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BAED-CHEM2122 General Chemistry 2

If 25 J are required to change the temperature of 5.0 g of substance A by 2.0°C, what is the
specific heat of substance A?

2.5 J/g C

Which phase of matter has the greatest motion and least orderly arrangement?

GAS

For which of these processes is the value of ΔH expected to be positive? 1. The temperature
increases when calcium chloride dissolves in water. 2. Steam condenses to liquid water 3. Water
boils 4. Dry ice sublimates

3 and 4 only

True/False: The rate of a chemical reaction is unrelated to the spontaneity of the reaction.

True

The formation ½A2+2B2+C→CAB4½A2+2B2+C→CAB4 has an enthalpy of formation of

-104 kJ and a change in entropy of -60.8 J/K at 30 °C. What is the free energy and spontaneity of
the reaction?

-85.6 kJ, spontaneous

Temperature is a measure of average ______ energy of individual atoms.

kinetic

The equation that relates enthalpy, temperature and entropy is

Gibbs Free Energy

ΔH value in an endothermic reaction is a positive number.

True
Which substance is the better conductor?

Steel eat transfer _____ occurs from hot

to cold.

always

The amount of energy required to raise the temperature of one gram of pure water by
one degree Celsius is defined as: a calorie

The SI unit of heat and energy is the __________.

Joule

A catalyst works by lowering

the activation energy

Entropy is a measure of the number of possible ways that the energy of a system can be
distributed.

True

The __________ law of thermodynamics states that entropy is always increasing.

Second

Which of the following is NOT true at equilibrium?

Gaseous

For the reaction... N2(g)+3H2(g)⇌2NH3(g)N2(g)+3H2(g)⇌2NH3(g). If the pressure in the

system is increased, which substance(s) will increase in concentration?

NH3
When the rate of the forward reaction is equal to the rate of backward reaction, the system is
said to be in

the correct answer is: Chemical Equilibrium

2SO2(g)+O2(g)⇌2SO3(g)2SO2(g)+O2(g)⇌2SO3(g). Adding SO3(g)SO3(g) will

The correct answer is: shift equilibrium left

2SO2(g)+O2(g)⇌2SO3(g)2SO2(g)+O2(g)⇌2SO3(g). Removing O2(g)O2(g) will

The correct answer is: shift equilibrium left

What are the two factors to look for when determining if the reaction is at equilibrium?

The correct answer is: Forward and reverse reaction rates are equal and concentration is
constant

This symbol indicates that a reaction is ___________

The correct answer is: reversible

For the reaction... SO2+O2⇌SO3SO2+O2⇌SO3. If the concentration of SO2SO2 is increased,

the equilibrium of the reaction will shift ___________.

The correct answer is: right

What is the effect of increasing the pressure on the following equilibrium: 2NO(g)
+O2(g)⇌2NO2(g)?
The correct answer is: TheyieldofNO2increases
Which of the following is NOT true at equilibrium?

The correct answer is: The concentration of the reactants is equal to the concentration of the
products.

Which of the following would have the highest entropy?

A hot gas

H2(g)+Cl2(g)⇌2HCl(g)H2(g)+Cl2(g)⇌2HCl(g) The forward reaction is exothermic. What will

happen to the equilibrium if the temperature is increased?

The correct answer is: equilibrium shifts left

A(n) _____________ is a device for measuring temperature.

The correct answer is: thermometer

Which law states "The entropy of a closed system is always increasing"?

The correct answer is: 2nd Law

The second law of thermodynamics states that entropy of a system tends to ______________.

The correct answer is: increase

Which law of thermodynamics states that absolute zero cannot be reached?

The correct answer is: 3rd

Heat transfer by conduction occurs when...

he correct answer is: particles bump into each other

A slower particle has a lower energy than an identical, faster particle.

The correct answer is 'True'.

The transfer of thermal energy between objects of different temperatures is called...

The correct answer is: heat

When thermal energy is added to a substance, the substance's particles move:

The correct answer is: More rapidly at an increased distance from each other.

Heat transfer by convection occurs when...

The correct answer is: large numbers of atoms move from place to place

Thermal energy always moves:

The correct answer is: From a high temperature object to a lower temperature object.

The first law of thermodynamics states that energy is

The correct answer is: conserved It

is possible to reach absolute zero.

The correct answer is 'False'.

A substance with a high specific heat:

Requires a lot of energy to become hot.

H2(g)+Cl2(g)⇌2HCl(g)H2(g)+Cl2(g)⇌2HCl(g). Removing Cl2(g)Cl2(g) will

The correct answer is: shift equilibrium left

Temperature is a measure of the...

The correct answer is: average kinetic energy of molecules in a substance

Heat travels from the sun to the earth by the process of...

The correct answer is: radiation

H2(g)+Cl2(g)⇌2HCl(g)H2(g)+Cl2(g)⇌2HCl(g). Increasing the pressure will

The correct answer is: have no change

The temperature of a glass of cold water will eventually...

The correct answer is: Match the temperature of the surrounding environment.

What is the conjugate base in the following reaction? HCO3−+HCI→H2CO3+C1−

The correct answer is: Cl_

What is the conjugate acid in the following equation?

