt is
30. What is Hinsberg reagent? a)Ar-X b) Ar-NO2
31. Hofmann’s Bromamide reaction is to convert +
c) ArN2 X - d) ArN2+X-HSO4-
a) Acid to alcohol b) Alcohol to acid 49. Aniline is____ basic than ammonia.(Less)
c) Amide to amine d) Amine to amide 50. Name the major product formed during the
32. The bad smelling substance formed by the action of following conversions
[Link] on chloroform and aniline is i) Nitrous acid is treated with methyl amine
a) Nitrobenzene b)Phenyl isocyanide (Methyl alcohol/Methanol)
c)Phenyl cyanide d)Phenyl thiocyanide ii) Benzene diazonium chloride is treated with KI
33. The conversion of benzene diazonium salt to haloarenes (Iodobenzene/C6H5I)
in presence of copper in acidic medium is iii) Nitrobenzene treated with iron scrap and
called____(Gatterman reaction) Hydrochloric acid (Aniline/C6H5NH2)
34. Explain the preparation of primary amine by Gabriel 51. the product obtained when propionamide subjected
pthalimide synthesis. for Hoffmann degradation
35. Arrange the following compounds,in the increasing orer of a)Methyl amine b) Propyl amine
their basic nature in aqueous solution. Benzamine(pKb=9.38), c)Ethyl amine d)Ethyl bromide
Ethanamine(pKb=3.29), Phenylmethanamine(pKb=4.70) 52. Choose the most stable diazonium salt
36. Hinsberg’s reagent is a) C6H5CH2N2+X- b) CH3N2+X-
a) Benzene sulphuryl chloride b)Chlorobenzene c) C6H5N2+X- d)CH3CHN2+X-
c)benzene sulphonyl chloride d)Benzene carbonyl chloride 53. Larger the pKb values of amin, weaker is the
37. Amongst the following amines, the strongest base in _____(Basic strength)
aqueous medium is 54. Explain carbylamine reaction with an equation by
a) CH3NH2 b) (CH3)3N c)(CH3)2NH d)C6H5NH2 taking methyl amine.
38. _______ are foul smelling substances( Isocyanide) 55. Nitrogen atom of amino group is_____hybridised.
39. Why diazonium salt is generally not stored and is used a)Sp b)Sp2 c)Sp3 d) Sp3d
immediately after its preparation? (It is very unstable and 56. Which of the following has highest pKb value?
dissociates to give Nitrogen) a)(CH3)3CNH2 b)NH3
40. Complete the following reaction by giving major products; c)(CH3)2NH d)CH3NH2
273𝐾−278𝑘 [Link] of aniline with benzene diazonium
ii) C6H5NH2 + NaNO2 + 2HCl → ? C6H5N2+Cl-
𝐵𝑟2 /𝐾𝑂𝐻 chloride in acidic mediumgives____
ii)R-CO+NH2 → ? R-NH2 (p-aminoazobenzene)
41. Explain Sandmeyer reaction with equation. 58. Explain Hinsberg’s test of differntiation of
[Link] IUPAC name of an amine (CH3)2N-C2H5. primary,secondary and tertiary amines.
a)N,N-Dimethylethanamine b)N,N-Dimethylpropanamine 59. Which of thr following amines is more basic in
c)1,1-Dimethylpropanamine d) N-Ethyl-N-methylethanamine aqueous medium
[Link] case of amines, the melting points are normally highest a) Dimethyl amine b)Methyl amine
for a)Primary amines b) Secondary amines c) Trimethyl amine d)Ammonia
c)Tertiary amines d) Quaternary ammonium slats 60. Which of the following amine does not react with
44. On heating Benzene diazonium chloride with Hinsberg’s reagent?
hypophosphorous acid the product obtained a) Primary amine b) tertiary amine
is______(Benzene) c) Secondary amine
d) Both Primary and secondary amine
45. How is aniline converted to phenyl isocyanide.
61. Gabriel pthalimide synthesis is used to prepare___amines [Link]’s reagent is
only (Primary) a)C6H5SO2 b) C6H5SO2Cl2
62. An aromatci compound A react with nitrous c) C6H5SO2Cl d) C6H5Cl2
acid(HNO2+HCl) at 273-278K to give a product B. It reacts with [Link] react with bromine and alkali to form
water give phenol. Name the product A and B. write the primary amine. The reaction is known as
balanced chemical equations.(A- C6H5NH2 B- C6H5N2+Cl-) a) Hoffmann reaction b) Kolbe’s reaction
63. Write IUPAC name of the following CH3-CH2-N-(CH3)2 b) Etard reaction d)Cannizzaro reaction
64. Why Hofmann’s bromamide reaction is called degradation 82. If the product obtained by an amine with
reaction? (Product has one carbon lesser than Hinsberg’s reagent is insoluble in NaOH solution,
reactant(amide) then the amine is
65. Among the following the stronger base in aqueous medium a) Primary amine b) Secondary amine
is c) Tertiary amine d) Either a) or c)
a)(CH3)3N b)NH3 83.p-hydroxyazobenzene is a_____(dye)
c)(CH3)2NH d)CH3NH2 84. The reagent used to convert benzenediazonium
66. Benzene diazonium chloride when warmed with water gives chloride to benzene is_____
a) Phenol b) Chlorobenzene c) Benzene d) Aniline a) H2O b) Cu2Cl2/HCl
66. The gas liberated when ethyl amine reacts with HNO2 is___ c) Cu/HCl d) CH3CH2OH
(Nitrogen/N2) 85. _____ is Hinsberg’s reagent.( C6H5SO2Cl)
[Link] is diazotisation? Write the equation. 86. Identify the more basic compound among Aniline,
68. Give the IUPAC name of trimethyl amine.(N,N-dimethyl 4-Nitroaniline, 4-methylaniline.( 4-methylaniline)
methanamine) 87.N-methylethanamine is a
[Link] on Hoffmann bromamide degrdation gives a)Primary amine b) Secondary amine
a) Methyl amine b) Ethyl amine c)Tertiary amine d) None of these
c) Propyl amine d) Ethyl cyanide 88. Hinsberg reagent is
70. The amine with more basicity in gaseous phase a) Benzene sulphonyl chloride
is____(Tertiary amine) b)Alcoholic potash
71. How does benzene diazonium chloride reacts with phenol? c) ammonical silver nitrate
Write chemical equation. d)Zinc amalgam and concentrated HCl
72. Primary, Secondary and Tertiary amines can be distinguished 89.p-amino azobenzene is____(dye)
by 90. How primary aliphatic amines react with nitrous
a) Schiff’s reagent b) Tollen’s reagent acid? Write general equation.
c)Fehling’s reagent d) Hinsberg’s reagent [Link] the equation for the reaction between
73. Amides on reduction with lithium aluminium hydride yield benzene diazonium chloride and phenol in basic
a) Nitriles b)Amines c) Alcohols d) Aldehydes medium. Mention the colour of the product.(orange)
74. Solubility of ethylamine in water is due to formation of 92. Mention the foul smelling substances formed
____bonding with water( Hydrogen) when a primary amine is heated with chloroform and
75. How do you convert an amide into primary amine having alcoholic potash.(Isocyanide)
one carbon atom less than the starting compound? Name the 93. The correct order of basic character among the
reaction. following in aqueous solution
76. Arylamines get coloured on storage due to i) NH3 ii) CH3NH2 iii) (CH3)2NH iv) )(CH3)3N
atmospheric_____(Oxidation) a) i<iv<ii<iii a) iv<i<ii<iii
77. How do you prepare benzene diazonium chloride by a) iv<ii<i<iii a) i<ii<iii<iv
diazotisation? Give equation 94. Amines are generally
78. Give reaso: Aromatic amines are weaker bases than a) Electrophilic b) Acidic
ammonia ( Due to resonance in aniline, lone pair of electron c) Basic d) Neutral
on Nitrogen is less available for protonation 95. Carbylamine reaction is answerd by
79. Write the general formula of diazonium salt.(ArN2+X-/ a)Carboxylic acid b)30 amines
RN2+X- c)20 amines d)10 amines
VASANTH KUMAR G
[Link] sulphonyl chloride will not precipitation with____
(30 amines)
97. Explain with a chemical equation for the conversion of
aniline to 4-bromoaaaniline
[Link] diazonium chloride reacts with phenol to form p-
hydroxy azobenzene in
a) acidic medium b) neutral medium
c) basic medium d) both acidic and neutral medium
[Link] of the following order of basic strength of amines in
aqueous solutions is correct?
a)(CH3)2NH >CH3NH2> (CH3)2N
b)CH3NH2> (CH3)3NH > CH3)2N
c)CH3)2N>(CH3)2NH > CH3NH2
d)(CH3)3N > (CH3)2NH>CH3NH2

VASANTH KUMAR G
VASANTH KUMAR G ALCOHOLS, PHENOLS AND ETHERS GPUC FOR GIRLS, PUTTUR
Alcohols, phenols, ethers 18. When phenol is treated with zinc dust___ formed
Preparatory-2024 (Phenol)
19. Identiify ‘A’ in the following reaction
𝐻𝐼
(CH3)3C-OC2H5→ C2H5OH + A (CH3)3C-I)
[Link] one among the follwowing can be
This reaction is dehydrated to an alkene when passed over Cu at
known as 3000C?
a) Reimer Tiemann reaction b) Kolbe’s reaction a)CH3OH b) CH3CH2OH
c) Cumene process d) Wurtz reaction c)CH3-CH(CH3)-OH d)(CH3)3C-OH
2. How is phenol manufactured by Cumene process ? [Link] of the following is most acidic?
3. Explain Kolbe's reaction with equation. a)phenol b)CH3CH2OH
𝑃𝐶𝐶,[𝑂] c)Picric acid d)p-Nitrophenol
4. CH3 -CH=CH-CH2OH → CH3 -CH=CH-CHO
5. Explain the mechanism of acid catalyzed dehydration of 22. When phenol is treated with Conc. HNO3 forms
ethanol to ethene. a) Anisole b)Picric acid c)Aspirin d)Salicylic acid
23. Denatured alcohol is
6. Name the main product formed in the following reactions
𝐶𝑢/𝐴𝑔,573𝐾 a)Etahnol+methane
ii) CH3 -CH2-OH → CH3 -CHO b)Rectifiedspirit+methanol+pyridine
7. which of the following has lowest boiling point? c)undistilled ethanol d)rectified spirit
a) phenol b)O-nitrophenol [Link] kolbe’s reaction
c)p-nitrophenol d) m-nitrophenol [Link] the product obtained when phenol is refluxed
[Link] happens when phenol is treated with NaOH solution in with chloroform in presence of aqueous sodium
the presence CHCl3. Give reaction hydroxide at 340K. Name the reaction
[Link] the following (Salicylaldehyde/2-hydroxy benzaldehyde, Riemer-
Tiemann )
26. What is the effect of -NO2 group on acidity of
Phenol + CH3I phenol (Increases)
10. Explain the mechanism of hydrolysis of ethene to ethanol [Link] Friedel Crafts acylation of anisole
11. Describe Williamson’s ether synthesis. 28. Quinol is an example for
[Link] reagent is a mixture of a) 10 alcohol b)Dihydric alcohol
a) Anhydrous ZnCl2 +Con HCl b) Aqueous ZnCl2 +Con HCl c) Phenol d) dihydroxy benzene
c) Anhydrous ZnCl2 +Dil HCl d) Dilute ZnCl2 +Con HCl 29. In case of anisole, by protonation of ether the ion
13. Which of the following compound is called Picric acid? formed is
a) p-Nitrophenol b) 2,4-Dinitrophenol a) Carbanion b) Carbocation
c) 2,4,6-Trinitrophenol d) 2,6-Dinitrophenol c) Methyl phenyl oxonium ion d) methyl ion
[Link] the compound which is more acidic than phenol: 30. Explain with equation cumene process name the
a) o-nitrophenol b) ethanol products.
c) o-methylphenol d) o-methoxyphenol 31. Convert salicylic acid into acetyl slaicylic acid with
15. In the hydroboration – oxidation reaction of propene with equation.
diborane, H2O2 and NaOH, the organic compound formed is [Link] organic compound A having molecular formula
a) H3C – CH2 – OH b) CH3 CH(OH) CH3 C6H5Cl react with sodium methoxide compound B is
c) CH3 - CH2 - CH2 - OH d) (CH3)3C – OH formed .B is treatede with acetyl chloride in the
presence of lewis acid gives two organic compound C
and D write chemical reaction and name of B,C,D.
33. What is denaturation of alcohol?
[Link] the product formed when 10 alcohls heated in 34. Which of the following has lowest boiling point?
presence of Conc.H2SO4 at 413K (diethyl ether) a)Phenol b)o-nitrophenol
c) p-nitrophenol d) m-nitrophenol
35. Rectifiedspirit is 49. Write equation of the following reaction and
a) ethyl alcohol mixed with methyl alochol mention the products. Friedel -Craft's acetylation of
b) 50 % ethanol + 50% water anisole
c) 95.5% ethanol + 4.4 % water 50. Acidic strength of different classes of alcohols
d) 75% ethanol +25% water follow the order___
[Link] the mechanism of hydrolysis of ethene to ethanol a) 30>20>10 b) 10>20>30
[Link] Williamson’s ether synthesis c) 20>30>10 d) 10>30>20
[Link] happens when phenol is treated with NaOH solution 50. Phenol gives benzene when treated with___
in the presence of CHCl3? Give reaction a) CO2 b) Zinc c) CHCl3 d) K2Cr2O7
[Link] general equations for the formation 10,20 and
30 alcohols from carbonyl compound using Grignard
reagent.
[Link] the product formed when tertiary butyl
bromide reacts with sodium methoxide. Write equation
[Link] the product in the reaction
𝐻2 𝑆𝑂4, 413 𝐾
CH3CH2OH →
a) CH3-CH3 b) CH3-CHO
c) CH3-O-CH3 d) C2H5-O-C2H5
[Link] the products, A and B in the following
This reaction is known as
reaction C6H5-O-R + H-X → A + B
a) Reimer-Tiemann reaction b) Kolbe’s reaction
[Link] acetylation of salicylic acid with equation.
b) c) Cumene process d) Wurtz reaction
56. Which of the following gas is liberated when
41. Which one of the following on oxidation gives a ketone
alcohol is treated with sodium
a) Primary alcohol b) Secondary alcohol
a) O2 b) Cl2 c) H2 d) CO2
c) Tertairy alcohol d) All of these
57. Resorcinol is an example of
42. How is phenol manufactured by Cumene process?
a) Monohydric phenol b) Dihydric phenol
43. Explain the mechanism of acid catalyzed dehydration of c) Trihydric phenol d) Tetrahydric phenol
ethanol to ethene [Link] the Following reaction
44. Name the main product formed in the following reactions
𝑃𝐶𝐶,[𝑂] 𝐶𝑢/𝐴𝑔,573𝐾
a) CH3-CH=CH-CH2OH → b) CH3-CH2-OH→
45. Explain Kolbe’s reaction with equation. 59. Name the product when phenol is treated with
46. Conversion of phenol to salicylic acid is bromine water.
a) Williamson’s reaction b)HVZ reaction 60. When phenol is treated with Conc. HNO3 forms
c) Kolbe’s reaction d) Wurtz reaction a) Anisole b) Picric acid
47. The enzyme which can catalyse the conversion of glucose c) Aspirin d) Salicylic acid
to ethanol is 61. Denatured alcohol is
a) Invertase b)Maltase c) Zymase d) Diastase a) Etahnol +methane
48. Identify A, B and C in the following reaction b) Rectified spirit + Methanol+pyridine
c)Undistilled ethanol
d) rectified spirit
62. With chemical equation, explain the preparation of
primary alcohol from Grignard reagent

