XII/IQM#3/28/01/2021/PCB Ans.

Key Target NEET 2021

CHEMISTRY
1. A
Sol. 2nd step is oxidative ozonolysis which give acid.
2. C
1
Sol. Heat of hydrogenation 
hyperconjugation
Heat of hydrogenation of cis > trans.
3. C
H
H2SO4 O3
CH2 O + O C
 Zn – H2O H
OH
Sol. A Decolourise cold KMnO4
resist oxidation
4. C
5. C

Sol.
sp  Non planar.
2
N

H H
6. C 7. C
8. B
Sol. It has 3 acidic hydrogen & will produce 1.5 mol H2
9. B 10. C
11. B
Sol. Electron withdrawing gp on substrate is excellent substrate for SN2
12. A 13. A
14. A H
B2H6 PCC
Sol. H3C – CH2 – C= CH2 H2O2/HO
– CH3CH2 – C – CH2OH CH3CH2 – CH – CHO
CH3 CH3 CH3
(X) (y) Chiral
OH O
| ||
If X is CH 3  CH  C  CH 3  CH 3  CH  CH  CH 3  CH 3  C  CH  CH 3 (Inactive )
| | |
CH3 CH3 CH3
15. B
Sol. sp2 hybridisation is very less stable at bridgehead carbon of a bicyclic compound.
16. A 17. A
18. B
CH2 CH2
+ CH2 +
H -H
OH 
Sol. -H2O

19. C
Sol. It is 3° alcohol that gives 3° carbocation which is easily formed.

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XII/IQM#3/28/01/2021/PCB Ans. Key Target NEET 2021
20. B

Sol. In CH 3 CO C H2CH 2Br , the -hydrogen is more acidic due to electron-withdrawing effect of the C = O
group, therefore, it can be easily abstracted by a base. Further, the product formed is stabilized by
resonance due to conjugation of the double bond with the C = O group. Thus CH3COCH2CH2Br is most
reactive towards alcoholic KOH

CH 3 COCH 2 CH 2Br    CH 3  C  CH  CH 2  CH 3  C  CH  C H2
KOH( alc .)
 HBr || |
O O
21. A
  
H2O
Sol. C 6H5  C H  OCH 3   C 6H5  C H  O CH 3  C 6H5  CH  O CH 3
|  Highly stabilise
Cl
22. D
Sol. Carbocation rearrangement as Benzylic carbocation is more stable
23. A
CH3 CH3 O OH
||
| | |
Sol. CH3  CH  Br  Mg 1. C6H5  C  CH3
 CH3  CH  Mg  Br 
 CH3  C  C6H5
2. H2O |
CH  CH3
|
CH3
24. B 25. A 26. B O O
27. D COCH3 COO Na
– +

Sol. Aralkyl halides are more reactive than aryl NaOI

halides, therefore, only the halogen in the side Sol. iodoform
+ CHI3
chain is displaced. +
H
CH2Cl CH2CN
NaCN OH O
DMF COOH COOH
NaBH4
I I water
28. D
Sol. It is SN2 & aprotic polar solvent will favour. 39. C
29. B 40. D
30. A Sol. NaBH4 will not reduce double bond
Sol. It is SN2 attack of CH3O–, on less hindered side 41. B
Sol. A = CH3CN; B = CH3COOH; C = CH3CH2OH
CH3 3 OCH3
2 42. A
to form 1 43. A
OH
Sol. X is cis and Br2 has anti-attack. The product has
to be a racemic mixture
31. B 32. C 33. C Y is trans and anti-attack of Br2 gives meso
34. A compound i.e., C and D are same compound
35. B 44. B
CH3 CCl3 CCl3
Sol. Li
+
Li 3Cl2/ Br2/Fe
Br Sol.
Sunlight
D2O Br

45. C
D
36. B 37. C
38. A

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XII/IQM#3/28/01/2021/PCB Ans. Key Target NEET 2021

Physics and Biology (Answer Key)

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