Based on GHS (rev 3) (2009)

MS 1804:2008, CLASS :Part V :2013 - Malaysia

Date of issue/ Date of revision : 26.08.2019

Date of previous issue : 11.06.2018
Version : 2.0

SAFETY DATA SHEET

Leffingwell Nutra-Phos N 12-12-4

Section 1. Identification of the hazardous chemical and of

the supplier
Product identifier : Leffingwell Nutra-Phos N 12-12-4
Product type : solid (Powder.)
Product code : PYP96W

Uses
Area of application : Professional applications
Material uses : Fertilizers.

Supplier
Supplier's details : Yara International (M) Sdn Bhd

Address
Street : Petaling Jaya Selangor Darul Ehsan
Lot 3.02, Level 3,
1 First Avenue, Bandar Utama,
Postal code : 47800
Country : Malaysia

Telephone number : +603-7726 4181

Fax no. : +603-7722 2479
e-mail address of person : [email protected]
responsible for this SDS
Emergency telephone number : +60 3 6207 4347 (7/24)
(with hours of operation)

National advisory body/Poison Center

Name : Pusat Racun Negara (National Poisons Centre)
Telephone number : +60 (0)4 6570099

Section 2. Hazards identification

Classification of the : TOXIC TO REPRODUCTION (Fertility) - Category 2
substance or mixture. TOXIC TO REPRODUCTION (Unborn child) - Category 2
HAZARDOUS TO THE AQUATIC ENVIRONMENT -
CHRONIC HAZARD - Category 2

GHS label elements

Leffingwell Nutra-Phos N 12-12-4

Hazard pictograms :

Signal word : Warning

Hazard statements : H361 Suspected of damaging fertility or the

unborn child.
H411 Toxic to aquatic life with long lasting effects.

Precautionary statements

Prevention : P202 Do not handle until all safety precautions

have been read and understood.
P280-d Wear protective gloves/clothing and
eye/face protection.
P273 Avoid release to the environment.
Response : P391 Collect spillage.
P308 IF exposed or concerned:
P313-a Get medical attention.

Disposal : P501 Dispose of contents and container

according to local regulations.

Other hazards which do not : Fine dust clouds may form explosive mixtures with air.
result in classification Handling and/or processing of this material may generate
a dust which can cause mechanical irritation of the eyes,
skin, nose and throat.

Section 3. Composition and information of the ingredients

of the hazardous chemical
Substance/mixture : Mixture

Ingredient name CAS number %

colemanite (calcium borate) 12291-65-5 >= 10- <12.5
zinc oxide 1314-13-2 >= 5- <7
potassium pentahydrogen bis(phosphate) 14887-42-4 >= 3- <5

Any concentration shown as a range is to protect confidentiality or is due to batch variation.

There are no additional ingredients present which, within the current knowledge of the supplier
and in the concentrations applicable, are classified as hazardous to health or the environment
and hence require reporting in this section.
Occupational exposure limits, if available, are listed in Section 8.

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Remark : This product contains Boron (see section 7 and 11).

Section 4. First aid measures
Description of necessary first aid measures
Eye contact : Immediately flush eyes with plenty of water, occasionally lifting
the upper and lower eyelids. Continue to rinse for at least 10
minutes. Check for and remove any contact lenses. Get
medical attention if irritation occurs.
Inhalation : Get medical attention if you feel unwell. Remove victim to
fresh air and keep at rest in a position comfortable for
breathing. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or
oxygen by trained personnel. If unconscious, place in recovery
position and get medical attention immediately. Maintain an
open airway. Loosen tight clothing such as a collar, tie, belt or
waistband.
Skin contact : Flush contaminated skin with plenty of water. Remove
contaminated clothing and shoes. Get medical attention if
symptoms occur.
Ingestion : Wash out mouth with water. If material has been swallowed
and the exposed person is conscious, give small quantities of
water to drink. Do not induce vomiting unless directed to do so
by medical personnel. Get medical attention if you feel unwell.
Remove victim to fresh air and keep at rest in a position
comfortable for breathing.