A) CH3CHO B) CH3CH2OCH2CH3 C) CH2=CH2

VASANTH KUMAR G
[Link] the product formed in the following chemical 78. Give the composition of Lucas’s reagent
reactions 79. Structure of resorcinol
𝐻2 𝑆𝑂4, 413 𝐾
i) CH3CH2OH → ? (CH3CH2OCH2CH3)
𝐻𝐼
ii) (CH3)3C-OC2H5 → ? (CH3)3C-I + CH3CH2I
64. In the hydroboration-oxidation reaction of propene, with
diborane, H2O2 and NaOH the organic compound formed is 80. Identify the named reaction
∆
a) Ethyl alcohol b) Propan-2-ol CH3ONa +CH3I → CH3-O-CH3 +NaI
c) Propan-1-ol d) propanal a) Wurtz reaction b) Wurtz fittig reaction
c) Williamson’s ether synthesis d) Fittig reaction
65. When phenol is treated with bromine water it forms 81. Between water and alcohol which one is weaker acid?
a) m-bromophenol b) o- and p- bromophenol Give reason.
c)2,4-dibromophenol d)2,4,6-tribromophenol 82. Explain the mechanism of hydration of excess of
[Link] product obtained when tertiary butyl alcohol is ethanol into diethyl ether in the presence of acid catalyst
passed over heated copper at 3000C? at 413K
a)Aldehyde b)Alkene 83. Between o-nitro phenol and p-nitro phenol which one
c) Ketone d) carboxylic acid has less volatile? Give reason (p-nitrophenol,
[Link] alcohol that produces turbidity immediately when intermolecular H-bonding)
treated with Lucas reagent is 84. Anisole reacts with HI at 373K gives a mixture of
a)1-hydroxy butane b) 2-hydroxy butane a) C6H5I + CH3OH b) C6H5OH + CH3I
c)2-hydroxy-2-methylpropane d)1-hydroxy-2- c) C6H5CH2OH + CH3I b) C6H5OH + CH3CH2I
methylpropane 85. What is lucas reagent? Which class of alcohols
[Link] the product obtained when phenol is refluxed with produce immidiate turbidity with it at room temperature
chloroform in presence of aqueous sodium hydroxide at
340K. Name the reaction (Salicylaldehyde, Reimer-
Tiemann)
69. What is the effect of -NO2 group on acidity of phenol this reaction product ‘X’ is
70. Explain Friedel crafts acylation of anisole a) o-nitrophenol b) p-nitro phenol
71. How does anisole react with bromine in ethanoic acid? c)mixture of o- and p-nitro phenol
Give equation d) 2,4,6-trinitrophenol
72. Choose strogest acid among the following 87.2-chloro-2-methylbutane on reaction withalcoholic
a) 2-Nitrophenol b) 4-Bromophenol KOH gives X as the major product.
c) 4-Nitrophenol d)3-Nitrophenol a)2-methylbutan-1-ol b)2-methylbut-1-ene
73. An organic compound A reacts with chloroform in the c) 2-methylbut-2-ene d) 2-methylbutan-2-ol
presence of excess of base to give B. Identify A and B and 88. Which of the following will react fastest with Lucas
name the reaction. reagent?
(A-Sodium phenoxide, B-Salicyladehyde) a) Ethyl alcohol b) Isopropyl alcohol
74. Propanone on reaction with alkyl magnesium bromide c)tertiary alcohol d) all react at equal rate
ollowed by hydrolysis will produce 89. How is methanol manufactured form carbon
a) Primary alcohol b) Secondary alcohol monoxide and dihydrogen
c) Tertiary alcohol d) Carboxylic acid 90. What happens when phenol is treated with dilute
75. What happens when phenol is heated with zinc dust? nitric acid ? give reaction . Name the method used for the
Write equation separation of products.
76. What is the effect of following group on acidity of 91. p-nitrophenol is less volatile than o-nitrophenol due to
phenol. i)-NO2 (Increases) ii)-CH3 (decreases) a) intramolecular H-bond b) intermolecular H-bond
77. Explain williamson’s ether synthesis for the preparation c) Covalent bond d) ionic bond
of methoxymethane.

VASANTH KUMAR G
92. Phenol reacts with Zinc dust to give 109. Which of the following alcohol would react fastest
a) Benzene b) Benzoic acid with Lucas reagent at room temperature.
c) Benzaldehyde d)cumene a) Tertiary alcohol b) Secondary alcohol
93. Explain the preparation of propan-1-ol from propene c) Primary alcohol d) Tertairy amine
and the name the rule involved 110. Name the product formed when phenol is heated with
[Link] the equation for the preparation of t-butyl methyl i) Zn dust (Benzene) b)Chromic acid (Benzoquinone)
ether by Willimson’s synthesis. 111. Explain the prepartion of Anisole from Williamson’s
95. The enzyme that convert glucose and fructose into ether synthesis
ethanol is [Link] of the following is the least soluble in water
a) Zymase b) Diastase c) Invertase d) Maltase a)n-Butyl alcohol b) Methanol
96. How do you convert phenol into picric acid? Write the c)n-hexyl alcohol d)n-heptyl alcohol
equation 113. In allylic alcohol, the hydroxy(-OH) is attached to
97. Which of the following is an unsymmetrical ether? a) Sp3 carbon b) Sp2 carbon c) Sp carbon d) dsp2
a) C2H5O C2H5 b) CH3OCH3 carbon
c) C2H5OCH3 d)CH3CH2CH2OC3H7 114. Glycerol is an example for
98. Cresols are less acidic than phenol. Why? a) dihydric alcohol b) dihydric phenol
99. An example for simple ether is____ c) trihydric phenol d) trihydric alcohol
a) Methoxyethane b) Phenoxybenzene
c) Methoxy benzene d) Ethoxybenzene
[Link] phenol with higher acidic nature among the
following is___
a) 2,4,6-trinitrophenol b)2,4,6-Trimethylphenol
c) 3-nitrophenol d)3-methyl phenol
101. Among the following, trihydric alcohol is
a) Ethanol b) Ethylene glycol
c) Glycerol d) Propanol
[Link] Lucas reagent, immediate turbidity is produced
by
a) Primary alcohols b) Secondary alcohols
c) tertiary alcohols d)None of these
103. How is phenol converted to salicylic acid? Write
equation
104. When phenol is treated with excess of bromine water
it gives a) m-bromophenol b)o- and p-bromophenol
c)2,4-dibromophenol d)2,4,6-trinromophenol
105. Anisole on treatement with conc. HNO3 and Conc.
H2SO4 gives_____
a)Phenol b) o- and p-nitroanisole
c)Nitorbenzene d)m-nitroanisole
[Link] is salicylic acid converted to Aspirin? Write
equation.
[Link] Cumene process for the preparation of phenol
108. Which enzyme convert Glucose and fructose both into
ethanol
a) Diastase b) Invertase c) Zymase d) Maltase

VASANTH KUMAR G
VASANTH KUMAR G HALOALKANES & HALOARENES GPUC FOR GIRLS, PUTTUR
Preparatory-2024 24. Name the reagent used in Finkelstein reaction.
[Link] reacts with magnesium in dry ether to give Mention its role.
a compound A, A is 25. Define stereocentre? How many asymmetric carbon
a) C6H5OH b) C6H5 MgCl atoms are there in 2,3-dichlorobutane (2/two)
c) C6H5CH2 MgCl d) MgCl2 [Link] chemical name of phosgene is
2. The chlorofluorocarbon compounds of methane and a)Acetyl chloride b) methyl chloride
ethane are called___(Freons) c) carbonyl dichloride d) chloroform
2
3. Explain the Swart's reaction with an example. 27. SN mechanism has____ of configuration(Inversion).
[Link] : SN² mechanism with an example. 28. Name the product formed when chloromethane reacts
5. Give one reason : Aryl halides are less reactive towards with i) aqueous KOH ii) alcoholic KCN
nucleophilic substitution reaction. [Link] the isomeric pentyl chlorides, the one which
6. Explain Fittig reaction with an equation. has lowest boiling point is___
[Link] reactivity the following alkyl halides towards SN² a)n-pentyl chloride b)iso pentyl chloride
reaction is in the order c) neo pentyl chlorides d) Sec pentyl chlorides
a) CH3F< CH3Cl> CH3Br> CH3I 30. Freons are___ compounds of methane and
b) CH3F< CH3Cl> CH3Br< CH3I ethane.(Chloroflouro)
c) CH3F> CH3Cl> CH3Br> CH3I d)None of these 31. How is alcohol converted to chloroalkanes using
8. The substance which is not metabolized by the animals thionyl chloride? Write equation.
and many species of insects developed resistance to__(DDT) 32. The expected stereo chemical change of optically
9. Explain Swartz reaction with example. active haloalkanes during SN2 mechanism is
10. What are enenatiomers? Give example a) Racemisation b) Inversion
11. The Molecular formula of Freon-12 is c) Retention d) No stereochemical change
a)CF4 b) CF3Cl c)CF2Cl2 d) CFCl3 33. Why does SN mechanism is said to follow 2nd order
2

[Link] condition for optical activity is____(Chirality) kinetics.

[Link] react with KCN to forms alkyl cyanides as 34. Write the major product in the following reaction and
main product, while AgCN forms isocyanide as the Chief name the rule to support the major product.
𝐴𝑙𝑐𝑜ℎ𝑜𝑙𝑖𝑐 𝐾𝑂𝐻
product” Give reason. CH3-CH2-CH2-CH(Br)-CH3→ (pent-2-ene)
14. State ‘Saytzeff’s rule(Zaitsev) with an example. 2
35. Rate of reaction of SN depends on
15. Mention the condition to show an optical activity of an a) Concentration of haloalkanes
organic molecule. b) Concentration of nucleophile
16. Give an example for an alkylidene halide c) Both concentration of haloalakens and nucleophile
17. Define freons. Give an example. d) None of these
[Link] reaction involves the reaction of alkyl halide 36. Lucas reagent is mixture of conc. HCl
with__(Sodium) and____(Anhy.ZnCl2)
[Link] method of preparation of an alkyl fluoride by treating 37. Explain Wurtz-fitting reaction with an example
alkyl chloride with metallic fluoride 38. The method of preparation of an alkyl fluoride by
a)Finkelstein reaction b)wurtz reaction treating alkyl chloride with metallic fluoride is
c)Swartz reaction d)Fittig reaction a) Finkelstein reaction b)Wurtz reaction
20. 1-chlorobutane on reaction with [Link] gives c) Swartz reaction d) Fittig reaction
a)1-butanol b)2-butene c)1-butene d)2-butanol 39. Wurtz reaction involves the reaction of alkyl halide
21. The poisonous gas formed when chloroform is exposed with____
to air and light is__(Phosgene) 40. Define freons. Give an example
22. Aryl halides are less reactive than alkyl halides towards [Link] the condition to show an optical activity of an
nucleophilic substitution reactions. Give reasons organic molecule.
[Link] the reaction for the formation of fluoro methane 42. Give an example for an alkylidene halide.
from bromo metahne and name the reaction. 43. Alkyl magnesium halides are known as___(Grignard
reagent)
44.1-chlorobutane on reaction with alc. KOH gives 65. When chloroethane is reacted with alcoholic potash
a) 1-butanol b) 2-butene the hydrocarbon liberated is
c)1-butene d)2-butanol a) Ethane b) Propene c) Butene d) Ethene
45. Write the reaction for the formation of fluoro methane 66. The general formula of Grignard reagent
from bromo methane and name the reaction. is_____(RMgX)
46. The alkyl halide having highest boiling point is 𝑑𝑟𝑦 𝑎𝑐𝑒𝑡𝑜𝑛𝑒,∆
67. CH3Br +NaI → CH3I + NaBr. This
a)CH3I b) CH3Br c) CH3Cl d) CH3F
reaction is
[Link] gases liberated when primary alcohol react with
a) Finkelstein reaction b) Swartz reaction
sulphonyl chloride are a) H2 and HCl b) SO2 and HCl
c) Wurtz reaction d) Fittig reaction
c) SO2 and H2O d) SO3 and H2
68. ___ is used in the production of freon refrigerant R-
48. CCl2F2 is an example for______(Freons)
22 (Hydrochloroflurocarbon)
49. How can you obtain fluoro alkane from other haloalkane?
Name the reaction. [Link] for the optical activity is___
50. Along with chemical equation explain Friedel Craft’s a)Presence of superimposable mirror image
acylation reaction by taking chloro benzene as an example. b)Presence of plane of symmetry
51. Bromination of methane in presence of sunlight is a c)Absence of sterocentre
a) Nucleophilic substitution b) Free radical substitution d)Presence of non-superimposable mirror image
c) Electrophilic substitution d) Nucleophilic addition 70. For the same alkyl group, the boiling points of alkyl
52. Explain Friedel-craft’s acylation of chlorobenzene with halides vary as
equation. a) RI > RCl> RBr>RF b) RI > RBr> RCl>RF
53. What are enantiomers? c) RF > RCl> RBr>RI d) RI > RBr> RF>RCl
54. Equimolar mixture of dextro & leavo rotatory isomers is 71. Tetrachloromethane is_____(Carbon tetrachloride)
called_____ mixture (racemic) [Link] is the value of optical rotation of a racemic
55. Explain Swart’s reaction with balanced chemical equation mixture? (zero)
by taking ethyl bromide an example. 73. A grignard reagent may be made by reacting
56. Explain Fittig reaction by taking bromobenzene an magnesium with
example a)Methyl amine b)Diethyl ether
57. Name the reagents in the following conversions. c) Ethyl iodide d) Ethyl alcohol
i) Alkyl halide into alkene(Alcoholic KOH) 74. Swart’s reaction is useful in the synthesis
ii) Chlorobenzene into diphenyl (Na & dry ether) of___(Alkylfluoride)
58. What is grignard reagent? Why it is necessary to avoid 75. Give reason:
even traces of moisture from a grignard reagent? i) Chloroform is stored in closed dark bottles (To avoid
59. Reaction of chloroethane with chlorobenzene and sodium oxidation to form poisonous gas phosgene)
in the presence of dry ether is known as ii) p-dichlorobenzene has higher melting point than
a) Wurtz reaction b) Wurtz-Fittig reaction ortho and para isomers (due to symmetry)
c) Fittig reaction d) Friedel craft reaction 76. The halogen exchange method preferred for the
60. 2-chloro-2-methylbutane on reaction with alcoholic KOH preparation of alkyl iodide is
gives X as the major product. a) Finkelstein reaction b) Swartz reaction
a) 2-methylbutan-1-ol b) 2-methylbut-1-ene c) Wurtz reaction d) Fittig reaction
c) 2-methylbut-2-ene d) 2-methylbutan-2-ol 78. Alkyl Fluoride are synthesised by heating alkyl chloride
61. Number of chlorine atoms in DDT are____(5/Five) or alkyl bromide in presence of ___
62. What are recemic mixture? Mention its optical activity. a) Hg2F2 b) CoF2 c) AgF d) All of above
63. The IUPAC name of tertiary butyl chloride is [Link] an alkyl halide reacts with alcoholic AgNO3,
a) 2-chloro-2-methyl propane b) 3-chloro butane the main product obtained is____
c)4-chloro butane d)2-chloro-3-methyl propane a) Nitro alkane b)Nitro alkene
64. Write the mechanism involved in the following reaction: c)alkyl nitrate d) alkane isonitrile
CH3Cl + KOH → CH3OH + KCl Mention the order and [Link] undergo usually
configuration of the product (SN2 , second order kinetics a) Additionreactions b) Electrophilic reaction
Inversion) c) Nucleophilic reactions d)Elimination reaction
VASANTH KUMAR G CO-ORDINATION COMPOUNDS GPUC FOR GIRLS, PUTTUR

