Extraction of Gold: by Dr. Ahmed Ameed

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Extraction of Gold

By Dr. Ahmed Ameed

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Characteristics and uses of gold
 Density : 19.3 g/cm3, Tm:1064 oC
 Shinny: for Jewelry
 Durable: does not tarnish or corrode easily, sometimes
used in dentistry to make the crowns for teeth.
 Malleable and ductile: can be bent & flattened . For this
reason it is used to make fine wires and thin, flat sheets
 Good conductor for heat & electricity: used in
transistors, computer circuits & firefighting cloths.

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Types of ores

 Gold occurs principally as a Native metal,


usually alloyed with silver (as Electrum), or
with mercury(as an Amalgam). Native gold can occur
as sizeable nuggets, flakes, grains or microscopic
particles embedded in other rocks.
 Ores in which gold occurs in chemical composition
with other elements are comparatively rare. They
include calaverite, sylvanite,nagyagite, petzite and kren
nerite
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Gold extraction
Gold mining
• Hard rock mining – used
to extract gold encased in
rock. Either open pit
mining or underground
mining.

• Panning )‫ – (الفصل‬sand and gravel


(‫ )حصى‬containing gold is shaken
around with water in a pan. Gold
is much denser than rock, so
quickly settles to the bottom of
the pan.
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Gold extraction
Gold mining
• Sluicing – water is channelled to
flow through a sluice-box with
riffles )‫ (تموجات‬at the bottom which
create dead-zones in the water
current which allows gold to drop
out of suspension.

• Sluicing and panning results in the direct recovery of


small gold nuggets )‫(خامات الذهب‬and flakes.

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Gold extraction
Gold ore processing Gold cyanidation:

• The most commonly used process for gold extraction.

• Used to extract gold from low-grade ore.

• Gold is oxidised to a water-soluble aurocyanide


metallic complex Au(CN)2.
• In this dissolution process, the milled ore is agitated
with dilute alkaline cyanide solution, and air is
introduced:

4Au + 8NaCN + O2 + 2H2O  4NaAu(CN)2 + 4NaOH


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Gold extraction
Gold ore processing Gold cyanidation:

• At a slurry concentration of around 50% solids, the


slurry passes through a series of agitated mixing tanks
with a residence time of 24 hrs.

• The gold-bearing liquid is then separated from the


leached solids in thickener tanks or vacuum filters &
the tailings )‫ (مخلفات المعالجة‬are washed to remove Au
and CN- prior to disposal.

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Gold extraction
Gold ore processing Heap Leaching

• Is an alternative to the agitated leaching process.


• Drastically reduced gold recovery costs of low grade
ore.
• Ore grades as low as 0.3 g per ton can be
economically processed by heap leaching.

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Gold extraction
Gold ore processing Heap Leaching

• Generally requires 60 to 90 days for processing ore


that could be leached in 24 hrs in a conventional
agitated leach process.
• Au recovery is around 70% as compared with 90% in
an agitated leach plant.
• BUT, has gained wide favour due to vastly reduced
processing costs.
• Frequently, mines will use agitated leaching for high-
grade ore & heap leaching for low grade ores that
would otherwise be considered waste rock.
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Gold extraction
Gold ore processing Gold cyanidation:
Merrill-Crowe process
• Traditional method for Au recovery from pregnant
cyanide solutions.

• Once dissolution of Au is complete, the remaining rock


pulp if filtered off through various filters to produce a
sparkling )‫ (المع‬clear solution.

• O2 is removed from the clarified solution by passing


the solution through a vacuum deaeration column.

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Gold extraction
Gold ore processing Gold cyanidation:
Merrill-Crowe process
• Zinc dust is then added to the cyanide solution to
chemically reduce the gold to the metal.
2Au(CN)2 + Zn 2Au+ Zn(CN)4
• The metallic gold is then filtered out & refined.

Smelting of resultant powder (rich Au) into steel molds


and the slug is remove from the top furnace.

Electrolysis is done to get high gold grade 99.999%


purity.
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Cyanide process of gold production

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