MATERIAL SAFETY DATA SHEET
MICROPOSIT REMOVER 1165
38680 4.00 US US MSDS_US
1.
CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Code Trade Name Manufacturer/Supplier Address 38680 MICROPOSIT REMOVER 1165 Shipley Company 455 Forest St. Marlborough, Massachusetts 01752 (508) 481-7950 (508) 481-7950 (800) 424-9300 28 October 1996 4 March 1999 Amy C. Nichols Shipley Company, 455 Forest Street, Marlboro, MA 01752 (508-481-7950)
Phone Number Emergency Phone Number Chemtrec # MSDS first issued MSDS data revised Prepared By: Local Sales Company
2.
COMPOSITION/INFORMATION ON THE INGREDIENTS
Components without CAS numbers are Trade Secret Component Name CAS# / Codes Concentration
1-methyl-2-pyrrolidinone Pyrrolidone Compound 872-50-4 94.00 - 95.00 5.00 - 6.00
3.
HAZARD IDENTIFICATION
Main Hazards Routes of Entry Carcinogenic Status Target Organs Health Effects - Eyes - Irritant - Combustible - Skin - Eye Inhalation, ingestion, eye and skin contact, absorption. Not considered carcinogenic by NTP, IARC and OSHA - Skin - Eye Liquid or vapor may cause conjunctival irritation and transient corneal damage. Material may cause slight irritation on prolonged or repeated contact. Repeated or prolonged contact may produce defatting of the skin leading to irritation and dermatitis. Swallowing may have the following effects: - irritation of mouth, throat and digestive tract - nausea - vomiting Page 1 of 7
Health Effects - Skin
Health Effects - Ingestion
MSDS_US
MATERIAL SAFETY DATA SHEET
MICROPOSIT REMOVER 1165
38680 4.00 US US MSDS_US
3.
HAZARD IDENTIFICATION
Health Effects - Inhalation Exposure to vapor may have the following effects: - irritation of nose, throat and respiratory tract
4.
FIRST AID MEASURES
First Aid - Eyes Immediately flush the eye with plenty of water for at least 15 minutes, holding the eye open. Obtain medical attention if soreness or redness persists. Wash skin with water. Obtain medical attention if blistering occurs or redness persists. Wash out mouth with water. Obtain medical attention. Remove from exposure. If there is difficulty in breathing, give oxygen. Seek medical attention if symptoms persist. Treat symptomatically.
First Aid - Skin
First Aid - Ingestion First Aid - Inhalation
Advice to Physicians
5.
FIRE FIGHTING MEASURES
Extinguishing Media Use water spray, foam, dry chemical or carbon dioxide. Keep containers and surroundings cool with water spray. This product may give rise to hazardous vapors in a fire. Vapors can travel a considerable distance to a source of ignition and result in flashback. Pressure may build up in closed containers with possible liberation of combustible vapors. Wear full protective clothing and self-contained breathing apparatus.
Special Fire-Fighting Procedures
Unusual Fire & Explosion Hazards Protective Equipment for FireFighting
6.
ACCIDENTAL RELEASE MEASURES
Spill Procedures Contain and absorb using earth, sand or other inert material. Transfer into suitable containers for recovery or disposal. Finally flush area with plenty of water.
MSDS_US
Page 2 of 7
MATERIAL SAFETY DATA SHEET
MICROPOSIT REMOVER 1165
38680 4.00 US US MSDS_US
6.
ACCIDENTAL RELEASE MEASURES
Personal Precautions Wear appropriate protective clothing. Wear respiratory protection. Eliminate all sources of ignition. Prevent the material from entering drains or water courses.
Environmental Precautions
7.
HANDLING AND STORAGE
Handling Use local exhaust ventilation. Avoid contact with eyes, skin and clothing. Keep container tightly closed when not in use. Store in original containers. Store away from sources of heat or ignition. Storage area should be: - cool - dry - well ventilated - out of direct sunlight
Storage
Other None known.
8.
EXPOSURE CONTROLS/PERSONAL PROTECTION
Occupational Exposure Standards An exposure limit of 25ppm is recommended. Can be absorbed 1-methyl-2-pyrrolidinone through skin. An exposure limit of 75ppm is recommended. (15min) Engineering Control Measures Engineering methods to prevent or control exposure are preferred. Methods include process or personnel enclosure, mechanical ventilation (local exhaust), and control of process conditions. Respiratory protection if there is a risk of exposure to high vapor concentrations. The specific respirator selected must be based on the airborne concentration found in the workplace and must not exceed the working limits of the respirator. Butyl rubber gloves. Chemical goggles. Normal work wear.
Respiratory Protection
Hand Protection Eye Protection Body Protection
9.
PHYSICAL AND CHEMICAL PROPERTIES
Physical State Color Liquid Natural, slightly white Page 3 of 7
MSDS_US
MATERIAL SAFETY DATA SHEET
MICROPOSIT REMOVER 1165
38680 4.00 US US MSDS_US
9.
PHYSICAL AND CHEMICAL PROPERTIES
Odor VOC (g/l) Specific Gravity pH Boiling Range/Point (C/F) Flash Point (PMCC) (C/F) Explosion Limits (%) Solubility in Water Vapor Density (Air = 1) Evaporation Rate Vapor Pressure Mild Amine 1030 1.03 Not applicable. 202/396 88 / 190 Lower limit 0.99 Completely soluble. Heavier than air. Slower than ether 1-methyl-2-pyrrolidone: 0.5 at 25 C.