Preparatory -2024 25. The denticity of the ethylene diamine tetra acetate
[Link] co-ordination compound is used in the treatment of ligand is a) 2 b) 3 c) 1 d) 6
cancer tumors 26. Define ionization isomerism. Give an example.
a)Cis-platin b) trans-platin 27. What is spectrochemical series?
c)EDTA d) Diethyl glyoximate 28. Differentiate between strong field ligands and weak
[Link] is denticity? Give one example field ligands.
3. Write the IUPAC name of K2[Zn(OH)4] 29. The co-ordination compound is used in the treatment
[Link] are metal carbonyls? Explain Synergic pairing of cancer tumours.
effect in metal Carbonyl a) Cis-platin b) Trans-platin
5. The denticity of the ethylene diamine tetra acetate ligand c)EDTA d) Diethyl glyoximate
is a)1 b)2 c) 4 d) 6 30. Draw the geometrical isomers of [Fe (NH3)2(CN)4]-
6. Write the IUPAC nomenclature of the complex 31. What are Metal Carbonyls? Explain Synergic pairing
[Cr (NH3)3(H20)3JCl effect in metal Carbonyl
[Link] ionization isomerism. Give an example 32.[EDTA]4- is a
8. What is Spectrochemical Series ? a) Monodentate ligand b) Bidentate ligand
9. Differentiate between strong field ligands and weak field c) Polydentate ligand d) None of the above
ligands. 33. Define linkage isomerism of co-ordination
10. What are facial and meridional isomers? Give example. compounds? Give an example
11. Which of the following ligand if present in a complex 34. The formula of hexaammine cobalt (III) chloride
lead to the exhibition of linkage isomerism. is____
a)CN- b) -ONO c) Cl- d) EDTA a)[Co(NH3)6]Cl b)[Co(NH3)6]Cl2
[Link] the energy level diagram for the crystal field c) [Co(NH3)6]Cl3 d) [Co(NH3)6]Cl4
splitting in octahedral complexes. [Link] is homoleptic complex? Give an example.
13. Give an example for a complex exhibiting facial- 36. What is spectrochemical series?
merdional isomerism and write the isomeric structure of 37. Draw the structure of optical isomers of [CoCl2(en)2]+
that complex 38. What is the coordination number of Cr in
14. What is linkage isomerism? K3[Cr(C2O4)3]
15. Explain the splitting of d-orbitals in tetrahedral co- 39. according to CFT the electronic configuration of the
ordination sphere. central atom in [Fe(CN)6]+3 with d5 electrons is
[Link] synergetic bonding in metal carbonyls 3
a) 𝑡2𝑔 𝑒𝑔2 2
b) 𝑡2𝑔 𝑒𝑔3 c) 𝒕𝟓𝟐𝒈 𝒆𝟎𝒈 0
c) 𝑡2𝑔 𝑒𝑔5
[Link] the structure of Co(CO)8 complex 40. What is ambidentate ligand? Give an example
18. .Explain the spliting of d-orbital in tetrahedral co- 41. What type of isomerism is shown by coordinate
ordination sphere compound containing ambidentate ligand?
19. The more stable complexex containing 42. Which of the following is ambidentate ligand
a) Unidentate ligand b) Bi dentate ligand a) Cl- b) Br- c) SCN- d)NO+
c) Chelate ligand d) Ambidentate ligand 43. For the given complex [Co(NH3)Br] SO4. Write the
20. What are cationic complexes? Give one example. IUPAC name and its ionisation isomer.
21. Mention the type of isomerism exhibited by 44. Which set of d-orbiital of metal/ion experience more
[Co(H2O)6]Cl3 & [Co(H2O)5 Cl]Cl2. H2O. Write IUPAC repulsion in octahedral field created by the ligand? (eg)
names of the complexes. 45. The isomers of [Co(NH3)Br] SO4. Are an example for
22. Draw energy level diagram for crystal field splitting a) Linkage isomerism b) Co-ordination isomerism
in octahedral complexes. Write relation between ∆0 and c) Ionisation isomerism d)Solvate isomerism
pairing energy in weak field lligands. (∆0 <P) [Link] the structure of Co(CO)8 complex.
[Link] is heteroleptic complex? Give an example 47. The oxidation state of Ni in [Ni(CO)4] is
a) +2 b) 0 c) +3 d)+4
24. What are facial and meridional isomers? Give example

VASANTH KUMAR G
48. Which of the following ligand if present in complex 64. Oxidation state of iron in K4[Fe(CN)6] is
lead to the exhibition of linkage isomerism. a) +2 b) +3 c) +6 d) +4
a) :CN b) -ONO c) Cl d) EDTA [Link] are ambidentate ligands? Give one example
49. How many moles of AgCl is precipitated when 66. Based on the relative magnitudes of ∆0 (CFSE) and P
[Co(NH3)4Cl2] Cl reacts with AgNO3 (1 mole) (pairing energy) mention the conditions under which high
[Link] of the following is paramagnetic? spin and low spin complexes are formed.
a) [Ni(CO)4] b)[Co(NH3)6]3- 67. Metal-carbon bond in metal carbonyl possess
c)[Ni(CN)4]2- d) [NiCl4]2- a)σ charcter b) π Charcter
51. Write the cis and trans isomers for [CoCl2(en)2]+ c) both σ and π Charcter d) neither σ and π Charcter
52. Write the relation between ∆0 and ∆t for the complexes 68. How many ions formed when potassium
having same metal, the same ligand and metal-ligand hexacyanidoferrate(III) is dissolved in aqueous solution.
𝟒 a) 3 b) 4 c) 5 d) 6
distances.( ∆t = 𝟗 ∆0)
69. The oxidation state of metal ion in a complex
53. The Co-ordination number of the following complex is
represents a) Primary valency b) Secondary valency
[Co(en)2 Cl2]+ a) 2 b) 4 c) 6 d)5
c) Coordination number d) None of these
54. The co-ordination number of cobalt in the complex [Co
70. According to werner theory secondary valency of
(en)2(H2O)2] Cl is a)4 b) 2 c)6 d)3
metal corresponds to its
55. How many ions are produced from the
a) Oxidation number b) Co-ordination number
complex[Cr(NH3)6]cl3 in solution (4/Four)
c) Any of these d) Neither a nor b
56. A fraction of chlorine precipitated by solution from
1 𝟐 1 1
71. Primary and secondary valency of the complex
[Cr (NH3)3 Cl] Cl2 is a) 𝒃) 𝟑 c) 3 [Co(NH3)6]+3 are
2 4
57. Draw energy level diagram for the crysatl field splitting a) 4,6 b) 3,6 c) 2,3 d) 6,3
in octahedral complexes and write the electronic [Link] number of donar atoms in EDTA are
configuration for d4 ions when ∆0 >P (𝒕𝟒𝟐𝒈 𝒆𝟎𝒈 ) a) 2 b) 4 c) 6 d) 8
58. The crystal field theory considers the metal-ligand bond 73. A complex with hybridization sp3 will have the
to be a) Covalent bond b) Ionic bond geometry of a) Square planar b) Tetrahedral
c) polar bond d) Hydrogen bond c) Octahedral d) Trigonal bipyramidal
[Link] denticity of the EDTA ligand is 74. The concept of t2g is proposed in
a) 2 b) 6 c) 3 d) 1 a) Crystal field theory b) Pauling theory
-2
60. In [NiCl4] complex the hybridisation of nickel is c) Lewis theory d) Sidwick theory
a)d2sp3 b) sp3 c) sp3d2 d) dsp2 75. The t2g set of orbitals in octahedral complex is
61. Violet coloured[Ti(H2O)6]Cl3 becomes colourless upon stabilized by___ CFSE
heating. Why? (on heating removal of water molecule, a) 2/5 b) 3/5 c) 1/5 d) 1
due to absence of ligand ,crystal field does not occur) 76. The strong field ligand among the following is
62. What is the necessary condition required for the a) Cl- b) F - c) I - d) S -2
splitting up of ‘d’ orbitals in an octahedral complexes? 77. The catalyst used in polymerization of alkenes is
Draw the energy level diagram for thiis splitting. a) Wilkinson catalyst b) Ziegler-natta catalyst
63. The oxidation number of central metal ion in c) Pd-catalyst d) Zeise’s salt catalyst
complex[Cr(NH3)3(H2O)3]Cl3 is
a)+3 b) 0 c)+2 d)+6

VASANTH KUMAR G
VASANTH KUMAR G d & f BLOCK ELEMENTS GPUC FOR GIRLS, PUTTUR
Preparatory-24 24. Name the element with highest melting point in the
[Link] of the following clements are not regarded as 3d series of transistion metals(Cr/Chromium)
transition metals 25. In the transistion series the element with highest
a) Zn, V and Cd b) Zn, CO and Mn melting point is
c) Cd, Ti and Mn d) Zn, Cd and Hg a) Mn b)Fe c) Cr d) Cu
2. Lanthanoid contraction is due to increase in___(Effective 26. The basic character of the transistion metal
nuclear charge) monoxide follows the order
[Link] the differences between lanthanoides and actinoides a) VO>CrO>TiO>FeO b)CrO>VO>FeO>TiO
with reference to c)TiO>FeO>VO>CrO d)TiO>VO>CrO>FeO
i) Structural variability ii) Chemical reactivity 27. Transisition metals act as good catalyst. Write three
iii) Electronic configuration reason
4. Calculate the Magnetic moment of Mn²+ ion. (atomic number 28. Give any three differences between lanthanides and
of Mn =25) actinides
[Link] the transition series the element with highest melting point 29. Interstial compounds have____ melting point then
is a)Mn b) Fe c) Cr d) Cu those of pure metals.(High)
6. Interstitial compounds have___ melting point then those of 30. Calculate the spin only magnetic moment of
pure metals.(high) Mn+2(aq) ion (Z=25)
[Link] the spin only magnetic moment of Mn+2 ion(Z=25) 31. What is lanthanoid contraction? Write any two of
8. Brass is an Alloy of its consequences.
a)Cu+Zn b)Cu +Sn c) Cu + Mg d) Cu +Al 32. Acidified potassium dichromate oxidizes hydrogen
9. Calculate the spin only magnetic moment of Mn3+ ion(Z=24) sulphide to a) Sulphur b) Sulphur dioxide
10. Give any three General Characteristics of Actinoids. c) Sulphur trioxide d) allmof these
[Link] belongs to ___ in the modern periodic table. 33. The common oxidation state of actinide series
a) 7th period,III B group b) 7th period,III A group is______(+3)
c) 6th period,III B group d) 6th period,III A group 34. Calculate the magnetic moment of Ti3+ (Z=22)
12. Which of the following statements about the interstial 35. Element of 3d series which has maximum number
compound is incorrect of unpaired electrons in its ground state is___
a) They retain metallic conductivity a) Iron b) Manganese
b) They have higher melting points than the pure metal c) Cobalt d) Chromium
c) They are much harder than pure metal 36. The alloy misch metal consists of_____
d) They are chemically reactive (Lanthanides)
13. The metal used to make alloy steel for armour plates safes 37. What are interstial compounds? Mention their
and helmet is___(Mn-manganese) properties(any two)
14. The transistion elements forms coloured complex. Explian. 38. Which one of the following ions is colourless in
[Link] transistion elements acts as good [Link] any two aqueous solution?
reasons. a) Cr2+ b) Zn2+ c) Cu2+ d)Mn2+
[Link] the unit for magnetic momentum 39. The 3d series element which has positive EO value
[Link] is lanthanoid contraction? Mention any two is_____(Cu-copper)
consequences of lanthanoid contraction. 40. Calculate spin only magnetic moment of
[Link] only lanthanoid that shows radioactivity manganese[Z=25] in its lowest oxidation state
is___(Pm/Promethium) 41. The unit of magnetic moment is
[Link] aqueous solution cuprous ions undergo a) Kg.m b) Kg.m-2
a)oxidation b)reduction c) Bohrmagneton(B.M) d) Kg.m-3
c) Sublimation d) Disproportionation 42.____ gas liberated when Lanthanoids(Ln) reacts
21. Zn,Cd,and Hg are not regarded as d block elemennts. Why? with acids.
22. Calculate the spin only magnetic moment of V(III), (Z=23) 43. With reference to the first row transistion series
23. Ce(OH)3 is found to be more basic than Lu(OH)3. Give
reason
a)Name the metal which possesses maxiumum number of [Link] and Hf have identical atomic radii. Give reason
oxidation state [Link] any two reasons for the formation of large
b)Among Zn2+ and Cu2+ which is colourless? number of complex compound by transistion metals.
c)No of unpaired electron in Cr+ [Link] exhibit a greater range of oxidation state.
[Link] of the following statements about the interstial Give reason
compound is incorrect? [Link] of the following 3d series transistion metal ion
a)They retain metallic conductivity has colourless?
b)They have higher melting points than the pure metal a) Cu+2 b) Cu+ c) Cr3+ d) Fe+2
c)They are much harder than pure metal 69. The most stable oxidation state of copper is_____
d)They are chemically reactive. 70. How does K2Cr2O7 react with (i) I- ii) Fe2+ iii)
45. The metal used to make alloy steel for hamour plates,safes H2S to give I2 , Fe3+, S respectively. Write balanced
and helmet is___(Mn) chemical equations
46. Which of the following element is not regarded as 71. Write any three different between Lanthanides and
transition element? actinides
a) Fe b) Mn c)Sc d) Zn 72. The magnetic moment of divalent ion in aqueous
47. Mention the unit for magnetic momentum solution if its atomic number is 25 is
48. Zr and Hf have a almost equal atomic and ionic radii a) 5.92 BM b) 4.89 BM c)3.87 BM d) 2.82BM
because of ____ contraction (Lanthanoid) 73. Name the transistion element which does not exhibit
49. What is actinoid contraction? Give any two general +2 oxidation state (Scandium-Sc)
characteristics 74. Give reason for the followings
50. In aqueous solution cuprous ions undergo a) Actinoids show varaible oxidation states
a)Oxidation b)Reduction b) Cerium exhibit +4 oxidation states
c) Sublimation d) Disproportination c) The study of acitnoid element is difficult
51. The only Lanthanoid that shows radioactivity is___(Pm- 75. Which of the following are d-block elements but not
Promethium) regarded as transistion elements?
52. Zn,Cd, and Hg are not regarded as d- block elements. a) Cu,Ag,Au b) Zn, Cd,Hg c) Fe,Co,Ni d) Ru,Ph,Pd
Why? [Link] non-transistion metal present in bronze is___
53. Calculate the spin only magnetic moment of V(III), (Z=23) 77. Which of the following transistion metal ions is
54. Ce(OH)2 is found to be more basic than Lu (OH)3. Give colourless
reason (Lanthanoid contraction) a) V+2 b) Cr+3 c) Zn+2 d) Ti+3
55. Name the element with highest melting point in the 3d 78. The elements in which electrons are progressively
series of transistion metals. filled in 4f orbital are called___(Lanthanoids)
56. The non-transistion metal present in brass is___(Zn-Zinc) 80. Calculate the magnetic moment of Ti3+ ion[Z=22]
57. Calculate the spin only magnetic moment of Fe3+ 81. In 3d series the highest oxidation state is shown by the
ion(Z=26) element____(Mn/manganese)
58. Cu+2 salts are coloured. Give reason 82. Calculate the spin only magnetic moment of Cu+2
59. The common oxidation state exhibited by elements in 3d ion.(Z=29)
series is a) +7 b)+3 c)+2 d)+4 [Link]+ ion is not___ in aqueous solution(Stable)
60. Most of the Actinoids are___ in nature 84. Give reason: Transistion metals are paramagnetic in
61. Calculate the spin only magnetic momment of nature.
3+
M ion(z=26) 85. Number of unpaired electrons in Zn2+ is___
62. Colour of transition metals ions are due to absorption of a) 3 b) 2 c) 0 d) 1
some wavelenghth. This result in 86. A transition element with highest oxidation state is__
a) d-s transistion b)s-s transistion 87. Name the 3d series element that shows +1 oxidation
c) s-d transistion d) d-d transistion state. (Copper)
[Link] of TiCl4 and Al(CH2CH3)3 is called___ catalyst 88. Why is the study of actinoids is difficult?
(Ziegler Natta)
64. Calculate spin only magnetic moment of Cr3+ ion(Z=24)
VASANTH KUMAR G
89. The transistion element that do not show variable
oxidation state is____ a)Ti b)Sc c) Cu d)V
90. The number of unpaired electrons present in Fe3+(z=26)
is__(5/five)
[Link] the geometry of chromate ion
92.d-block element form complex due to
a)Small size and high ionic charges
b) large size and high ionic charges
C)Small size and low ionic charges
d) large size and low ionic charge
[Link] contraction is due to increase
in____(Effective nuclear charge)
94. The metallic bond strength in 1st transistion series
increases from
a) Sc to Cu b) Sc to Cr c) Cr to Zn d) Sc to Mn
95. The common oxidation state of d-block is +2 due to loss
of ___ number of 4s electrons(Two)