Most important symptoms/effects, acute and delayed

Potential acute health effects
Eye contact : Exposure to airborne concentrations above statutory or
recommended exposure limits may cause irritation of the
eyes.
Inhalation : Exposure to airborne concentrations above statutory or
recommended exposure limits may cause irritation of the
nose, throat and lungs. Exposure to decomposition products
may cause a health hazard. Serious effects may be delayed
following exposure.
Skin contact : No known significant effects or critical hazards.
Ingestion : No known significant effects or critical hazards.

Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:
irritation
redness

Inhalation : Adverse symptoms may include the following:

respiratory tract irritation
coughing

Skin contact : No specific data.

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Leffingwell Nutra-Phos N 12-12-4

Ingestion : No specific data.

Indication of immediate medical attention and special treatment needed, if necessary

Notes to physician : Treat symptomatically. Contact poison treatment specialist
immediately if large quantities have been ingested or inhaled.
In case of inhalation of decomposition products in a fire,
symptoms may be delayed. The exposed person may need to
be kept under medical surveillance for 48 hours.
Specific treatments : No specific treatment.
Protection of first-aiders : No action shall be taken involving any personal risk or without
suitable training.

See toxicological information (Section 11)

Section 5. Fire-fighting measures

Extinguishing media
Suitable extinguishing media : Use an extinguishing agent suitable for the surrounding fire.
Unsuitable extinguishing : None identified.
media
Specific hazards arising from : Fine dust clouds may form explosive mixtures with air. This
the chemical material is toxic to aquatic life with long lasting effects. Fire
water contaminated with this material must be contained and
prevented from being discharged to any waterway, sewer or
drain.
Hazardous thermal : Decomposition products may include the following materials:
decomposition products nitrogen oxides
phosphorus oxides
metal oxide/oxides
ammonia
Avoid breathing dusts, vapors or fumes from burning
materials.
In case of inhalation of decomposition products in a fire,
symptoms may be delayed.

Special protective actions for : Promptly isolate the scene by removing all persons from the
fire-fighters vicinity of the incident if there is a fire. No action shall be taken
involving any personal risk or without suitable training. Move
containers from fire area if this can be done without risk. Use
water spray to keep fire-exposed containers cool.
Special protective equipment : Fire-fighters should wear appropriate protective equipment
for fire-fighters and self-contained breathing apparatus (SCBA) with a full
face-piece operated in positive pressure mode.
Remark : Non-explosive.

Section 6. Accidental release measures

Personal precautions, protective equipment and emergency procedures
For non-emergency personnel : No action shall be taken involving any personal risk or without
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suitable training. Evacuate surrounding areas. Keep

unnecessary and unprotected personnel from entering. Do not
touch or walk through spilled material. Shut off all ignition
sources. No flares, smoking or flames in hazard area. Avoid
breathing dust. Provide adequate ventilation. Wear appropriate
respirator when ventilation is inadequate. Put on appropriate
personal protective equipment (see Section 8).

For emergency responders : If specialized clothing is required to deal with the spillage, take
note of any information in Section 8 on suitable and unsuitable
materials. See also the information in "For non-emergency
personnel".

Environmental precautions : Avoid dispersal of spilled material and runoff and contact with
soil, waterways, drains and sewers. Inform the relevant
authorities if the product has caused environmental pollution
(sewers, waterways, soil or air). Water polluting material. May
be harmful to the environment if released in large quantities.
Collect spillage.