The correct answer is: HPO

42−
HSO4−(aq)+H2O(l)→H3O+(aq)+SO42−(aq)HSO4−(aq)+H2O(l)→H3O+(aq)+SO42−
(aq). Identify the Acid in the above reaction.

The correct answer is: HSO4−

CO32−(aq)+H2O(l)→HCO3−(aq)+OH−(aq)CO32−(aq)+H2O(l)→HCO3−(aq)+OH−
(aq). Using the above reaction, which compound is the conjugate base?
The correct answer is: OH−
Which of the following is transferred between a conjugate acid-base pair?

The correct answer is: A Proton

If a solution is basic which ion will be more present?

The correct answer is: OHA

compound that donates H+ ions is

The correct answer is: A Bronsted-Lowry Acid

What are the products to a neutralization reaction?

The correct answer is: H2OH2O + Ionic
Salt
What might happen if you mixed a strong acid with an equally strong base?

The correct answer is: You'd wind up with a pH-neutral substance.

A substance that remains when a base has accepted an H+ ion is

The correct answer is: A Conjugate Acid

Which of the following is the correct units of the solubility product, Ksp for Ag2CO3Ag2CO3?
The correct answer is: mol3dm
−9
For an endothermic reaction, as the temperature of the solution increases,

The correct answer is: solubility of the salt increases ; Ksp increases

The molar solubility of PbI2 is 1.52 x 10-3 M. Calculate the value of Ksp for PbI2PbI2.
The correct answer1.40x10 −8 mol3dm
is:
−9
Silver chromate, Ag2CrO4Ag2CrO4, has a Ksp of 8.96x10[−12]8.96x10[−12]. Calculate the
solubility in mol/L of silver chromate.
The correct answer1.31x10 −4 M
is:
which of the following is the correct units of the solubility product, Ksp for AgCl?
The correct answer is: mol2dm
−6
Given that the molar solubility of Sn(OH)2 is "s". The correct mathematical expression for
solubility product constant of Sn(OH)2 is:

The correct answer is: 4s3=Ksp

Changes in pressure will only affect substances that are in the __________ state.

The correct answer is: gaseous

Which metal is the negative electrode?Zn/Zn2+//Cu2+/Cu

The correct answer is: zinc

Electrons always flow from

The correct answer is: anode to cathode

The gain of electrons is called?

The correct answer is: reduction

What reaction occurs at the anode?: Ag+/Ag = 0.80V, Ni2+/Ni = -0.25V

The correct answer is: Ni→Ni2+ +2 e−
An iron nail is put into a solution of copper nitrate, iron is above copper in the activity series of
metals, what will happen?

The correct answer is: the iron nail will become copper plated

If Al is above Co in the activity series of metals, which of the following will occur if Al metal is put
into a solution of cobalt nitrate? The correct answer is: all of the above

What occurs to the mass of copper electrode in the following reaction? Zn/Zn2+//Cu2+/Cu
The correct answer is: increases

How does a solution become supersaturated?

The correct answer is: dissolve more solute than you should be able to.

The amount of solute actually dissolved in a given amount of solvent is known

as______________________.

The correct answer is: solubility or concentration

You can make a solution more concentrated by adding _________

The correct answer is: solute

Precipitation of silver chloride , AgCl will occur when

The correct answer is: Qsp = Ksp

Which of the following is the correct units of the solubility product, Ksp for BaSO4BaSO4?\) ~
no unit }
The correct answer is: mol2dm
−6
An unknown salt, M2Z, has a Ksp of 3.3x10−93.3x10−9. Calculate the solubility in mol/L of M2Z.
The correct answer9.4x10 −4 M
is:
For an exothermic reaction, as the temperature of the solution increases,

The correct answer is: solubility of the salt decreases ; Ksp decreases

Solution where more solute can still be dissolved at the given temperature.

The correct answer is: Unsaturated

Solution where more solute can still be dissolved at the given temperature.

The correct answer is: Unsaturated

Which of the following shows the correct dissolution reaction for BaCl2?

The correct answerBaCl2⇌Ba (aq )+2 Cl− ( aq )

is:
2+ When a solvent contains as much of the
solute as it can hold, the solution is said to be

The correct answer is: saturated

"As temperature increases, the solubility for a slightly soluble salt will also increases."Is the
above statement correct?

The correct answer is: No, because the Kspwill change as the temperature change and it is
depends on the type of reaction (endothermic or exothermic reaction)

Which of the following is the correct units of the solubility product, Ksp for PbI2PbI2?
The correct answer is: mol^3 dm^{-9]
A saturated solution is formed when

The correct answers are: Qsp, Ksp

Which of the following is the correct units of the solubility product, Ksp for BaSO4BaSO4?\) ~
no unit }
The correct answer is: mol2dm
−6
A saturated solution is formed when

the correct answers are: Qsp, Ksp

Given their standard reduction potentials, which of the species is going to be

oxidized? : Cu2+/Cu=0.34VCu2+/Cu=0.34V, Zn2+/Zn=−0.76V

The correct answer is: Zn

Oxidation occurs at the

The correct answer is: anode

What would be the theoretical cell potential of the previous electrochemical cell? Ag+/Ag =
0.80V,Ni2+/Ni=−0.25V

The correct answer is: 1.05V