[Link] character decreases in the following oxides.

a) Mn2O7> MnO2>MnO b) MnO> MnO2> Mn2O7
c) Mn2O7>MnO> MnO2 d) MnO> Mn2O7> MnO2
VASANTH KUMAR G BIOMOLECULES GPUC FOR GIRLS, PUTTUR
Preparatory-2024 21. Sucrose is invert sugar. Give reason.
[Link] monosaccharide found in honey is 22. How is glycylalanine formed? Write the number of
a)Glucose b) Fructose c) Maltose d) Sucrose peptide bonds present in it.
2. Pick out which is not a hormone 23. Why cannot Vitamin-C stored in our body?
a) Cytosine b)Glucagon c) Steroid d) Epinephrine 24. Which of the following is water soluble vitamin
3. Write chemical reaction to show glucose contains. a) Vitamin-A b) Vitamin-K
i)six carbon atoms in a straight chain c) Vitamin-C d) Vitamin-D
ii) Presence of carbonyl group iii) Five – OH groups 25. The harmone regulates the blood sugar level is
4. What is zwitter ion of an amino acid? Give its general a) Insulin b) Thyroxine
structure. c) Adrenaline d) Corstisol
5. The carbohydrate which is essential constituent of plant [Link] the Haworth’s Structure of -D(+) Glucose
cell is a)Starch b) Cellulose c) Fructose d) Maltose 27. Name the disease caused by the deficiency of vitamin-
[Link] of the following constitute the genetic material of A
plant cell? a)Nucleic acid b) Proteins [Link] Vitamin B2 is also known as
c) Lipids d) Carbohydrates a)Thiamine b) Pyridoxine
[Link] are hormones ? Give examples c) Ascorbic acid d) Riboflavin
8. Name the disease caused by the deficiency of Vitamin C [Link] helical structure of protein is stabilized by
[Link] on oxidation with nitric acid gives a) Dipeptide bond b) Hydrogen bond
a) Saccharic acid b) Gluconic acid c) Peptide bond d) Ionic bond
c) Glyceraldehyde d) n-hexane 30. Define denaturation of protein. Give an example.
10. In DNA the linkages between different nitrogenous 31. Mention the glycosidic linkage present in lactose.
bases are 32. Give an example for a reducing sugar
a) peptide linkage b) phophate linkage 33. Define nucleotide
c) H-bonding d) Glycosidic linkage 34. How many peptide bonds are present in tetrapeptide.
11. What are non-essential amino acids? Name naturally [Link] any one sulphur containing amino acid.
occuring α-amino acid. Which is not optically active. 36. The main storage polysaccharide of plants is
[Link] i) Denaturation of protein ii) peptide linkage a) Starch b) Cellulose c) Glycogen d) Glucose
13. Give an example for water soluble vitamin. 37. Amongs naturally occuring - amino acids, the one
14. Maltose, a disaccharide is formed by___ which is not optically active is
a) two units o glucose a) Lysine b) Glycine c) Cysteine d)Alanine
b)one unit of glucose and one unit of gfructose 38. Which level of structure remains intact during
c) one unit of galactose and and one unit of glucose denaturation of globular proteins?
d) two unit of fructose 39. write the Haworth’s structure of Lactose.
15. The harmone/s which regulate/s the glucose level in the 40. What is fibrous protein? Name the protein present in
blood is are Hair.
a) Insulin b) Glucagon c) Thyroxine d) both a & b 41. The water-soluble component of starch is
[Link] number of peptide bonds present in a dipeptide a) Vitamin-C b) Amylopectin
is___ c) Amylose d) Galactose
17. Write the Haworth structure of Maltose. 42. Which of the following is a steroid hormone.
18. Name the notrogeneous base present in DNA but not in a) Insulin b) Glucagon c) Androgen d) Thyroxine
RNA. 43. Name the suagr moiety present in RNA
19. The oxidation of glucose to gluconic acid by bromine 44. Write the zwitter ionic structure of glycine.
water confirms that glucose molecule has 45. How do you account for the absence of free aldehyde
a) Carbonyl group b) Ketonic group group in the pentaacetae of D-glucose?
c) Hydroxyl group d) aldehydic group 46. Write the basic structural difference between starch
20. Xeropthalmia is due to the deficiency of and Cellulose.
a) Vitamin-A b) Vitamin-B c) Vitamin-D d) Vitamin-C 47. How many peptide bonds are present in hexapeptide
.48. The Nitrogenous base present in RNA but not in DNA is 71. The linkages which remain unaffected during
a) Thymine b) Uracil c) Adenine d) Guanine denaturation are
49. The hormone which is responsible for preparing the a) hydrogen bonds b) disulphide linkage
uterus for implantation of fertilized egg is c) Peptide bonds d) all these
a) Testosterone b) Estradiol 72. Name the nucleic acid which carries genetic
c) Glucocorticoids d) Progesterone information.(DNA)
50. The deficiency of which vitamine increases the blood 73. Which vitamin deficiency causes increases the blood
clotting time? clotting time? (vitamin-K)
[Link] the protein present in muscles. 74. Deficiency of Vitamin-C cause the disease called
52. Give an example fro invert sugar. a) Anaemia b) Scurvy c) Rickets d) Beri-beri
53. Among these which one can form Zwitter ion 75. Which of the follwing nitrogeneous base is not
a) CH3-COO-CH3 b) NH2-CH2-COOH present in DNA
c) H2N-CO-C2H5 d) CH3-CH2-COOH a) Uracil b) Adenine c) Cytosinne d) Thymine
[Link] correct base sequence of hydrogen bonding in DNA 76. Name the hormone responsible for preparing uteru
double helix structure for implantation of fertilized egg.( Progesterone)
a)A-C, T-G b)A-T, G-C c)G-C, A-C d)A-A, T-T [Link] one of the following acids is a Vitamin
55. Mention the two hormones which regulate the blood a) Aspartic acid b) Ascorbic acid
sugar level c) Adipic acid d) Saccharic acid
[Link] any two difference between amylose and [Link] number of peptide bonds present in a tetrapeptide
amylopectine. is
[Link] is nucleoside? Write any one function of RNA a) One b) Two c) Three d) Four
[Link] hormone is responsible for Hypothyroidism? 79. Give an example of a) Fibrous protein b) Globular
59. Deficiency of Vitamin-D causes protein
a) Scurvy b) beri-beri 80. Name the sugar present in DNA.
c) Rickets d) Muscular weakness 81. Cellulose is a polymer of
60. A nucleoside on hydrolysis gives a) Fructose b) ribose c) Sucrose d) Glucose
a) an aldopentose & a nitrogenous base 82. Among the following vitamins the one whose
b) an aldopentose & phosphoric acid deficiency causes rickets is
c) an aldopentose , a nitrogenous base & phosphoric acid a) Vitamin A b) Vitamin D c) Vitamin B d)Vitamin C
d) a nitrogenous base & phosphoric acid 83. water soluble component of starch is ____(Amylose)
61. Which of the following vitamin deficiency causes scurvy 84. Which of the following statement is wrong with
disease. respect to vitamins?
a) Vitamin-A b) Vitamin-D a) Vitamins A,D,K and E are fat soluble
c) Vitamin-E d) None of the above b) Vitamins B and C are water soluble
[Link] any two differences between DNA and RNA c) Deficiency of Vitamin B12 causes pernicious anaemia
63. Which Hormone increase glucose level in blood. d) Deficiency of vitamin D causes bleeding gums
64. The non-reducing sugar is 85. Write the zwitter ion structure of alanine.
a) maltose b) Sucrose c) Lactose d)Glucose 86. Name the fibrous protein present in hair , wool and
65. Which of thefollowing ‘B’ group vitamin can be stored silk.(Keratin)
in the body a) B1 b) B2 c) B6 d)B12 87. When does a protein lose its biological activity?
66. Name the monomer of nucleic acids. 88. The vitamin soluble in water is____
67. Give an example for amino acid derivatives Hormone a) A b) C c) D d) K
68. Name the disease caused by the deficiency of vitamin B6 89. Invert sugar is
69. Lysine is a/an a) Maltose b) Sucrose c) Lactose d) None of
a) Neutral amino acid b)acidic amino acid these
c) basic amino acid d) heterocyclic amino acid 90. What are reducing sugar? Is maltose a reducing
70. Name the optically inactive -amino acid sugar?

