JEE (Main)-2022 : Phase-2 (26-07-2022)-Morning
CHEMISTRY
SECTION - A Choose the correct answer from the options given
Multiple Choice Questions: This section contains 20 below :
multiple choice questions. Each question has 4 choices (A) (A)-(III), (B)-(I), (C)-(II), (D)-(IV)
(1), (2), (3) and (4), out of which ONLY ONE is correct.
(B) (A)-(III), (B)-(II), (C)-(I), (D)-(IV)
Choose the correct answer :
(C) (A)-(IV), (B)-(III), (C)-(I), (D)-(II)
1. Match List-I with List-II.
(D) (A)-(IV), (B)-(II), (C)-(III), (D)-(I)
List-I List-II
(Compound) (Shape) Answer (B)
V2 O5
(A) BrF5 (I) bent Sol. (A) 2SO2(g) + O2(g) 2SO3
(B) [CrF6]3– (II) square pyramidal Pt(s) Rh(s)
(B) 4NH3(g) + 5O2(g)
(C) O3 (III) trigonal bipyramidal
4NO(g) + 6H2O(g)
(D) PCI5 (IV) octahedral
(C) N2(g) + 3H2(g)
Fe(s)
2NH3(g)
Choose the correct answer from the options given
below : (D) Vegetable oil(l) + H2
Ni(s)
(A) (A)-(I), (B)-(II), (C)-(III), (D)-(IV)
Vegetable ghee(s)
(B) (A)-(IV), (B)-(III), (C)-(II), (D)-(I)
3. Given two statements below:
(C) (A)-(II), (B)-(IV), (C)-(I), (D)-(III)
Statement I : In Cl2 molecule the covalent radius is
(D) (A)-(III), (B)-(IV), (C)-(II), (D)-(I)
double of the atomic radius of chlorine.
Answer (C)
Statement II : Radius of anionic species is always
Sol. (A) BrF5 – square pyramidal
greater than their parent atomic radius.
(B) [CrF6]3– – octahedral
Choose the most appropriate answer from options
(C) O3 – bent
given below:
(D) PCI5 – trigonal bipyramidal
(A) Both Statement I and Statement II are correct.
2. Match List-I with List-II.
List-I List-II (B) Both Statement I and Statement II are
(Processes/ (Catalyst) incorrect.
Reactions) (C) Statement I is correct but Statement II is
(A) 2SO2(g) + O2(g) (I) Fe(s) incorrect.
2SO3(g) (D) Statement I is incorrect but Statement II is
(B) 4NH3(g) + 5O2(g) (II) Pt(s) – Rh(s) correct.
4NO(g) + 6H2O(g) Answer (D)
(C) N2(g) + 3H2(g) (III) V2O5 Sol. • Covalent radius is not double of atomic radius.
2NH3(g) • Radius of anionic species is always greater
(D) Vegetable oil(l) + H2 (IV) Ni(s) than their parent atomic radius as nuclear
Vegetable ghee(s) charge decreases in anionic counterpart.
-9-
JEE (Main)-2022 : Phase-2 (26-07-2022)-Morning
4. Refining using liquation method is the most suitable 8. Which of the given reactions is not an example of
for metals with: disproportionation reaction?
(A) Low melting point (A) 2H2O2 2H2O + O2
(B) High boiling point (B) 2NO2 + H2O HNO3 + HNO2
(C) High electrical conductivity (C) MnO 4 4H 3e MnO 2 2H2 O
(D) Less tendency to be soluble in melts than (D) 3MnO 24 4H 2MnO 4 MnO 2 2H2 O
impurities
Answer (C)
Answer (A)
7 4
Sol. Refining using liquation method is the most suitable Sol. MnO 4 4H 3e MnO2 2H2O
for metals with low melting point. The above reaction involves the reduction of MnO4
5. Which of the following can be used to prevent the to MnO2.
decomposition of H2O2?
9. The dark purple colour of KMnO4 disappears in the
(A) Urea (B) Formaldehyde titration with oxalic acid in acidic medium. The
(C) Formic acid (D) Ethanol overall change in the oxidation number of
manganese in the reaction is :
Answer (A)
(A) 5 (B) 1
Sol. Urea is used as a stabilizer for the storage of H 2O2.
(C) 7 (D) 2
6. Reaction of BeCl2 with LiAlH4 gives :
Answer (A)
(A) AlCl3
7
(B) BeH2 Sol. 2K MnO4 5H2 C2O4 3H2SO 4
2
(C) LiH
K 2 SO4 2MnSO 4 10CO2 8H2 O
(D) LiCl
Change is oxidation state Mn is 5.