10.
STABILITY AND REACTIVITY
Stability Conditions to Avoid Incompatibilities Hazardous Polymerization Hazardous Decomposition Products Stable under normal conditions. - High temperatures - Static discharge - Oxidizing agents - Acids - Reducing agents Will not occur. - carbon monoxide - Carbon Dioxide - oxides of nitrogen
11.
TOXICOLOGICAL INFORMATION
Acute Data Chronic/Subchronic Data 1-methyl-2-pyrrolidone: Dermal LD50 (rat) 8000mg/kg. The negative mutagenic findings together with equivocal results from long-term animal studies suggest that it is unlikely to be a carcinogen. It was not mutagenic when tested in bacterial or mammalian systems. Developmental effects were seen in laboratory animals only at dose levels that were maternally toxic. Experimental studies in animals have provided some evidence of embryo/fetotoxicity and birth defects only at doses producing marked maternal toxicity. None known. Page 4 of 7
Genotoxicity
Reproductive/Developmental Toxicity
Additional Data
MSDS_US
MATERIAL SAFETY DATA SHEET
MICROPOSIT REMOVER 1165
38680 4.00 US US MSDS_US
11.
TOXICOLOGICAL INFORMATION
12.
ECOLOGICAL INFORMATION
Mobility The product will dissolve rapidly in water. The product is poorly absorbed onto soils or sediments. The product will leach into soil. The product is expected to be readily biodegradable. Product is not expected to bioaccumulate. The product may be harmful to aquatic organisms.
Persistence/Degradability Bio-accumulation Ecotoxicity
13.
DISPOSAL CONSIDERATIONS
Product Disposal Incineration is the recommended method of disposal. Dispose of in accordance with all applicable local and national regulations. Labels should not be removed from containers until they have been cleaned. Empty containers may contain hazardous residues. Dispose of containers with care.
Container Disposal
14.
TRANSPORT INFORMATION
DOT Ground: UN Proper Shipping Name UN Class UN Number UN Packaging Group N.O.S. 1: N.O.S. 2: Subsidiary Risks ADR/RID Substance Identification Number CERCLA RQ Marine Pollutant Not Regulated per 49 CFR 173.150(f)(2) Not Regulated Not applicable. Not applicable. Not applicable. Not applicable. Not applicable. None. None assigned. None. No.
MSDS_US
Page 5 of 7
MATERIAL SAFETY DATA SHEET
MICROPOSIT REMOVER 1165
38680 4.00 US US MSDS_US
15.
REGULATORY INFORMATION
TSCA Listed All components of this product are listed on the U.S. Toxic Substances Control Act Chemical Inventory (TSCA Inventory) or are exempted from listing because a Low Volume Exemption has been granted in accordance with 40 CFR 723.50. U.S. exporters of this product are required to notify the U.S. Environmental Protection Agency (EPA) that a regulated substance(s) is leaving the U.S. market. This product contains the following substance(s) which are subject to Section 12(b) export notification: - 1-Methyl-2-pyrrolidinone (CAS# 872-50-4) D.2.B B.3 All components have been checked for inclusion on the Massachusetts Substance List (MSL). Those components present at the de minimus concentration have been identified in the hazardous ingredients section of the MSDS. This product does not contain materials which the State of California has found to cause cancer, birth defects or other reproductive harm. Immediate, delayed health hazard This product contains a chemical which is listed in Section 313 at or above de minimis concentrations. The following listed chemicals are present: (quantity present is found elsewhere on this MSDS) - 1-methyl-2-pyrrolidinone (872-50-4)
TSCA Exemptions TSCA Sec.12(b) Export Notification
WHMIS Classification MA Right To Know Law
California Proposition 65
SARA TITLE III-Section 311/312 Categorization (40 CFR 370) SARA TITLE III-Section 313 (40 CFR 372)
16.
OTHER INFORMATION
NFPA Rating- FIRE NFPA Rating- HEALTH NFPA Rating- REACTIVITY NFPA Rating- SPECIAL Revisions Highlighted Abbreviations 2 1 0 None.
CAS#: Chemical Abstract Services Number ACGIH: American Conference of Governmental Industrial Hygienists OSHA: Occupational Safety and Health Administration TLV: Threshold Limit Value PEL: Permissible Exposure Limit Page 6 of 7
MSDS_US
MATERIAL SAFETY DATA SHEET
MICROPOSIT REMOVER 1165
38680 4.00 US US MSDS_US
16.
OTHER INFORMATION
STEL: Short Term Exposure Limit NTP: National Toxicology Program IARC: International Agency for Research on Cancer R: Risk S: Safety LD50: Lethal Dose 50% LC50: Lethal Concentration 50% BOD: Biological Oxygen Demand Koc: Soil Organic Carbon Partition Coefficient. TLm: Median Tolerance Limit TLm: Median Tolerance Limit Disclaimer The data contained herein is based on information that Shipley Company believes to be reliable, but no expressed or implied warranty is made with regard to the accuracy of such data or its suitability for a given situation. Such data relates only to the specific product described and not to such products in combination with any other product and no agent of Shipley Company is authorized to vary any of such data. Shipley Company and its agents disclaim all liability for any action taken or foregone on reliance upon such data.
MSDS_US
Page 7 of 7