VASANTH KUMAR G
91. Name the naturally occuring amino acids which is
optically inactive.
92. The helical structure of protein is stabilized by
a)dipeptide bond b) peptide bond
c)Hydrogen bond d) ether bond
93. Glucose on oxidation with [Link] acid to give
a) Gluconic acid b) Glycolic acid
c) Saccharic acid d) Glucaric acid
94. Name the vitamin stored in adipose tissue and liver.
[Link] of the following is a poysaccharide?
a) Starch b)Glucose c) Fructose d) Maltose
96. Ascorbic acid is a chemical name of
a) Vitamin A b) Vitamin B c) Vitamin C d) Vitamin D
97. Name the bond present between two nucleotides.
[Link] is a chemical name of;
a) Vitamin A b) Vitamin B1 c) Vitamin C d) Vitamin K
99. The nitrogenous base adenine form hydrogen bonding
with a) Thymine b) Cytosine
c) Guanine d) None of the above
VASANTH KUMAR G ELECTROCHEMISTRY GPUC FOR GIRLS PUTTUR
1. During the electrolysis of conc. Sulphuric acid, the [Link] a spoon of copper metal is placed in a solution of
compound/ion liberated at anode is ferrous sulphate
a) H2 b) O2 c) S2O8 2- d) SO4 -2 a)Cu will precipitate b) Fe will precipitate out
[Link] conductivity of electrolytic conductors is due to _____. c)Cu & Fe precipitate d) no reaction will take place
a) Flow of free mobile electrons b) Movement of ions [Link] the electrolysis of sodium chloride, the gas
c) Either movement of electrons or ions d) Cannot be said liberated at anode is a) H2 b) O2 c) Cl2 d)N2
3. Name the electrolyte uses in dry cell. [Link] much electricity in terms of faraday is required
a) NH4Cl + KCl b) NH4Cl + ZnCl2 to produce one mole of Al from Al3+ ion?
c) KOH paste d) Zn-Hg/[Link] 1
a)1F b) 6F c) 3F d) 3F
4. Resistance of a conductivity cell filled with 0.02M KCl
[Link] charging the lead storage battery, PbSO4(s) on
solution is 520 Ω. Calculate the conductivity and molar
cathode is converted in to
conductivity of that solution.
a) PbO b)PbO2 c)Pb d) O2
5. Calculate the emf of the cell in which the following
[Link]’s law is applicable at_____
reaction take place, at 298 K: (Mg/Mg+2 (0.130M)// Ag+
27. Law used to determine the limiting molar
(0.0001M) /Ag) Given: Eo cell = 3.17 V
conductivity of weak electrolyte is
6. Calculate the equilibrium constant for the reaction at 250C:
a) Henry’s law b) Raoult’s Law
Cu(S) + 2 Ag+ (aq) → Cu2+(aq) + 2Ag(s) Eo cell =0.46V
c) Farday’s Law d) Kohlrausch’s Law
7. Electrical conductance through metals is called _______
[Link] of aqueous Sodium chloride will produce
8. What is conductivity? Write the SI unit of conductivity?
a) Sodium at cathode & Chlorine at anode
9. State Kohlrausch’s law of independent migration of ions.
b) Chlorine at cathode &Sodium at anode
[Link] the mathematical expression for limiting molar
c) Hydrogen at anode & Chlorine at cathode
conductivity of sodium chloride (NaCl).
d) Chlorine at anode & Hydrogen at cathode
11. Draw labelled diagram of Standard Hydrogen Electrode.
29. The reaction that take place at anode in an
Write half-cell reaction & Eo value by taking SHE as anode.
electrochemical cell is
12. What are Fuel cells? Mention one of its applications.
a)reduction b) oxidation
[Link] the electrode reaction taking place at cathode of H2
c) Hydrolysis d) None of above
- O2 fuel cell.
[Link] electrochemical cell can behave like a an electrolytic
Preparatory-24
cell when a) Ecell=0 b) Ecell> Eext c)Ecell< Eext d)Ecell= Eext
[Link] conductivity of electrolytic solution
15. The Quantity of electric charge required to reduce one
a) increase with dilution b) decrease with dilution
mole of MnO4- to Mn2+ a) 1F b) 3F c) 5F d) 2F
c)remain same d) None of these
16. Which of the following will not conduct electricity in
2. A certain half cell reaction X +e- → has very large
aqueous solution?
value of negative reduction potential this implies that
a) Sugar b) copper sulphate c) common salt d) none of
a) X can be readily reduced
these
b) X can be readily oxidized
17. The reaction is spontaneous if the cell potential is
c) X- can be readily reduced
a) negative b) positive c) zero d) infinite
d) X- can be readily oxidized
18. The potential difference developed between the electrode
3. Describe the construction and working of SHE with
and the electrode and the electrolyte is called___electrode p
neat labelled diagram
19. Calculate the rG at 298K for the cell reaction.
4. Write the cathodic ,anodic and overall reaction taking
Fe2+(aq)+Ag+(aq)→ Fe3+(aq)+Ag(s) (Given: E0cell=+0.03Vand
place in H2-O2 fuel cell.
F==96500C)
[Link] among is not used in the most common fuel
20. The conductivity of 0.001028 mol/L acetic acid is 4.95 X 10-5
cells? a)Hydrogen gas b)Metane
S/cm. Calculate its degree of dissociation if 𝝀m for acetic acid
c) Methanol d)Acetone
is 390.5 Scm2 mol-1
6. The amount of charge used to convert one mole of
21. Calculate the EMF of of cell in which the following
reaction take place Ni(s) + 2 Ag+(aq)→ Ni2+(aq)+ 2Ag(S) Al3+ to Al
Given[Ni2+]=0.160M and [Ag+] = 0.002M , E0cell =1.05V a)2,89,461 C b)19,2974 C c) 96500 C d) 48,2435 C
7. Explain the working function of lead storage battery OR [Link] the electrolysis of molten NaCl, the reaction
Write the equations for the reactions taking place at anode preferred at cathode is _____
and cathode for lead storage battery 1
a) Na+ + e-→ Na b) H+ + e-→ 2 H2
8. When Daniel cell is in use 1 1
a) Zn2+ are reduced to zn b) Zn is oxidized to Zn2+ c) Cl- + e- → 2 Cl2+ e- d) H2O + e- → 2 H2+ OH-
c) Cu is oxidized to Cu+2 d) Copper goes on dissolving 25. Between E0F2/F- = 2.87 V and E0Zn+2/Zn = -0.76 V which
9. The SI unit of molar conductivity is stronger oxidizing agent?
a)S b) m-1 c) Sm-1 d) Sm2 mol-1 26. What is the effect of dilution of an electrolyte solution
10. Name any two methods to prevent corrosion. on conductivity and molar conductivity?
11. State Faraday's First law of electrolysis. 27. Standard electrode potential of three metals X,Y and Z
12. The standard electrode potential for fluorine is the are -1.2V, +1.5 V, -3.2 V respectively, then reducing
highest in the electrochemical series indicating that fluorine power of the metal is
gas is a)X>Y>Z b)X>Z>Y c)Z>X>Y d)Z>Y>X
a)strong reducing agent b)weak reducing agent 28. Kohlrasch Law is applicable for
c)weak oxidizing agent d)Strong oxidizing agent a) Concentrated solution
13. The cathode in lead acid battery during discharging is b) Concentrated as well as dilute solution
a)Pb b)PbO2 c) PbO d)PbSO4 c) At infinite dilution d) None of these
14. Define limting molar conductivity 29. Standard reduction potential of hydrogen electrode is
15. Standard electrode potential refers to the electrode a)+1 b) 0 c)-1 d)Very high
potential of 30. Which of the following is the example for inert
a) The metal in combination with 1 mol L-1 solution of electrode? a) Gold electrode b)Copper electrode
its ions c) Zinc electrode d)Silver electrode
b) The metal in combination with its ions of any 31. How does molar conductivity vary with dilution?
concentration a) Decreases b) Increases
c) The metal in combination with 1 KgL-1 solution of its c) No change d) Inversely proportional
ions [Link] electrode potential refers to the electrode
d) The metal alone potential of
16. What is correct about H2-O2 fuel cell a)The metal in combination with 1 mol L-1 soution of its
a) Pt or Pd is used as catalyst ions
b)acidic conditions are maintained b) The metal in combination with its ios of any
c) water is electrolyzed d) Pt or Pd is used as concentration.
electrode c) The metal in combination with 1 Kg L-1 solution of its
17. State Kohlrausch’s law of independent migration of ions d) The metal alone.
ions. Mention two application of it. [Link] is correct about H2-O2 fuel cell
[Link] the balanced chemical equation for reaction that a) Pt or Pd is used as catalyst
occur at anode and cathode during rusting of iron. b)Acidic condition are maintained
19. In an electrolytic cell, the flow of electron is from c) Water is electrolysed
a) cathode to anode in solution b)cathode to anode d) Pt or Pd is used as electrode
through external supply 34.S.I. unit of conductivity is
c) cathode to anode through internal supply a) Sm b) Sm-1 c) ohm m-1 d) Sm-2
d) anode to cathode through internal supply 35. The standard electrode potential of the zinc electrode is
[Link] the electrolysis of dil H2SO4, the gas liberated at -0.76 V and that of the silver electrode is +0.8 . If the two
anode is a) H2 b) SO4-2 c) SO2 d) O2 electrodes are coipled the emf of the cell will be
[Link] the experimental determination of conductance a) 0.04V b)0.42V c)1.56V d)1.18V
of electrolytic solution by using Wheatstone bridge. 36. For the H2- O2 fuel cell, the reaction at cathode is
[Link] the electrolysis of molten NaCl using platinum a)2H2(g) +O2(g) → H2O(l) b) H+(aq) + OH- (aq)→ H2O(l)
electrodes the products liberated at a anode and cathode are 1
c) H+ + e- → 2 H2(g) d) O2(g)+ 2H2O
respectively.
a)Cl2 and Na b)Na and Cl2 c) Cl2 and H2 d) H2 and O2
[Link] the expression Q=It, t stands for___ 51. On which of the following the magnitude of
a)Temperature b) Time in second conductivity of a electrolytic solution does not depends?
c) Time in minutes d) Thermal stability a)Pressure b)Concentration of electrolyte
[Link] NaCl conducts electricity due to the presence of c)Temperature d) Nature of electrolyte
a) Free electrons b) Free molecules [Link] electrolyte used in lead storage battery is
c)Free ions d) atoms of Na and Cl a)NH4Cl +ZnCl2 b) 38% H2SO4
[Link] faradays of electricity passed through molten c) KOH +ZnO d) 38% HCl
Al2O3, aqueous solution of CuSO4 and molten NaCl. The 53. Electrolysis of aqueous sodium chloride(NaCl)
amount of aluminium, copper and sodium deposited at the produces
cathode will be in the ratio a) Sodium at cathode and H2 at anode
a)1 mol: 2 mol: 3mol b)1.5mol: 2 mol: 3mol b) Cl2 at anode and H2 at cathode
c)1 mol: 1.5mol: 3mol d)1 mol: 3mol: 2mol c) O2 at anode and H2 at cathode
[Link] Unit for molar conductivity d) Sodium at cathode and Cl2 at anode
a)S cm2 mol- a)S cm mol- c) S-1 cm2 mol- d)S-1 cm2 mol-2 [Link] of molar conductivity of acetic acid with
40. How many Coulombs are required for the following Concentration is correctly represented by
reactions: Al→ Al3+ + 3e-
a) 96500 x1 b) 96500 x2 c) 96500 x3 d)96500 x4
[Link] much electricity interms of Faraday is required to
reduce one mole of Cr2O7-2 to Cr3+
a)3F b) 6F c)4F d)2F 55. A galvanic cell after use is recharged by passing
42. If Eext > 1.1V is applied in the galavanic cell electric current through it. What type of cell is it? Give an
a) Electrons flow from Cu to Zn rod example with the anodic reaction took place in it.
b) Electrons flow from Zn to Cu rod 56. The degree on one mole of electron is
c) Current flow from Cu to Zn rod a) 1C b) 1F c)1.602 x 10-19C d) 9.1 x 10-31C
d) No flow of current or electron 57. During electrolysis of dilute sulphuric acid the product
43. A Smuggler could not carry gold by depositing iron on formed at anode is
the gold surface since a) S2O82- b) O2 c) SO2 d) H2
a) Gold is denser b) Iron rusts 58. An Example for secondary ceel is
c) Gold has higher reduction potential than iron a) Leclanche cell b) Daniel cell
d)Gold has lesser reduction potential than iron c) Mercury cell d) Nickel-Cadmium cell
44. Electrolysis of brine gives a mixture of 59. During electrolysis of aqueous sodium chloride, the
a) H2 ,Na, Cl2 b) H2 , Cl2, NaOH, gas liberated at anode is
c) H2 , O2 ,NaOH d) O2 , Cl2, NaOH a) Hydrogen b) Oxygen
45. Name the anode, cathode, and electrolyte used in Dry c) Chlorine d) Hydrogen chloride
cell 60. Which one of the following cell can convert chemical
46. The difference between the electrode potentials of two energy of H2 and O2 directly into electrical energy?
electrodes when no current is drawn through thye cell is a) Mercury cell b) Daniel cell
called a) Cell potential b) cell emf c) Fuel cell d) lead storage cell
c)potential differences d) Cell voltage 61. The quantity of electricity required to obtained one
47. The quantity of electricity required for the reduction of mole of Aluminium from Al2O3 is
one mole of Al3+ ions is a)1F b)2F c)3F d) 4F a)1F b)2F c)3F d) 4F
48. Standard electrode potential at 298K is ____ [Link] of the following cell was used in Apollo space
a)-0.76V b) 0.10V c)+0.34 V d)0.0V programme? a) Mercury cell b) Daniel cell
49. Fused NaCl on electrolysis, at cathode gives___ c) H2–O2 Fuel cell d) Dry cell
a) Chlorine b) Sodium
c) Sodium amalgam d)Hydrogen
[Link] molar conductivity. How is it related to
concentration and conductivity? Write the SI unit of
conductivity.
Preparatory-24(problems) 11. The resistance of 0.1 M solution is found to be 2.5 X
[Link] equlibrium constant for the following cell reaction 103 Ω. Calculate the molar conductance. Given cell
was found to be 6.509 x 108. Calculate the standard cell constant= 1.15 cm-1
potential Cd(s) + Sn+2(aq) )→ Cd+2(aq) + Sn(s) (R=8.314 JK-1 [Link] plating is carried out according to the
mol-1 ,F=96500C) equation
2. Calculate the molar conductance of 0.15M acetic acid CrO3 + 6H++ 6e- → Cr + 3 H2O, How long will it take to
solution if its conductivity at 298K is 1.6X 10-4 Scm-1 plate 1.5g of chromium if 12.5A current flows?(Atomic
mass of Cr=52, F=96500C)
[Link] resitance of a 1M salt solution occupying volume 13.A solution of NiNO3 is electrolysed between platinum
between two platinum electrodes 1.8 cm apart and 5.4 cm2 electrodes using a current of 5 amperes for 20 minutes.
in area was found be 32𝛺. Calculate the conductivity of a What mass of Ni is deposited at the cathode?
solution. [Link] limiting molar conductivity of calcium
[Link] the button cells, widely used in a watches and other sulphate , limiting molar conductance of calcium and
devices in the following reaction take place Zn(s) +Ag2O(s) sulphate ions are 119 and 160 S cm2 mol-1 respectively.
+H2O(l) →Zn2+(aq)+ 2Ag(s)+2OH-(aq). Determine ∆𝐺 for the 15. A solution of CuSO4 is electrolysed for 10 minutes
with a current of one ampere. What is the mass of copper
reaction (E0Zn = -0.76V and E0Ag= +0.34V)
deposited at the Cathode?(Atomic mass of Cu-= 63 g mol-
1,
[Link] resistance of 0.1 MKCI solution is found to be 520 𝛺 One faraday=96500 C mol-1
and shows a conductivity value of 0.248 S cm. Find the 16. at 298K, the E0Cell of the cell 2 Fe3+ +2I- → 2 Fe2+ +I2
value of cell constant. is 0.23 V. Find the equilibrium constant of the cell if free
energy change is -45.5 KJ
6. The molar conductivity at infinite dilution of Al (SO4)3 is
[Link] of a conductivity cell filled with 0.1 mol L-1
858 Scm2 mol-1, Calculate the molar ionic conductivity of
KCl solution is 100 Ω. If the resistance of the same cell
Al3+ ion, Given that 𝜆° SO42-= 160 Scm² mol-1
when filled with 0.02 mol L-1 KCl solution is 520 Ω.
[Link] resistance of 0.01M acetic acid solution is found to be Calculate the conductivity and molar conductivity of
220 𝛺, when measured in a cell has two electrodes of area of 0.02 mol L-1 KCl solution. The conductivity of 0.1 mol L-
1
cross section 3.8 cm2 placed 10.5cm apart. Calculate KCl solution is 1.29 S cm-1.
conductivity.