(E) BeAlH4
10. Cl CH4 A B
Choose the correct answer from options given
below : A and B in the above atmospheric reaction step are:
(A) (A), (D) and (E) (B) (A), (B) and (D)
(A) C2H6 and Cl2 (B) CHCl2 and H2
(C) (D) and (E) (D) (B), (C) and (D)
Answer (B) (C) CH3 and HCl (D) C2H6 and HCl
Sol. 2BeCl2 + LiAlH4 2BeH2 + LiCl + AlCl3 Answer (C)
7. Borazine, also known as inorganic benzene, can be Sol. Cl CH4 CH3 HCl
(A) (B)
prepared by the reaction of 3-equivalents of “X” with
6-equivalents of “Y”. “X” and “Y”, respectively are: 11. Which technique among the following, is most
(A) B(OH)3 and NH3 appropriate in separation of a mixture of 100 mg of
p-nitrophenol and picric acid?
(B) B2H6 and NH3
(A) Steam distillation
(C) B2H6 and HN3
(B) 2-5 ft long column of silica gel
(D) NH3 and B2O3
(C) Sublimation
Answer (B)
(D) Preparative TLC (Thin Layer Chromatography)
Sol. 3B2H6 6NH3 2B3N3H6
(Borazine) Answer (D)
- 10 -
JEE (Main)-2022 : Phase-2 (26-07-2022)-Morning
Sol. Thin layer chromatography is a technique used to
isolate non-volatile mixtures.
Hence, mixture of p-nitrophenol and Picric acid is (B)
separated by TLC.
12. The difference in the reaction of phenol with
bromine in chloroform and bromine in water
medium is due to:
(A) Hyperconjugation in substrate
(B) Polarity of solvent (C)
(C) Free radical formation
(D) Electromeric effect of substrate
Answer (B)
Sol. Phenol gives different products with bromine in
chloroform and water medium due to the polarity
(D)
difference between chloroform and water acting as
solvent
13. Which of the following compounds is not aromatic?
Answer (C)
Sol.
(A) (B)
(C) (D)
Answer (C)
15. Which reactant will give the following alcohol on
Sol. is a non-planar compound, reaction with one mole of phenyl magnesium
bromide (PhMgBr) followed by acidic hydrolysis?
hence it is not aromatic.
14. The products formed in the following reaction, A
and B are
(A) CH3 – C N (B) Ph – C N
(C) (D)
Answer (D)
(A)
Sol.
- 11 -
JEE (Main)-2022 : Phase-2 (26-07-2022)-Morning
16. The major product of the following reaction is Sol. Diazonium salt containing aryl group directly linked
to electron donating group is most stable due to
resonance. The +M effect stabilizes the
intermediate whereas Electron withdrawing group
on benzene destabilizes the intermediate at para
position.
(A) (B)
(C) (D)
Answer (A)
Order will be A > C > D > B.
18. Stearic acid and polyethylene glycol react to form
Sol. which one of the following soap/s detergents?
(A) Cationic detergent (B) Soap
(C) Anionic detergent (D) Non-ionic detergent
Answer (D)
Sol.
(When G = EDG) (When G = EWG)
EDG Electron donating group
EWG Electron withdrawing group The product do not contain any ion in their
constitution hence it is a non-ionic detergent.
17. The correct stability order of the following
19. Which one of the following is a reducing sugar?
diazonium salt is
(A)
(A) (A) > (B) > (C) > (D)
(B) (A) > (C) > (D) > (B)
(C) (C) > (A) > (D) > (B)
(D) (C) > (D) > (B) > (A) (B)
Answer (B)
- 12 -
JEE (Main)-2022 : Phase-2 (26-07-2022)-Morning
Answer (C)
(C)
Sol.
Aniline does not undergo Friedel Craft reaction
because the reagent AlCl3 being electron deficient
(D) acts as a Lewis acid.
SECTION - B
Numerical Value Type Questions: This section
contains 10 questions. In Section B, attempt any five
Answer (A)
questions out of 10. The answer to each question is a
Sol.
NUMERICAL VALUE. For each question, enter the
correct numerical value (in decimal notation,
truncated/rounded-off to the second decimal place; e.g.
06.25, 07.00, –00.33, –00.30, 30.27, –27.30) using the
mouse and the on-screen virtual numeric keypad in the
place designated to enter the answer.
The sugar gives +ve Tollen’s test hence it’s a
1. Chlorophyll extracted from the crushed green
reducing sugar.
leaves was dissolved in water to make 2 L solution
20. Given below are two statements: one is labelled as
of Mg of concentration 48 ppm. The number of
Assertion (A) and the other is labelled as Reason
atoms of Mg in this solution is x × 1020 atoms. The
(R).
value of x is ________. (Nearest integer)
Assertion (A) : Experimental reaction of CH3Cl
(Given : Atomic mass of Mg is 24 g mol–1; NA = 6.02 ×
with aniline and anhydrous AlCl3 does not give
1023 mol–1)
o and p-methylaniline.