Methods and materials for containment and cleaning up

Small spill : Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Avoid dust generation. Do not dry
sweep. Vacuum dust with equipment fitted with a HEPA filter
and place in a closed, labeled waste container. Dispose of via
a licensed waste disposal contractor.
Large spill : Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind.
Prevent entry into sewers, water courses, basements or
confined areas. Avoid dust generation. Do not dry sweep.
Vacuum dust with equipment fitted with a HEPA filter and
place in a closed, labeled waste container. Avoid creating
dusty conditions and prevent wind dispersal. Dispose of via a
licensed waste disposal contractor. Note: see Section 1 for
emergency contact information and Section 13 for waste
disposal.

Section 7. Handling and storage

Precautions for safe handling

Not for human or animal consumption.

Protective measures : Put on appropriate personal protective equipment (see

Section 8). Do not handle until all safety precautions have
been read and understood. As a precaution, keep exposure
as low as possible for pregnant women, children and workers
in reproductive age. Avoid dust generation. Do not breathe
dust. Do not get in eyes or on skin or clothing. Do not ingest.
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Avoid breathing dust. Avoid release to the environment. Avoid

the creation of dust when handling and avoid all possible
sources of ignition (spark or flame). Prevent dust
accumulation. Use only with adequate ventilation. Wear
appropriate respirator when ventilation is inadequate. Keep in
the original container or an approved alternative made from a
compatible material, kept tightly closed when not in use.
Electrical equipment and lighting should be protected to
appropriate standards to prevent dust coming into contact with
hot surfaces, sparks or other ignition sources. Take
precautionary measures against electrostatic discharges. To
avoid fire or explosion, dissipate static electricity during
transfer by grounding and bonding containers and equipment
before transferring material. Empty containers retain product
residue and can be hazardous. Do not reuse container.
Advice on general : Eating, drinking and smoking should be prohibited in areas
occupational hygiene where this material is handled, stored and processed.
Workers should wash hands and face before eating, drinking
and smoking. Remove contaminated clothing and protective
equipment before entering eating areas. See also Section 8
for additional information on hygiene measures.

Conditions for safe storage, : Store in a segregated and approved area. Store in original
including any incompatibilities container protected from direct sunlight in a dry, cool and well-
ventilated area, away from incompatible materials (see
Section 10) and food and drink. Store locked up. Eliminate all
ignition sources. Separate from oxidizing materials. Keep
container tightly closed and sealed until ready for use.
Containers that have been opened must be carefully resealed
and kept upright to prevent leakage. Do not store in unlabeled
containers. Use appropriate containment to avoid
environmental contamination.

Specific recommendations to : Do not generate and inhale liquid fertilizer aerosols.

end users
In addition to overalls, gloves and eye protection, use of
efficient respiratory protection (P2/P3 respirators with a tight
face seal) during discharge of fertilizer bags and maintenance
of equipment is recommended to minimize inhalation
exposure and to ensure safe-use during this activity (see
section 8).

Risk assessments show safe use during normal spreading of

fertilizers containing below 5% of boron by tractor (liquid or
granular) and backpack (liquid).

Section 8. Exposure controls/personal protection

Control parameters
Occupational exposure limits

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Leffingwell Nutra-Phos N 12-12-4

Ingredient name Exposure limits

zinc oxide JKKP PENGGUNAAN BKK (2000-04-04)
TWA 10 mg/m3 Form: Dust
TWA 5 mg/m3 Form: Fume

Appropriate engineering : Use only with adequate ventilation. If user operations generate
controls dust, fumes, gas, vapor or mist, use process enclosures, local
exhaust ventilation or other engineering controls to keep
worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls
also need to keep gas, vapor or dust concentrations below
any lower explosive limits. Use explosion-proof ventilation
equipment.
Environmental exposure : Emissions from ventilation or work process equipment should
controls be checked to ensure they comply with the requirements of
environmental protection legislation. In some cases, fume
scrubbers, filters or engineering modifications to the process
equipment will be necessary to reduce emissions to
acceptable levels.