8. The conductivity of a 0.01M solution of acetic acid at

298 K is 1.65 X 10-4 S cm-1. Calculate dissociation constant
for acetic acid. (given for acetic acid=390 S cm2 mol-1)

9. 1 M solution of a salt surrounding two platinum

electrodes 2.1 cm apart and 4.2 cm2 in area was found to
offer a resistance of 50 ohm. Calculate the conductivity of
solution.
10. The conductivity of 0.001028 mol L- acetic acid solution
is 4.95 X 10-5 S Cm2 mol-1. Calculate degree of dissociation
of acetic acid, if limiting molar conductivity of acetic acid is
390.5 S Cm2 mol-1
VASANTH KUMAR G CHEMICAL KINETICS GPUC FOR GIRLS, PUTTUR

Preparatory-24 [Link] __ order reaction, units of both rate and rate

[Link] of a reaction is determined by constant are same.(Zero order)
a) balanced chemical equation [Link] the distribution curve showing temperature
b) experimental rate expression dependence of rate of the reaction.
c) unbalanced chemical equation d) Thermo-Chemical eq 23. For a reaction, A+B →products, the rate law is given
2. The molecularity of a reaction cannot be; by V= k [A]1[B]1, order of reaction is
a)Zero b) Fraction c) Both a and b d)Whole number a) First order b) Second order
[Link] rate of reaction at a particular moment of time is c) Third order d)Zero order
called [Link] half life period of _____ order reaction is directly
4. Define order of a reaction. For which order reaction the proportional to the initial concentration of reactant.(Zero)
unit of rate of reaction and rate constant same ? 25. The order of the reaction for decomposition of
[Link] of the following is an acceptable value of Hydrogen peroxide in alakline medium
molecularity? a) 5 b) 0 c) 3/2 d) 2 a) First order b) Second order
6. Molecularity of the reaction is always____(Intiger) c) Pseudo first order d)Zero order
7. Define collision frequency and temperature co-efficient. 26. The temperature dependence of the rate of a chemical
[Link] value of activation for a radioactive decay is reaction is explained by ____
a)High b)Low c) almost zero d) Moderate 27. Show that for the first order reaction, half life period
9. Which of the following is also known as ‘Trial and error’ is independent of initial concentration of the reactants.
method? 28. The rate law equation for the reaction:
a)integrated method b)isolation method A +2B→ C +D is rate ( r) =k [A], the order with respect
c) initial rate method d)Half-life method to ‘B’ a) Two b) One c)Zero d) All of these
10. The rate of a paticular reaction doubles when 29. The representation of rate of reaction in terms of
temperature changes. concentration of the reactant is known as____
11. The order of the reaction for the decomposition of 30. The conversion of molecules X to Y follows second
hydrogen peroxide in alakline medium. order kinetics. If the concentration of X is increased to
a) First order b) Zero order three times, how will it affect the rate of formation of Y
c) Second order d)Pseudo first order 31. Order of a reaction is determined by
12. The temperature dependence of the rate of a chemical a) Balanced chemical equation
reaction is explained by___(Arrehenius equation) b) Unbalanced chemical equation
13. Show that for the first order reaction, half life period is c) Experimental rate expression
independent of initial concentration of the reactants d) Thermo-chemical equation
14. Half life period is independent of intial concentration of 32. A catalyst _____ energy of activation.(Decreases)
reactant for a) First order b) Zero order 33. For a first order reaction, the half life period is 110
c) Second order d)Third order min. Calculate the time required to complete 75 % of the
[Link] pseudo First order Reaction. Give an example. reaction.
16. Acid hydrolysis of ethyl acetate is an example for 34. For the reaction P + Q →products, rate law is r =
a)Zero order reaction b) Pseudo first order reaction k[P]1/2 [Q]3/2 a) 1 b) ½ c) 0 d) 2
c) Second order reaction d) Fraction order reaction 35. According to the collision theory, the reactant
17. In a multistep reaction, rate of reaction depends molecules are assumed to be_____(Hard sphere)
on___(Slowest step) 36. The thermal decomposition of HI on gold surface is
18. Molecularity of reaction cannot be_____(Zero) an example of a) Zero order b) First order
19. Reperesent graphically the effect of catalyst on reaction c) Half order d) Second order
rates. 37. Molecularity of elementary reaction can be predicted
[Link] the reaction 2A +3B → 4C +D, which of the following only by _____ (Balanced chemical equation)
does not express average rate of the reaction ? 38. Radioactive desintigration is an example of
𝑑[𝐴] 𝒅[𝑪] 𝑑[𝐷] 𝑑[𝐵]
a) - b) - c) + d) - a) Zero order b) First order
2𝑑𝑡 𝟒𝒅𝒕 𝑑𝑡 3𝑑𝑡
c) Third order d) Second order
39. Gibb’s free energy of a reaction is not altered by the 57. What are the main criteria for effective collision
addition of____(Catalyst) according to collision theory
[Link] for fractional order of reaction is [Link] the reaction 2A + B→ A2B, the reactant A will
a) H2 + Cl2→ 2HCl b)H2 + I2→ 2HCI disappear at ___
b) H2 + F2→ 2HF d) H2 + Br2→ 2HBr a) Twice the rate that B will disappear
41. For the reaction 2N2O5→4NO2 + O2 The order of reaction b) Half the rate that B will disappear
is ____first order c) The same rate that B will disappear
42. Write any 2 difference between order and molecularity of d) D) The same rate that A2B will appear
the reaction. [Link] life of a first order reaction is 4 seconds, and
43. In a reaction when the concentration of reactant is the initial concentration of the reaction is 0.12 M, the
increased by nine times, the rate increases by 3 times. The concentration of the reactant left after 16 seconds.
order of the reaction is a) 3 b) 2 c) 1 d) 1/2 a)0.0075M b)0.06M c)0.03M d)).0015M
44. Define rate of a reaction. What is the unit of rate of 60.A reaction involving two different reactants in an
reaction? elementary reaction can never be___(unimolecular)
45. For a chemical reaction A→B, it is found that the rate of
Preparatory-24 (problems)
reaction doubles when the concentration of A is increased
[Link] the first order reaction, half-life period of the
four times. The order of the reaction is
reaction is 120 minutes, calculate the time taken to
a) two b) one c) half d) zero
complete 90%o of the reaction.
46. A reaction proceeds with a uniform rate throughout. The
2. The specific reaction rate of a reaction triples when
order is____Zero order
the temperature changes from 30C to 50°C. Calculate
47. For the first order reaction, the plot of lnR v/s t gives a
the energy of activation of the reaction (R =8.314 JK-1
straight line with slope equal to
𝒌 𝑘 𝑘
mol-1 )
a) - b) c) 𝑙𝑛 d) -k 3. The rate constant of a reaction at 500K and 700K are
𝟐.𝟑𝟎𝟑 2.303 2.303
48. Inversion of cane sugar is an example of____ 0.02 S-1 and 0.07S-1 respectively. calculate the energy
reaction(Pseudo first order). of activation of the reaction.
49. The half life period for a zero- order reaction is inversely 5. A reaction is found to have a rate constant 3.46 X 10-
5
proportional to the ___(rate constant) at 250C and rate constant 4.87 X 10-3 at 650C.
50. The number of collision per second per unit volume of Caculate activation energy for the reaction((R =8.314
reaction mixture is called as____(Collision frequency) JK-1 mol-1 )
51. For the reaction 2HI(g) → H2(g)+ I2(g), which of the 6. Rate of a reaction A B increases two times by
following relation is correct? increasing the concentration ‘A’ by four times, what is
𝑑[𝐻2 ] 𝑑[𝐼2 ] 1 𝑑[𝐻𝐼] 𝑑[𝐻2 ] the order of a reaction?
𝑎) − = b) 2 =
𝑑𝑡 𝑑𝑡 𝑑𝑡 𝑑𝑡
2𝑑[𝐻𝐼] 𝑑[𝐼2 ] 𝑑[𝐼2 ] 1 𝑑[𝐻𝐼]
7. Half -life period of a first order reaction is 30
c) - 𝑑𝑡 = 𝑑𝑡 d) = −2 seconds. Calculate the time required for the 2/3rd
𝑑𝑡 𝑑𝑡
52. For a reaction 2 NO(g) + O2(g) → 2NO2(g) the correct completion of the reaction.
expression for average rate of a reaction is____ [Link] rate of a particular reaction doubles when
a) ravg = +
∆[𝑁𝑂]
b) ravg = −
∆[𝑂2 ] temperature changes from 270C to 370C. calculate the
∆𝑡 ∆𝑡
1 ∆[𝑁𝑂] 1 ∆[𝑁𝑂2 ]
energy of activation.
c) ravg = + 2 d) ravg = − 2 9. The decomposition of N2O5 in CCl4 at 318K has
∆𝑡 ∆𝑡
53._____ of a reaction can not be fraction.(Molecularity) been studied by monitoring the concentration of N2O5
54. Define half life period of a reaction. Mention the order of a in the solution. Intially , the concentration of N2O5 is
reaction in which t1/2 is independent of concentration of the 2.33 mol L-1 and after 184 minutes it is reduced to 2.08
reactant. mol L-1 the reaction take place according to the
55. NH4NO2→ N2 +H2O is an elementary reaction. The equation.
molecularity is ____(one) 2N2O5(g) →4NO2(g) +O2(g) calculate the average rate of
56. Write Arrhenius equation realting the rate constant of a reaction in terms of minutes and the rate of production
chemical reaction and absolute temperature. What is Ea in the of NO2 during this period.
equation? VASANTH KUMAR G
10. The Initial concentration of N2O5 in the following first 26. The decomposition of Cl2O7 at 500 K in the gas phase to
order reaction N2O5(g) →4NO2(g) + ½ O2(g) was 1.24 x 10-2 Cl2 and O2 is a first order reaction. After 1 minute at 500K, the
mol L-1 at 318K. the [NO2] ater 60 minutes was 0.20 x 10-2 pressure of Cl2O7 falls from 0.08 to 0.04 atm. Calculate the rate
constant in s-1
mol L-1 at 318 K. Calculate the rate constant of the reaction
27. In first order reaction, the concentration of a reactant
at 318K.
decreses from 400 mol L-1 to 25 mol L-1 in 200 seconds.
[Link] constant of a reaction at 300 Kand 400 K are 0.0345
Calculate the rate constant for the reaction.
s-1 and 0.1365 s-1 respectively. Calculate the activation
28. Half life period of a first order reaction is 30 minutes.
energy for the reaction. (Given R= 8.314 JK-1mol-1)
Calculate the time required for 90% Completion of the
12.A first order reaction has a rate constant l.15 x 10-3 s-1.
reaction.
How long will 5 g of this reactant take to reduce to 3g?
29. For the first order reaction, show that the time taken
13. Rate constant of a first order reaction increases four
for 75% completion of the reaction is twice the time taken
times when the temperature canges from 270C to 470C.
for 50% completion of the reaction.
Calculate its activation energy. Given R =8.314 JK-1 mol-1 )
14. . Rate constant[k] of decay of a radioactive species is
[Link] a first order reaction, R→P the initial
found to be 5.5 x 10-14 s-1. Then find half life period and the
concentration of the reactant was 1.24 X10-2 mol L-1 at
time for 99.9 % decay of radioactive species
318 K. After 60 minutes its concentration was reduced to
15. For a first order reaction, the temperature coefficient of
0.20 x 10-2 mol L-1. Calculate the rate constant of the
the reaction is approximately 2. Calculate energy of
reaction at 318K
activation for the reaction(Ea) when temperature changes
from 300K to 310 K.( R =8.314 JK-1 mol-1 ) [Link] half life period of a first order reaction is 69.3
[Link] the rate constant of the first order reaction, If min. Calculate the time required for 75% completion of
70% of chemical reaction is completed in 23 mins the reaction
17. For a first order reaction, the half-life period is 120 min.
Calculate the time required to complete 90% of the reaction. [Link] specific reaction rate of a reaction doubled when
18. A first order reaction 40 min for 30% completion. temperature changes from 300C to 500C. Calculate the
Calculate the half-life period of the reaction. energy of activation of the reaction(R =8.314 JK-1 mol-1)

19. The energy of activation of a reaction is 60 kJ mol-1. If [Link] a first order reaction rate is 80% complete in 60
its rate constant at 310 K is 2 x 10-4 s-1. Calculate the rate minute. Find the half -life period (t1/2) of the reaction.
constant at 320K. (Given: R= 8.314 J K-1 mol-1)
[Link] rate constant of a certain reaction is 10 min-1.
20. Show that for a reaction, the time taken for the
Calculate the half-life period of this reaction in seconds.
completion of 99 % of the reaction is twice for the
completion of 90% of reaction [Link] rate constant of a reaction at 250K and 400K are
21. The rate constant for a reaction at 500 K and 700K are 0.01 s-1 and 0.03 s-1 respectively. Calculate the energy of
0.02 s-1 and 0.07 s-1 respectively. Calculate activation activation of the reaction(R =8.314 JK-1 mol-1)
energy (Given: R= 8.314 J K-1 mol-1)
22. The rate constant for a first order reaction is 60 s-1. How
much time will it take to reduce the intial concentration of
the reactant to its 1/16th value?
23. 60 % of first order reaction was completed in 60 minutes
calculate the time taken for 50% completed
24. The rate constant of first order reaction becomes 5 times
when the temperature is raised from 350K to 400 K.
calculate the activation energy(Ea) for the reaction.
25. The rate constant of a first order reaction at 600K is
1.60 x 10-5 s-1. Its energy of activation is 209 KJ/mol.
Calculate the rate constant of the reaction at 700K(Given R=
8.314 JK-1mol-1)

