CHEMISTRY DPP 1
BY GARIMA VERMA (CHEMISTRY FACULTY) | REFERRAL CODE : “CGVMAM”
IONIC EQUILIBRIUM
1 The formula weight of 𝐻2 𝑆𝑂4 is 98. The weight of the acid in 400 mL of 0.1
M solution is
(a) 2.45 g (b) 3.92 g (c) 4.90 g (d) 9.8 g
2 Normality of 2M sulphuric acid is
(a) 2 N (b) 4 N (c) N/2 (d) N/4
3 If pH = 3.31, then find out [𝐻 + ] (Approxy)
(a) 3.39 × 10−4 (b) 5 × 10−4 (c) 3.0 × 10−3 (d) None
4 If [𝑂𝐻 − ] = 5.0 × 10−5 M then pH will be
(a) 5 – log 5 (b) 9 + log 5 (c) log 5 – 5 (d) log 5 – 9
5 Basicity of 𝐻3 𝑃𝑂3 and 𝐻3 𝑃𝑂2 are respectively
(a) 1 and 2 (b) 2 and 3 (c) 3 and 2 (d) 2 and 1
6 Find out pH of solution having 2 × 10−3 moles of 𝑂𝐻 − ion’s in 2 litre
solution
(a) pH = 3 (b) pH = 3 + log 2 (c) pH = 3 – log 2 (d) pH = 11
7 pH of tomato juice is 4.4. Then concentration of 𝐻3 𝑂+ will be
(a) 39 × 10−4 (b) 3.9 × 10−5 (c) 3.9 × 10−4 (d) 3.9 × 105
8 8 g NaOH is dissolved in one litre of solution, the molarity of the solution is
(a) 0.2 M (b) 0.4 M (c) 0.02 M (d) 0.8 M
9 The amount of acetic acid present in 100 mL of 0.1M solution is
(a) 0.30 g (b) 3.0 g (c) 0.60 g (d) None
10 The number of milli equivalents of acid in 100 mL of 0.5N HCl solution is
(a) 50 (b) 100 (c) 25 (d) 200
CHEMISTRY DPP 1
BY GARIMA VERMA (CHEMISTRY FACULTY) | REFERRAL CODE : “CGVMAM”
11 If the molar concentration of 𝑃𝑏𝐼2 is 1.5 × 10−3 𝑚𝑜𝑙 𝐿−1 , the
concentration of iodide ions in g ion 𝐿−1 is
(a) 3.0 × 10−3 (b) 6.0 × 10−3
(c) 0.3 × 10−3 (d) 0.6 × 10−6
12 Order of dissociation of 0.1 N 𝐶𝐻3 𝐶𝑂𝑂𝐻 is (Dissociation constant =
1 × 10−5 )
(a) 10−5 (b) 10−4 (c) 10−3 (d) 10−2
13 If 𝛼 is the degree of dissociation of weak dibasic organic acid and y is the
hydrogen ion concentration, what is the initial concentration of acid
𝛼(𝑦)−1 𝑦(𝛼)−1
(a) 𝑀 (b) 𝑦(𝛼 )−1 𝑀 (c) 𝑀 (d) None of them
2 2
14 The degree of dissociation of acetic acid is given by the expression 𝛼 =
0.1 × 𝐶 −1 (where C = concentration of the acid) What is the pH of the
solution
(a) 1 (b) 2 (c) 3 (d) 4
15 Ostwald’s dilution law is not applicable for strong electrolytes because
(a) Strong electrolytes are completely ionised
(b) Strong electrolytes are volatile
(c) Strong electrolytes are unstable
(d) Strong electrolytes often contain metal ions
16 The degree of ionisation of a compound depends upon
(a) Size of the solute molecules (b) Nature of the solute molecules
(c) Nature of the container taken (d) The amount of current passed
17 Find out 𝐾𝑎 𝑓𝑜𝑟 10−2 𝑀 HCN acid, having pOH is 10
(a) 𝐾𝑎 = 10−4 (b) 𝐾𝑎 = 10−2 (c) 𝐾𝑎 = 10−5 (d) None of them
18 Which of the following will occur if a 1.0 M solution of a weak acid is
diluted to 0.01 M at constant temperature
CHEMISTRY DPP 1
BY GARIMA VERMA (CHEMISTRY FACULTY) | REFERRAL CODE : “CGVMAM”
(a) Percentage ionisation will increase (b) [𝐻 + ] will decrease to 0.01 M
(c) 𝐾𝑎 will increase (d) pH will decrease by 2 units
19 The pH of 0.15 M solution of HOCl (𝐾𝑎 = 9.6 × 10−6 ) is
(a) 4.42 (b) 2.92 (c) 3.42 (d) None
20 The extent of ionisation increases (weak electrolytes)
(a) With the increase in concentration of solute
(b) On decreasing the temp. of solution
(c) On addition of excess of water to the solution
(d) On stirring the solution vigorously
21 If Ka of HCN = 4 × 10−10 , then the pH of 2.5 × 10−1 molar HCN (aq) is
(a) 4.2 (b) 4.7 (c) 0.47 (d) 5.0
22 The molarity of nitrous acid at which its pH becomes 2. (𝐾𝑎 =
4.5 × 10−4 ) :-
(a) 0.3333 (b) 0.4444 (c) 0.6666 (d) 0.2222
23 Correct statement for HCN weak acid at 250 𝐶 temperature
𝐾𝑎 𝐾𝑎 ×[𝑂𝐻 − ]
(a) 𝛼 = (b) 𝛼 =
[𝐻 + ] 𝐾𝑤
2
(c) (a) & (b) both (d) 𝐾𝑏 = 𝐶𝛼
ANSWER KEYS
1.B 2.B 3.B 4.B 5.D 6.D 7.B
8.A 9.C 10.A 11.A 12.D 13.C 14.A
15.A 16.B 17.D 18.A 19.B 20.C 21.D
22.D 23.C