Individual protection measures

Hygiene measures : A washing facility or water for eye and skin cleaning purposes
should be present. Wash hands, forearms and face thoroughly
after handling chemical products, before eating, smoking and
using the lavatory and at the end of the working period. Wash
contaminated clothing before reusing.
Eye/face protection : Safety eyewear complying with an approved standard should
be used when a risk assessment indicates this is necessary to
avoid exposure to liquid splashes, mists, gases or dusts.

Skin protection
Hand protection : Chemical-resistant, impervious gloves complying with an
approved standard should be worn at all times when handling
chemical products if a risk assessment indicates this is
necessary. For general applications, we recommend gloves
with a thickness typically greater than 0.35 mm. It should be
emphasized that glove thickness is not necessarily a good
predictor of glove resistance to a specific chemical, as the
permeation efficiency of the glove will be dependent on the
exact composition of the glove material.
Body protection : Personal protective equipment for the body should be selected
based on the task being performed and the risks involved.
Other skin protection : Appropriate footwear and any additional skin protection
measures should be selected based on the task being
performed and the risks involved and should be approved by a
specialist before handling this product.
Respiratory protection : Use respiratory protection with more than 94% efficiency (P2,
P3 or N95) and a tight face seal, when risk of exposure to
dust.

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Personal protective equipment :

(Pictograms)

Section 9. Physical and chemical properties

Appearance
Physical state : solid [Powder.]
Color : Light,
Odor : Odorless.
Odor threshold : Not relevant/applicable due to nature of the product.

pH : 9 [Conc.: 5 g/l] @ 20 °C (68 °F)

Melting/freezing point : 134 °C

Boiling/condensation point : Not relevant/applicable due to nature of the product.

Sublimation temperature : Not determined.

Flash point : Not determined.
Fire point : Not determined.
Evaporation rate : Not determined.
Flammability (solid, gas) : Non-flammable.

Lower and upper explosive : Lower: Not determined.

(flammable) limits Upper: Not determined.
Vapor pressure : Not determined.
Bulk density : 870 kg/m3

Density : Not applicable.

Relative density : Not applicable.

Solubility : insoluble in water.

Solubility in water : Not relevant/applicable due to nature of the product.

Partition coefficient: n- : Not determined.

octanol/water
Auto-ignition temperature : Not determined.

Decomposition temperature : Not determined.

Viscosity : Dynamic: Not relevant/applicable due to nature of the
product.

Kinematic: Not relevant/applicable due to nature of the

product.

Explosive properties : Non-explosive.

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Oxidizing properties : None

Section 10. Stability and reactivity

Reactivity : No specific test data related to reactivity available for this
product or its ingredients.

Chemical stability : The product is stable.

Possibility of hazardous : Under normal conditions of storage and use, hazardous

reactions reactions will not occur.

Conditions to avoid : Avoid the creation of dust when handling and avoid all
possible sources of ignition (spark or flame). Take
precautionary measures against electrostatic discharges. To
avoid fire or explosion, dissipate static electricity during
transfer by grounding and bonding containers and equipment
before transferring material. Prevent dust accumulation.

Incompatible materials : Reactive or incompatible with the following materials:

oxidizing materials
Urea reacts with calcium hypochlorite or sodium hypochlorite
to form the explosive nitrogen trichloride.

Hazardous decomposition : Under normal conditions of storage and use, hazardous

products decomposition products should not be produced.

Section 11. Toxicological information

Information on toxicological effects

Acute toxicity
Product/ingredie Method Species Result Exposure References
nt name
zinc oxide
LD50 Oral Rat > 5,000 mg/kg Not IUCLID 5
applicable.
LC50 Inhalation Rat > 5.7 mg/l 4h IUCLID 5
Dusts and mists
colemanite (calcium borate)
LD50 Dermal Rabbit > 5,000 mg/kg Not
applicable.

Conclusion/Summary : No known significant effects or critical hazards.