VASANTH KUMAR G
VASANTH KUMAR G SOLUTION GPUC FOR GIRLS, PUTTUR
Preparatory 2024 17. Define azeotropic mixture. Give an example for
[Link] water is an example for minimum boiling azeotropes
a) Binary solution b) Quaternary solution [Link] reason
c) Tertiary soution d) Not a solution i) Blood cell when placed in water swells (Osmosis)
[Link]-blood cell shrinks, when it is placed in a ii) Depression in freezing point of 0.1M aqueous
a) Hypotonic solution b) Hypertonic solution NaCl is nearly twice that of 0.1M glucose solution (
c) Isotonic solution d) saturated solution NaCl dissociate into two ions(Na+ &Cl-) number of
3. Give reason particle double where as glucose is non-electrolyte
a) soda water and soft drinks are sealed under high pressure does not dissociate)
(to increase the solubility of gas) 19. Increasing the temperature of an aqueous solution
b) The i-value or aqueous KCl is more than ethanol in will cause
benzene (because dissociation of KCl) a) decrease in molarity b) decrease in molality
4. Write any three differences between positive and c) decrease in mole fraction
negative deviation of Non-ideal solutions. d) decrease in mass %(w/w)
[Link] acid dissolved in benzene shows molecular mass 20.A solution of acetone in ethanol shows___
of a) 30 b) 60 c) 120 d) 180 deviation from Raolut’s law (positive)
[Link] solubility gas in liquids____ with the increase in 21. State Raoult’s law. Write its mathematical
temperature. (decreases) expression
7. Relative lowering of vapour pressure is equal to the [Link] any three characteristics of ideal solutions.
a) Mole fraction of the solute 23. Acetic acid dissolved in benzene shows a
c) Molarity of the solution molecular mass of a) 30 b) 60 c) 120 d) 180
b) Mole fraction of the solvent [Link] of gas in liquid is
d) Molality of the solution a)increases with increase in temperature
8. If solute is present in trace amounts, then conc is (b) Decreases with increase in temperature
expressed in_____(ppm/parts per million) (c) Unaffected on changing the temperature
9. Mention any two applications of Henry's law (d) Decreases with increase in pressure
10. What is the SI unit of molality.(mol/Kg) [Link] Henry's law, write its Mathematical forn.
[Link] of the following modes of expressing How does Henry's constant varies with the solubility?
concentration is dependent of temperature? 27. If blood cell is placed in a solution containing less
a) Molarity b) Mole fraction than 0.9%(mass/volume) sodium chloride, then the
c)Parts per million d) Molality cell will___(swell)
12. The relationship between mole fraction of gas in 28. What is the value of Van’t Hoff factor for
solution and partial pressure over the solution is given Na2SO4(Assuming complete dissociation) (3/Three)
by___(Henry’s law) [Link] boiling point is lowest for the equimolar
13. Define azeotropic mixture. Give an example for aqueous solution containing
maximum boiling azeotropes a) NaCl b)C6H12O6 c) BaCl2 d) La(NO3)3
14. What are hypertonic solutions? Give an example 30.A solution in which no more solute can be
15. The dissolution of gas in a liquid is governed by dissolved is called___ solution (saturated)
a) raoult’s law b) henry’s law [Link] of the solution obtained when copper
c) Boyle’s law d) Van’t Hoff factor dissolved in gold is
16. Solubility of a gas in liquid___ with decrease in a) Solid in solid solution b) Gas in gas solution
temperature (Increases) c) Liquid in liquid solution d) None of these
32.____ law behind the dissolution of CO2 gas in soft
under high pressure (Henry’s)
VASANTH KUMAR G
33. On mixing equal volumes of acetone and ethanol, what [Link] is the effect of increase in temperature on
type of deviation from Raoult’s law is expected?(positive) the solubility of a solid in liquid, if the process of
34. Low concentration of oxygen in the blood and tissues dissolution is a) exothermic (decreases)
of people living at high altitude is due to ______(low b) endothermic (Increases)
atmospheric pressure) 49. According to Henry’s law partial pressure of the
35. Mixture of acetone and ethanol shows positive gas in the vapour phase is proportional to its
deviation from raoult’s law. Give reason. (Ethanol- a) Molarity b) Molality
Acetone interaction is weaker than ethanol-ethanol c)Mole fraction d) Mass percentage
interaction) 50. The solutions which show a larger positive
36. The Van’t Hoff factor I for a dilute aqueous solution of deviation from Raoult;s law are
sucrose is a)Zero b) One c) Two d) Three called____azeotropes (Minimum boiling)
37. A solution in which no more solute can be dissolved at 51. If the solute dissociates in solution, Van’t Hoff
the same temperature and pressure is called____ factor is a)>1 b) 0 c) <1 d)=1
solution.(saturated) 52. The semi permeable membrane used in the
38. Negative deviation from Raoult’s law is observed in reverse osmosis is _____(Cellulose acetate)
which of the following binary liquid mixture 53. Aquatic species are more comfortable in cold
a) Etahnol & acetone b) Benzene+Toluene water rather than in warm water. This is due to
c) Acetone+Chloroform d)Acetone and carbon disulphide a) solubility of oxygen is more in warm water.
39. The van’t Hoff factor for acetic acid in benzene is____ b) solubility of oxygen is more in cold water.
40. What happens to the solubility of a gas in a liquid with c) solubility of gases increases with decrease of
increase in temperature ? Give reason. (Decreases, temperature. d) both (b) and (c)
because solubility of a gas in a liquid is Exothermic 54. How does the boiling point of solvent varies,
[Link] type of a azeotrope is formed by negative when a non-volatile solute is dissolved in it? Give
deviation from raoult’s law? Give an example (Maxium reason. (Boiling point increases, because adding
boiling azeotrope, 68% HNO3 +32% H2O) non-volatile solute vapour pressure of solvent
42. Which of the following conditions is not satisified by decreases)
an ideal Solution?
a)∆Hmixing=0 b)∆Vmixing=0 Extra:
c) Raoult’s law is obeyed
d) Formation of an azeotropic [Link] does Raoult’s law become a special case of
43. Osmotic pressure can be increased by___(increase in Henry’s Law?
concentration/Temperature) a) KH < P10 b)KH > P10
44. Molarity is b) c) KH =P10 d) None of these
a) Moles of solute/litre of solvent 2. The Cryscopic Constant Kf depends on
b) Moles of solute/litre of solution a) Nature of solute b) Nature of solute particles
c) Grams of solute /litre of solution c) Nature of solvent d) all the above
d) Moles of solute/kg of solvent 3. Wilted flowers revive when placed in fresh water
45. The unitless concentration term is______ due to
a)Mole freaction b) Mass percent a) Osmosis b) reverse osmosis
c)Molarity d) Both a & b c) diffusion d) effusion
46. Desalination of sea water can be done [Link] process of purification of sea water is
by_____(Reverse Osmosis) called_______(desalination)
47. Van’t Hoff factor for NaCl(assuming complete 5. Camphor dissolved in nitrogen gas is an example
dissociation) is_______(2/Two) for solution of the type;
a)Liquid in liquid b) Solid in liquid
VASANTH KUMAR G c) Solid in solid d) Solid in gas
6. Which of the following is a colligative property? [Link] 200C, the vapour pressure of pure liquid A is 22
a) Osmosis b) Osmotic pressure mm of Hg and that of pure liquid B is 75 mm of Hg.
c) Optical activity d) Boiling point What is the mole fraction of these two components in
7. Out of molality (m), molarity (M), parts per million a solution that has a vapour pressure of 48.5mm of Hg
(ppm) and mole fraction (x), which of this is temperature at this temperature( assuming ideal behaviour)
dependent? a) M b) x c) m
8.12.6 g of non -electrolyte is dissolved in 75g of
d) ppm
water. The freezing point of this solution is 271.9K.
8. The values Kb and Kf are are depends upon the nature
Calculate molar mass of the solute.(Freezing point of
a) solution b) solvent c) solute d) none of the
pure water & molar depression constant of water are
above
273.15K & 1.86 K Kg mol-)
[Link] the phenomenon of osmosis, the membrane allow
passage of 9.32g of unknown molecular solid is dissolved in
a) Solute only b) Solvent only 500g of water. The resulting solution freezes at 271.15
c) both solute and solvent d) none of these K. calculate the molar mass of this molecular
10. A solution in which no more solute can be dissolved at solid.(Given; Kf for water is 1.86 K Kg mol-1
the same temperature and pressure is called
a) Unsaturated solution b) dilute solution 10.800 cm3 of an aqueous solution of protein contains
b) Super saturated solution d) saturated solution 2.12 g of the protein. The osmotic pressure of such a
solution at 300 K is found to be 3.89 × 10-3 bar.
Preparatory -24 (problems) Calculate molar mass of protein. (R = 0.0823 L bar
𝑀 mol K-1).
[Link] the osmotic pressure of 5 %( ) solution of
𝑉
urea at 300K(Molar mass of urea is 60g/mol) [Link] vapour pressure of pure benzene at a certain
2. 18gm of Glucose (C6H12O6) is dissolved in 1 Kg of temperature is 0.850 bar. When a non-volatile, non
water in a saucepan. At what temperature will water boil electrolyte solid weighing 0.5 grams is added to 39
at 1.013 bar ? (kb for water is 0.52 K Kg mol-1, Molecular grams of benzene (Molar mass 78 grams). Vapour of
mass of glucose is 180 g/mol, B.P of water is 1000C) the solution is 0.845 bar. What is the molar mass of
3. An aqueous solution of glucose is 10% by mass of the solid substance?
glucose at 303K, the vapour pressure of pure water at 12. Vapour pressure of pure Chloroform(CHCl3) and
303K is 32.8mm of Hg. What is the vapour prssure of pure dichloromethane (CH2Cl2) at 298K are 200
solution? mmHg and 415 mmHg respectively. Total vapour
4. an aqueous solution of 0.6g of a solute X in 27.1 g of pressure of the binary s0oolution prepared by mixing
water freezes at 272.187K. If the cryosccopic constant of CHCl3 and CH2Cl2 at 298K is 348 mmHg. Calculate
water is 1.86 K Kg mol-1. Calculate the molecular mass of partial vapour pressure of more volatile component
X and its mole fraction in vapour phase of the solution.
5. Vapour pressure of dichloromethane (molar Mass = 13. Boiling point of water at 750mm Hg is 99.630C.
119.5g/mol) and chloroform (molar Mass 85g/mol) at How much sucrose [molar mass 342 g mol-1] is to be
298K are 200 and 415 mm Hg respectively. Calculate the added to 500 grams of water such that the solution
Vapour pressure of the solution prepared by mixing 25.5g boils at 1000C[Given Kb=0.52K kg mol-1]
dichloromethane and 40g of chloro form at 298 K 14. Solubility of a gas in water 0.001m STP.
Determine its Henry’s law constant.
[Link] pressure of benzene is 200mm of Hg. When 2 15. The vapour pressure of water is 12.3kPa at 300K.
gram of a non-volatile dissolved in 78 grams of benzene. Calculate Vapour pressure of 1 molal solution of a
Benzene has Vapour pressure of 195mm of Hg. Calculate non-volatile solute in it.
the molar mass of the solute.(molar mass of benzene is 78
g mol-
VASANTH KUMAR G
16. The mixture of 95% ethyl alcohol & 5% water by
volume shows which type of azeotrope?
a) Maximum boiling azeotrope
b)Minimum boiling azeotrope
c) Bothe Minimum and maximum boiling azeotrope
d) None of the above
[Link] Henry’s Constant (KH) value increase the solubility of
gas in liquid is____(decreases)
18. Calculate the mass of urea(NH2-CO-NH2) required to
making 2.5 Kg of 0.25 molal aqueous solution

VASANTH KUMAR G
VASANTH KUMAR G GPUC FOR GIRLS, PUTTUR

Aldehyde & Ketones (preparatory-2024) [Link] is Formalin?

[Link] reagent used to stop the oxidation of methyl benzene 21. Which of the following will not give aldol
to benzoic acid is Condensation?
a) CrO2Cl2 b) CrOCl2 c) Cr2OCl3 d) Cr2O2Cl a) acetaldehyde b) Phenyl acetaldehyde
2. On nitration of benzoic acid, the electrophile is substituted c) benzaldehyde d) 2-methyl pentanal
at a)Ortho position b)meta-position 22. Explain Cannizzaro’s reaction for benzaldehyde.
c)para position d) both O & P position 23. Give the mechanism for the addition of HCN to
3. How does ethanal(acetaldehyde)react with hydroxyl carbonyl compound.
amine? Write chemical equation [Link] a test to distinguish between aldehydes and
4. Explain aldol condensation reaction of ethanal ketones.
5. Name a test to distinguish between acetone and 25. The condensation product, Oxime is formed when an
acetaldehyde (Tollen’s reagent test) aldehyde or a ketone reacts with____
6. Identify B C6H6 →
𝐵,𝐴𝑛ℎ𝑦 𝐴𝑙𝐶𝑙3 /𝐶𝑢𝐶𝑙
C6H5CHO. Name the a) Hydrazine b) Semicarbazide
reaction. (B=CO,HCl, Gatterman-Koch reaction) c) Ammonia d) Hydroxylamine
26. Among the following carboxylic acids the strongest
7. Highest boiling point among the following compounds
acid is___
CH3CHO, CH3CH2OH, CH3COCH3, CH3-CH2-CH3
a) CH3COOH b) ClCH2COOH
a)CH3CHO, b) CH3CH2OH
c) Cl3CCOOH d) Cl2CHCOOH
c) CH3COCH3 d) CH3-CH2-CH3
27. Explain Rosenmund’s reduction with equation.
8.CH3-CHO +HCN → A: Compound A on hydrolysis givex
28. Write the IUPAC name of (CH3)2CHCOCH(CH3)2
a)CH3-CH2-COOH b)CH3- CH2-CH2-NH2
29. Give reasons for the more reactivity of aldehydes than
c)CH3-CO-COOH d)CH3-CH(OH)-COOH
ketones towards nucleophilic addition reactions.
9. CH3-CHO is more reactive than CH3COCH3 towards
𝑑𝑖𝑙 𝑁𝑎𝑂𝐻 𝐻𝑒𝑎𝑡
nucleophilic addition reaction. Give reason 30. 2CH3CHO → A→ B Identify A and B
10. Explain Clemmenson’s reduction with an example 31. Methanal on treating with Grignard reagent and
11. Explain aldol condensation reaction with example. followed by hydrolysis will give
[Link] agent used in Etard reaction is a)10 alcohol b)20 alcohol
a)H2-Pd b) CrO3 c) CrO2Cl2 d) KMnO4 c) 30 alcohol d) Mixture of alcohol
13. How do you prepare an aldehyde from acid chloride? 32. Complete the following reaction
Nam the reaction 𝑑𝑟𝑦 𝑒𝑡ℎ𝑒𝑟 𝐻3 𝑂 +
R-Mg-X +O=C=O → ? → ?
14. How does propanone reacts with hydrazine? Give
33. Among CH3-CH2-COOH and CH2=CH-COOH which
equation.
is more acidic? Give reason (CH2=CH-COOH, because
15. Name the reagent used in the Clemmensen reduction.
Carbonyl group attached to Sp2 hybridised carbon
(Zinc-amalgam and [Link])
atom which is more electronegative and make release
16. Explain Cannizzaro’s reaction taking benzaldehyde as an
of H+ ion easy
example write equation.
34. Why can’t formic acid be halogenated by Hell-
17. The role of Conc. H2SO4 in esterification reaction is
Volhard-Zelinsky reaction? (absence of α-hydrogen
a) As a catalyst b) as a Dehydratising agent
atom)
c) Both as a catalyst and dehydrating agent 𝑍𝑛−𝐻𝑔/𝐻𝐶𝑙
d) None of the above 35. R-CO-R→ A + H2O. Identify the product A and
18. Give name of the reagents to bring about following name the reaction.
transformations. 36. Explain the aldol condensation reaction of propanone
i)Hexan-1-ol to Hexanal with equation
ii) Cyclohexanol to cyclohexanone 37. Aldehydes and ketones both are identified by
iii)But-2-ene to ethanal. a)Tollen’s reagent b) Fehling’s solution
[Link] the reaction of Ketone with 2,4-DNPH with an c) Benedict’s solution d) 2,4-DNP
example. VASANTH KUMAR G
[Link] following aldehyde does not have the α-hydrogen [Link] the chemical equation for the reaction when
atom benzaldehyde is slightly heated with acetaldehyde in
a) CH3-CHO b) H-CHO presence of dilute alkali. Give the IUPAC name of the
c) CH3-CH2-CHO d) None of these product. (Cinnamaldehyde)
39. Explain esterification reaction and write the equation [Link] haloform reaction with an example.
40. Explain the mechanism of addition of HCN to aldehyde [Link] are generally less reactive than aldehydes,
in presence of NaOH Give reason?
41. Among formic acid and acetic acid, which is more acidic? 61. Identify the product in the following reaction
Give reason (acetic acid, because +I effect of methyl group CH3 -CO-CH3 + NH2OH →
in acetic acid destabilize the carboxylate ion) a)Oxime b) Hydrazone c) Imine d) phenyl
42. Explain Aldol condensation for acetaldehyde write the hydrazone
equation. 62. Ammonical silver nitrate is called
43. Complete the following reaction a) Fehling’s solution b) Benedicts’ reagent
c) Schiff reagent d) Tollen’s reagent
63. An acyl chloride ‘A’ is hydrogenated over catalyst
palladium on barium sulphate to form a carbonyl
compound ‘B’ which on heating with concentrated
sodium hydroxide forms the compound C and D. Identify
44. The catalyst used in Rosenmund reaction is the compound A,B,C and D
64. Complete the following reaction
a)Zn/Hg b)Pd/BaSO4 c) CO+HCl d) Raney Ni

