208 Syllabus

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155:208 Chemical Engineering Thermodynamics I Spring 2014

Lectures: Tue. & Fri., 12:00 p.m.–1:20 p.m., Hill-116

Instructor: M. Hara
Engineering Building, C-161
Busch Campus
Tel: (848)445-3817, Email: [email protected]
Office Hour: Tue. 2:30-4 pm

Teaching Assistant: Wei Meng


Engineering Building, C-115
Email: [email protected]
Office Hour: Mon, 4:00-5:30 pm

Kristin Steeley
Engineering Building, C-001
Email: [email protected]
Office Hour: Fri, 1:30-3:00 pm

Course Description: Thermodynamics relates work, heat, temperature, and states of matter
to each other. From a surprisingly small set of empirically based laws, an enormous amount
of information about the relationships among equilibrium parameters for a system can be
deduced. This information can then be applied to physical, chemical, and biological systems
including chemical process design, materials processing, and cellular processes.

Course Objectives: In this course, students learn how to apply knowledge of the laws of
thermodynamics, chemistry, physics, and engineering to analyze and solve physical and
chemical problems encountered in chemical and biochemical engineering. The course gives
the student the opportunity to analyze and interpret data, to identify, formulate, and solve
engineering problems, and to use the techniques, skills, and modern engineering tools
necessary for engineering practice.

Students will be introduced to the first and second law of thermodynamics and will learn to
apply these to the solution of chemical and biochemical engineering problems. Students will
be provided with the knowledge and awareness to understand the validity and
physicochemical interpretation of their solutions. Students will be introduced to the available
computational tools in solving thermodynamics-related problems.

Goals: The objective of this course is to introduce students to the principles of


thermodynamics as they apply to physical and chemical processes.

Knowledge, Abilities, and Skills Students Should Gain From This Course: 1. The
students should be able to apply energy balances to open and closed systems and to
evaluate the thermodynamic efficiency of compressors, turbines, Rankine cycles, and
refrigeration cycles. 2. They should be able to derive property relationships using
multivariable calculus and be comfortable using steam tables, pressure-enthalpy (P-H),
temperature-entropy (T-S), and enthalpy-entropy (H-S) charts. In addition, the students
should be able to calculate residual properties with equations of state. 3. The student should
be able to use computer software (such as ThermoSover) for the calculation of
thermodynamic properties of pure substances and mixtures.

Impact on Subsequent Courses in Curriculum: This is the first in a sequence of two


courses in Thermodynamics (155:208 & 155:309). Students completing 155:208 will be
required to take 155:309 in the fall semester of their junior year.

The material covered in this course (155:208) forms the fundamental basis for the topics of
phase equilibria, fugacity, chemical reaction equilibria and Gibbs free energy that will be
covered in 155:309. Thermodynamics in general plays an important role throughout chemical.
engineering including 155:324 Design of Separation Processes, 155:427 & 428 Chemical &
Biochemical Engineering Design & Economics, 155:441 Chemical Engineering Kinetics.
Thermodynamics is one of the main pillars of chemical engineering; others include transport
phenomena and reaction kinetics.

Textbook:
M. D. Koretsky, “Engineering and Chemical Thermodynamics,” 2nd Ed., J. Wiley & Sons Inc.,
(2013).

Bring your text to class (reference will be made to specific tables and figures during the
lectures)

Assessment:
Quizzes: 20 %, exams: 80 %

Course Content:
Book sections
0. Introduction

1. Basic Concepts 1.1,1.2


Properties
Extensive/Intensive, 1.3
Dependent/Independent 1.5
Equilibrium 1.4
P-V-T properties of pure substances, property tables 1.6, 1.7
The Ideal Gas Law 1.3

2. First Law of Thermodynamics


Heat & work 2.1
Reversible & irreversible processes 2.3
Closed systems 2.4, 2.7
Internal energy; Enthalpy; Heat capacity 2.6
Open systems 2.5, 2.8
Latent heat; Enthalpy of reactions 2.6
Thermodynamic cycles 2.9

3. Entropy & Second Law of Thermodynamics


Directionality & spontaneity of processes 3.1
2
Reversibility/Irreversibility 3.2
Entropy 3.3
The Second Law of Thermodynamics 3.4, 3.5
The Second Law of Thermodynamics (closed system) 3.6, 3.7
The Second Law of Thermodynamics (open system) 3.6, 3.7
The Rankine cycle; Refrigeration cycles 3.9

4. Equations of State
Intermolecular forces 4.2
Internal energy,
Attractive & repulsive forces
Ideal gas equation of state 4.1
Principle of corresponding states 4.2
Equations of State 4.3
van der Waals equation of state
Cubic equations of state
Virial equation of state
Generalized compressibility charts 4.4

5. Thermodynamic Property Relationships


Measured, fundamental, derived properties 5.1
Fundamental property relations 5.2
Thermodynamic web 5.2
Calculations of properties 5.3
Departure functions 5.4
Joule-Thomson expansion and Liquefaction 5.5

3
ABET Outcomes and Assessment

Program outcomes achieved in this course

(a) an ability to apply knowledge of mathematics, science, and engineering


(e) an ability to identify, formulate and solve engineering problems; and
(k) an ability to use the techniques, skills, and modern engineering tools necessary for
engineering practice

The achievement of outcomes (a), (e), and (k) will be addressed in this course as
follows:

Outcome (a): an ability to apply knowledge of mathematics, science, and engineering

Equations and models used are derived from the laws and fundamental relations of
thermodynamics. Concepts from chemistry and physics are correctly incorporated.

Outcome (e): an ability to identify, formulate and solve engineering problems

Systematic analysis has been applied for the solution of complex situations.

Outcome (k): an ability to use the techniques, skills, and modern engineering tools
necessary for engineering practice

Thermodynamic property estimators (ThermoSolver), word processing (such as WORD),


data analysis packages (such as Excel), and computational tools (MATLAB), are used as
needed. Graphical packages are used to generate publication-quality graphics.

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