Irritation/Corrosion
Product/ingredient Method Species Result Exposure References
name
potassium pentahydrogen bis(phosphate)

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Eyes Rabbit Severe IUCLID 5

irritant

Conclusion/Summary
Skin : No known significant effects or critical hazards.

Eyes : No known significant effects or critical hazards.

Respiratory : No known significant effects or critical hazards.

Sensitization

Conclusion/Summary
Skin : No known significant effects or critical hazards.
Respiratory : No known significant effects or critical hazards.

Mutagenicity

Conclusion/Summary : No known significant effects or critical hazards.

Carcinogenicity

Conclusion/Summary : No known significant effects or critical hazards.

Reproductive toxicity

Conclusion/Summary : Suspected of damaging fertility. Suspected of damaging

the unborn child.

Specific target organ toxicity (single exposure)

No known significant effects or critical hazards.

Specific target organ toxicity (repeated exposure)

No known significant effects or critical hazards.

Aspiration hazard
No known significant effects or critical hazards.

Information on the likely : Not available.

routes of exposure

Potential acute health effects

Eye contact : Exposure to airborne concentrations above statutory or
recommended exposure limits may cause irritation of the
eyes.
Inhalation : Exposure to airborne concentrations above statutory or
recommended exposure limits may cause irritation of the
nose, throat and lungs. Exposure to decomposition products
may cause a health hazard. Serious effects may be delayed
following exposure.
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Skin contact : No known significant effects or critical hazards.

Ingestion : No known significant effects or critical hazards.

Symptoms related to the physical, chemical and toxicological characteristics

Eye contact : Adverse symptoms may include the following:
irritation
redness

Inhalation : Adverse symptoms may include the following:

respiratory tract irritation
coughing

Skin contact : No specific data.

Ingestion : No specific data.

Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate effects : Not available.
Potential delayed effects : Not available.

Long term exposure

Potential immediate effects : Not available.
Potential delayed effects : Not available.

Potential chronic health effects

Carcinogenicity : No known significant effects or critical hazards.

Mutagenicity : No known significant effects or critical hazards.

Fertility effects : Suspected of damaging fertility.

Developmental effects : Suspected of damaging the unborn child.

Effects on or via lactation : No known significant effects or critical hazards.

Other effects : Repeated or prolonged inhalation of dust may lead to chronic

respiratory irritation.

Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:
irritation
redness

Inhalation : Adverse symptoms may include the following:

respiratory tract irritation
coughing

Skin contact : No specific data.

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Ingestion : No specific data.

Numerical measures of toxicity

Acute toxicity estimates
Not available.

Section 12. Ecological information

Toxicity
Product/ingred Method Species Result Exposure References
ient name
zinc oxide
Acute NOEC Fish. 0.026 - 0.075 720 h IUCLID 5
Fresh water mg/l
Acute LC50 Crustaceans 0.14 mg/l 24 h IUCLID 5
Fresh water
Acute EC50 Water flea 1 - 10 mg/l 48 h IUCLID 5
Fresh water
OECD 201 Algae 0.136 mg/l 72 h IUCLID
Acute IC50
Fresh water
colemanite (calcium borate)
Acute EC50 Daphnia > 100 mg/l 48 h
Fresh water

Conclusion/Summary : Toxic to aquatic life with long lasting effects.

Persistence and degradability

Conclusion/Summary : No known significant effects or critical hazards.

Bioaccumulative potential

Conclusion/Summary : No known significant effects or critical hazards.

Mobility in soil
Soil/water partition : Not available.
coefficient (KOC)
Mobility : Not available.
Other adverse effects : No known significant effects or critical hazards.