45. Explain how an acetaldehyde forms an oxime

46. Mention the condition, that an organic compound to
undergo Cannizzaro reaction.(do not contain α-hydrogen
atom)
47. Write the product formed when benzaldehyde is heated
with Conc. NaOH (Benzyl alcohol/C6H5CH2OH,
Sodiumbenzoate/ C6H5COONa)
48. Explain how diethyl cadmium reacts with acetyl chloride. 65. Name the oxidizing agent used in Etard
49. Explain with chemical equation effect of heat on acetic reaction.(Chromyl chloride/ CrO2Cl2
acid with ammonia. 66. Benzoyl chloride on reduction with H2/Pd-BaSO4
[Link] IUPAC name of HCHO is produces
a) Formic acid b) Formaldehyde a) Benzoic acid b) benzyl alcohol
c) Methanal d) Methanol c) benzoyl sulphate d) Benzaldehyde
51. How an aldehyde prepared from nitriles? Write equation. 67. Complete the following reactions
What is the name of the reaction?
52. How is ketone prepared from Grignard reagent and
nitrile? Give an example. 68. Condition for aldol condensation
53. Explain Cannizzaro reaction with an example a)Aldehyde & ketone does not contain α-H atom
[Link] the IUPAC name of CH3COCH3 (propan-2-one) b)Aldehyde & ketone does not contain β-H atom
55. In an Etard reaction, the oxidizing agent used is c) Aldehyde & ketone contain α-H atom
a) CrO2Cl2 b) KMnO4 c) CrO3 d) Anhyd. ZnCl2 d)Aldehyde & ketone contain β-H atom
56. Explain Gattermann-Koch reaction with equation for the 69. Complete the following reaction . Name the product
preparation of benzaldehyde.
57. Complete the following reaction
𝑁𝑎𝑂𝐻+𝐶𝑎𝑂,𝐻𝑒𝑎𝑡
C6H5COONa→ A+Na2CO3 (Benzene/C6H6)

VASANTH KUMAR G
[Link] is the condition of reactant undergo haloform [Link] Wolf- kishner reduction reaction with an
reaction (Halogen atoms replace all three α-H atom in example.
base) 83. Aldehyde which does not undergo cannizzaro reaction
71. Which of the following cannot reduce Tollen’s reagent is a)HCHO b)CH3CHO
a) CH3COCH3 b) HCHO c) C6H5CHO d) all the there a,b & c
c) CH3CHO d) C6H5CHO 84. Complete the following reactions
𝑆𝑛𝐶𝑙2 +𝐻𝐶𝑙 /𝐻3 𝑂 +
72. R-CN → R-CHO. The name of the
reaction.
a) Rosenmund b) Stephen
c) Etard d) Gattermann Koch 85. Write balanced chemical equation and name the
73. Complete the following reactions reaction. Benzene is treated with CO & HCl in presence
of anhydrous AlCl3
𝑍𝑛−𝐻𝑔/𝐶𝑜𝑛.𝐻𝐶𝑙
i) CH3-CHO → ? 86.
[Link] is Formalin? (40% Formaldehyde solution)
88. The IUPAC name of acetone is
ii) a)1-propanal b)2-propanone
c)2-butanone d) Butan-2,3-dione
74. Complete the following reactions
89. Ketones react with hydroxyl amine to form
a)Imine b) Semicarbazone
c) Oxime d) Hydrazone
[Link] the reaction identify ‘A’ and ‘B’ and also name the
reaction
𝑑𝑖𝑙 𝐾𝑂𝐻 ℎ𝑒𝑎𝑡/ −𝐻2 𝑂
2CH3CHO→ A→ B
50% 𝑁𝑎𝑂𝐻 91. Write the equation for self condensation of ethanal in
75. 2HCHO → CH3OH +HCOONa. The above presence of dilute sodium hydroxide.
chenical reaction represent [Link] solution A is aqueous copper sulphate and
a) Rosenmund’s reaction b) Cannizzaro reaction fehling solution B is
c) Kolbe’s reaction d) Etard’s reaction a)Alkaline sodium potassium tartarate
76. Complete the eauation and anme the reaction b) Ammonical silver nitrate solution
𝑁𝑎𝑜𝑋
R-CO-CH3 → c) Conc. HCl and Anhy. ZnCl2
77. Write the mechanism for the addition of HCN to d) Zinc amalgam and conc. HCl
𝑍𝑛−𝐻𝑔/𝐶𝑜𝑛.𝐻𝐶𝑙
carbonyl compound. 93.CH3-CO-CH3 → ___ complete the
78. Explain aldol condensation using acetaldehyde. reaction and name of it.
79. Formaldehyde does not undergo aldol condensation. 94. What is Tollen’s reagent? (Ammonical silver nitrate
Give reason (absence of α-H atom) solution)
80. Hybridization of carbon of carbonyl group is [Link] Clemmenson reduction carbonyl compound is
a) Sp b)Sp3d c) sp3 d) sp2 treated with___ to form corresponding hydrocarbon
81. Complete the following reaction a)Sodium amalgam +HNO3 b) Sodium amalgam +HCl
c) Zinc amalgam +HNO3 d) Zinc amalgam+HCl
96. Name the product formed when acetone undergo
Wolf-Kishner reduction (propane)
97.

a)Rosenmund’s reaction b)Stephen’s reaction

c) Cannizzaro’s reaction d)Gatterman-Koch reaction

VASANTH KUMAR G
98. How do you prepare acetaldehyde from acetyl Carboxylic acid- preparatory-2024
chloride? Write the equation
99. Write the important condition required for the molecule
1.A Grignard reagent ‘X’ reacts with CO2(dry ice) followed
to undergo condensation reaction and Cannizzaro reaction
by acid hydrolyis gives ethanoic acid. Write chemical
100. Write the chemical equation for the reaction when
equation. Name the compound ‘X’ (CH3MgBr/methyl
benzaldehyde is slightly heated with acetophenone in the
magnesium bromide)
presence of dilute alkali. Give the IUPAC name of the
[Link] organic compound with molecular formula C6H5Br
product.
on treatment with Mg in dry ether gives compound ‘A’.
[Link] (α) -Hydrogens of aldehydes and ketones are The compound ‘A’ on treatemnt with CO2(dry ice) to form
acidic. Give reason.(Electron withdrawing nature of an addition compound ‘B’. Then ‘B’ on acid hydrolysis
carbonyl group) gives ‘C’. Identify the compound A,B and C.A-
C6H5MgBr/ Phenyl magnesium bromide
B- C6H5-COOMgBr C- C6H5COOH
3. Write decarboxylation reaction of sodium benzoate.
[Link] Hell-Volhard-Zelinsky(HVZ) reaction with
example
[Link] salt of carboxylic acids are converted into
hydrocarbons by
a)Dehydration b) Dehydrohalogenation
c) Decarboxylation d) Dahalogenation
[Link] values of three Carboxylic acids A,B and C are 12.3,
14.6 9.8 respectively. Arrange them in the increasing order
of their acidic strength. ( B<A<C)
[Link] esterification reaction and write the chemical
equation for the same.
[Link] is the effect of electron releasing group on the
acidity of carboxylic acids(Acidity decreases)
[Link] the effect of substituents on the acidity of
carboxylic acids.
[Link] is decarboxylation? Give one example
[Link] the gas liberated when a carboxylic acid reacts
with sodium hydrogen carbonate[NaHCO3]
[Carbon dioxide/CO2]
12. The carboxylic acids have higher boiling points than
aldehydes, ketones and alcohols due to
a) Intra molecular hydrogen bonding
b) Inter molecular hydrogen bonding
c) Dipole moment
d) Vanderwaals force of attraction
13. How is benzamide obtained from benzoic acid? Write
equation.
14. Carboxylic acids are obtained by treating Grignard
reagent with
a) Ice b) Dry ice c) water d) CO
15.A Carboxylic acid heated with alcohol in the presence
of concentrated sulphuric acid . Name the reaction.
(Esterification).Identify the major product formed during
VASANTH KUMAR G the reaction and write the general equation
[Link] acetic acid and Formic acid, which is more [Link] pka value of trifluoroacetic acid, benzoic acid,
acidic? Give reason ( Formic acid, carboxylate ion gets formic acid and acetic acid are 0.23, 4.19,3.75 and 4.76
destabilised by +I effect of -CH3 group in acetic acid respectively. The strongest acid among them is
17. Identify the most acidic halogenic carboxylic acid a) trifluoroacetic acid b) benzoic acid
a)FCH2COOH b) BrCH2COOH c) formic acid d) acetic acid
c) ClCH2COOH d)ICH2COOH 33. What is esterification? Write its general equation
18. ‘A’ carboxylic acid reacts with chlorine in presence of [Link] nitration of benzoic acid.
red phosphorous. Write the equation and name the [Link] the IUPAC name of formic acid (Methanoic acid)
compound ‘A’ (α- chloro carboxylic acid, Hell-Volhard- [Link] lime is a mixture of
Zelinsky(HVZ) reaction a) NaoH +MgO b) NaOH +CaO
c) KOH +ZnO d) KOH +CaO
[Link] of the following will not undergo HVZ reaction? 37. Identify ‘A’ and ‘B’ in the following reaction:
a)Propanoic acid b) Etahnoic acid 𝑑𝑟𝑦 𝑒𝑡ℎ𝑒𝑟,𝑅𝑒𝑓𝑙𝑢𝑥 𝐻3 𝑂 +
c)2-methylpropanoic acid A +CO2 (solid) → CH3COOMgBr → B
d) 2,2-dimethylpropanoic acid (organic compound)
[Link] the nfollowing acids which is more acidic 38. Carboxylic acids exist as dimer in the vapour state or in
a) Acetic acid b) Dichloro acetic acid the aprotic solvents. Why?(intermolecular hydrogen
c) Trichloro acetic acid d) Monochloro acetic acid bonding)
21. How benzyl alcohol and sodium benzoate are prepared [Link] product formed when a carboxylic acid is treated
from benzaldehyde in the presence of base(OH-) with phosphorouspentoxide(P2O5)
[Link] benzene is prepared from sodium benzoate by a) primary alcohol b) Acid anhydride
decarboxylation reaction. c)Amide d) Hydrocarbon
[Link] balanced chemical equation of the reaction of 40. Illustarte side chain oxidation of Toluene to Benzoic
acetic acid with ammonia to give ammonium acetate and acid
acetamide. 41. An alkyl magnesium halide ‘A’ reacts with
[Link] acid is more acidic in the following carbondioxide(dry ice) followed by acid hydrolysis to give
H-COOH (pKa=3.75), C6H5-COOH (pKa =4.19) compound ‘B’.on reduction with LiAlH4 ‘B’ gives
CH3-COOH (pKa=4.75) Compound ‘C’ on acidic dehydration compound give
25. Explain the preparation of carboxylic acids from ethene. Identify A,B and C (A-CH3MgX, B-CH3COOH,
Grignard reagent. C-CH3CH2OH)
26. What is the effect of -CH3 and -NO2 substituents on [Link] acids exist in dimeric form even in vapour
acidity of carboxylic acids? (-CH3 decreases and -NO2 phase due to
inreases the acidity of Carboxylic acid. a)Hydrogen bond b) peptide bond
27. What type of carboxylic acids undergo HVZ reaction c) Ionic bond d)metalic bond
28. In the decarboxylation of carboxylic acid, the reagent 43. Name the product formed when benzoic acid is nitrated
used is (m-nitro benzoic acid)
a) Sodamide b) Caustic Soda 44. Decarboxylating reagent is
c) Soda lime d) Quick lime a)NaOH b)NaOH +CaO
29. A Grignard reagent Y react with CO2(dry ice) followed c)[Link] d) Zinc dust
∆
by acid hydrolysis gives acetic acid. Then name the 45. Write the end product CH3COOH + NH3→ ___ +H2O
compound Y and write the reaction (Y= CH3MgBr/ (CH3CONH2)
methyl magnesium bromide)
[Link] the effect of electron donating group on the
acidity of carboxylic acids.(destabilise the carboxylate
ion ,acidity decreases
31. What is Jones reagent? (Chromium trioxide in
sulphuric acid/CrO3-H2SO4)
VASANTH KUMAR G
Extra:

1. Which represents the correct order of relative acidic strengths?

(a) HCOOH > CH3COOH > ClCH2COOH > C2H5COOH
(b) ClCH2COOH > HCOOH > CH3COOH > C2H5COOH
(c) CH3COOH > HCOOH > ClCH2COOH > C2H5COOH
(d) C2H5COOH > CH3COOH > HCOOH > ClCH2COOH

2.A carboxyl group directly attached to benzene ring

(a) activates the ring
(b) deactivates the ring
(c) exhibits o- and p-directive influence
(d) destabilizes the ring
3. Addition of NaHSO3 to formaldehyde is an example of
(a)nucleophilic addition (b) electrophilic addition
(c) eletrophilic substitution (d) nucleophilic substitution
[Link] cyanide adds on to aldehydes and ketones to form corresponding
(a)cyanohydrins (b) oximes
(c) cyanides (d) none of these