Answer (24)
Reason (R) : The –NH2 group of aniline becomes
deactivating because of salt formation with Sol. In 2L 96 mg of Mg
anhydrous AlCl3 and hence yields m-methyl aniline
96 10 –3
as the product. Number of atoms of Mg NA
24
In the light of the above statements, choose the
= 4 10 –3 6 1023
most appropriate answer from the options given
below : = 24 × 1020
(A) Both (A) and (R) are true and (R) is the correct x = 24
explanation of (A). 2. A mixture of hydrogen and oxygen contains 40%
(B) Both (A) and (R) are true but (R) is not the hydrogen by mass when the pressure is 2.2 bar.
correct explanation of (A). The partial pressure of hydrogen is _______ bar.
(C) (A) is true, but (R) is false. (Nearest integer)
(D) (A) is false, but (R) is true. Answer (2)
- 13 -
JEE (Main)-2022 : Phase-2 (26-07-2022)-Morning
Sol. 40% w/w hydrogen gas is given in mixture of H2 and 4. 2.4 g coal is burnt in a bomb calorimeter in excess
oxygen. of oxygen at 298 K and 1 atm pressure. The
Wt. of H2 = 40 g temperature of the calorimeter rises from 298 K to
300 K. The enthalpy change during the combustion
Wt. of O2 = 60 g
of coal is –x kJ mol–1. The value of x is ______.
nH2 (Nearest integer)
H 2
nH2 nO2
(Given : Heat capacity of bomb calorimeter is 20.0
40 kJ K–1. Assume coal to be pure carbon)
2
Answer (200)
40 60
2 32 Csystem T
Sol. Q (Heat evolved)
20 n
20 1.875 2.4
ncoal
20 12
0.914
21.875 –20 300 – 298
Q
PH2 H2 PT 0.2
Q –200 kJ / mol
= 0.914 × 2.2
x = 200
= 2.01 2 bar
5. When 800 mL of 0.5 M nitric acid is heated in a
3. The wavelength of an electron and a neutron will beaker, its volume is reduced to half and 11.5 g of
become equal when the velocity of the electron is x nitric acid is evaporated. The molarity of the
times the velocity of neutron. The value of x is remaining nitric acid solution is x × 10–2 M. (Nearest
______. (Nearest integer) integer)
(Mass of electron is 9.1 × 10–31 kg and mass of (Molar mass of nitric acid is 63 g mol–1)
neutron is 1.6 × 10–27 kg)
Answer (54)
Answer (1758)
Sol. m moles of HNO3 = 800 × 0.5
h h
Sol. e , N Moles of HNO3 = 400 × 10–3
me Ve mN VN
= 0.4 moles
e N When Ve xVN
Weight of HNO3 = 0.4 × 63 g
1 1 = 25.2 g
me Ve mN VN
Remaining acid = 25.2 – 11.5
mN Ve
x = 13.7 g
me VN
13.7 1000
M
1.6 10 –27 400 63
x
9.1 10 –31
137
= 0.54
= 0.17582 × 104 252
1758 = 54 × 10–2
- 14 -
JEE (Main)-2022 : Phase-2 (26-07-2022)-Morning
6. At 298 K, the equilibrium constant is 2 × 10 15 for the 1
Sol. t 1
reaction: 2
a0 n1
Cu(s) + 2Ag+(aq)
Cu2+(aq) + 2Ag(s)
t1/2 = 100 sec a0 = 05
The equilibrium constant for the reaction t1/2 = 50 sec a0 = 1
1 2+
1 n 1
Cu aq Ag s
Cu s Ag aq
100 1
2 2
50 0 5
is x × 10–8. The value of x is ________
(2) = (2)n–1
(Nearest integer)
n–1=1
Answer (2)
n=2
Sol. Cu(s) + 2Ag+(aq)
Cu2+(aq) + 2Ag(s)
9. The difference between spin only magnetic
k = 2 × 1015
moment value of [Co(H2O)6]Cl2 and [Cr(H2O)6]Cl3 is
1
Cu s Ag aq
Cu aq 2Ag s
2 _________.
2
Answer (0)
1 1
K
Sol. Co 4s2 3d7
K 2 10
1 1
2 15 2
H2O is weak field ligand.
= 223 × 10–8
Co+2 3d7
x2
n=3 1 = n n 2
7. The amount of charge in F(Faraday) required to
obtain one mole of iron from Fe3O4 is __________. = 15 B.M.
(Nearest integer)
Cr 4s1 3d5
Answer (3)
Co+3 3d3
Sol. For Fe3O4,
n=3 2 = 15 B.M.
8
x
3 1 – 2 = 0
where x is oxidation state of Fe. 10. In the presence of sunlight, benzene reacts with CI2
to give product X. The number of hydrogens in X is
Fe3O 4 8H 8e 3Fe 4H2O
_________.
8 8F
Charge required = F 3F Answer (6)
3 3
8. For a reaction A 2B + C the half lives are 100 s
and 50 s when the concentration of reactant A is 0.5 Sol.
and 1.0 mol L–1 respectively. The order of the
reaction is ________. (Nearest integer)
Answer (2) Total number of hydrogens are 6.
- 15 -