Section 13. Disposal information

Product
Methods of disposal : The generation of waste should be avoided or minimized
wherever possible. Disposal of this product, solutions and
any by-products should at all times comply with the
requirements of environmental protection and waste
disposal legislation and any regional local authority
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requirements. Dispose of surplus and non-recyclable

products via a licensed waste disposal contractor. Waste
should not be disposed of untreated to the sewer unless
fully compliant with the requirements of all authorities with
jurisdiction. Waste packaging should be recycled.
Incineration or landfill should only be considered when
recycling is not feasible. This material and its container
must be disposed of in a safe way. Care should be taken
when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may
retain some product residues. Avoid dispersal of spilled
material and runoff and contact with soil, waterways,
drains and sewers.

Section 14. Transport information

Regulation: UN Class
14.1 UN number 3077
14.2 UN proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID,
N.O.S. (zinc oxide, )
14.3 Transport hazard class(es) 9

14.4 Packing group III

14.5 Environmental hazards Yes.
Additional information
Environmental hazards : Yes.

Regulation: ADR/RID
14.1 UN number 3077
14.2 UN proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID,
N.O.S. (zinc oxide, )
14.3 Transport hazard class(es) 9

14.4 Packing group III

14.5 Environmental hazards Yes.
Additional information

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Hazard identification number : 90

Regulation: IMDG
14.1 UN number 3077
14.2 UN proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID,
N.O.S. (zinc oxide, )
14.3 Transport hazard class(es) 9

14.4 Packing group III

14.5 Environmental hazards Yes.
Additional information
Marine pollutant : Yes.
Emergency schedules (EmS) : F-A, S-F

Regulation: IATA
14.1 UN number 3077
14.2 UN proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID,
N.O.S. (zinc oxide, )
14.3 Transport hazard class(es) 9

14.4 Packing group III

14.5 Environmental hazards Yes.
Additional information
Marine pollutant : Yes.

14.6 Special precautions for : Transport within user’s premises: Ensure that persons
user transporting the product know what to do in the event of
an accident or spillage.

IMSBC
Bulk cargo shipping name : Leffingwell Nutra-Phos N 12-12-4
Class : Not applicable.
Group : C
Marpol V : Non-HME

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Transport in bulk according to : Not applicable.

Annex II of MARPOL and the
IBC Code

Section 15. Regulatory information

Inventory list

Section 16. Other information

Key to abbreviations : ADNR/ADN = European Provisions concerning the International Carriage of
Dangerous Goods by Inland Waterway
ADR = The European Agreement concerning the International Carriage of
Dangerous Goods by Road
ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
bw = Body weight
GHS = Globally Harmonized System of Classification and Labelling of
Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From
Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)
NOHSC - National Occupational Health and Safety Commission
RID = The Regulations concerning the International Carriage of Dangerous
Goods by Rail
SUSMP - Standard Uniform Schedule of Medicine and Poisons
UN = United Nations

Procedure used to derive the classification

Classification Justification
TOXIC TO REPRODUCTION (Fertility) - Calculation method
Category 2
TOXIC TO REPRODUCTION (Unborn child) Calculation method
- Category 2
HAZARDOUS TO THE AQUATIC Calculation method
ENVIRONMENT - CHRONIC HAZARD -
Category 2

Key data sources : EU REACH IUCLID5 CSR.

National Institute for Occupational Safety and Health, U.S.
Dept. of Health, Education, and Welfare, Reports and
Memoranda Registry of Toxic Effects of Chemical
Substances.
Sphera Solutions Inc., 4777 Levy Street, St Laurent, Quebec
HAR 2P9, Canada.

History

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Leffingwell Nutra-Phos N 12-12-4

Date of printing : 07.10.2019

Date of issue/Date of revision : 26.08.2019
Date of previous issue : 11.06.2018
Revision comments : The following sections contain new and updated information:
9.

Version : 2.0
Prepared by : Yara Chemical Compliance (YCC).
|| Indicates information that has changed from previously issued version.

Notice to reader

To the best of our knowledge, the information contained herein is accurate. However, neither
the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the
accuracy or completeness of the information contained herein. Final determination of
suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described
herein, we cannot guarantee that these are the only hazards that exist.

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