MATERIAL SAFETY DATA SHEET

DISODIUM ETHYLENE BIS DITHIO CARBAMATE

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Product Name: NABAM 40% AQUEOUS SOLUTION

Company Identification: 237/2, Vellivoyal Chavadi
Chennai – 600 103. Tamilnadu
Office Telephone No: 044 64606747

2. COMPOSITION / INDORMATION OF INGREDIENTS

Chemical description: Disodium Ethylene Bis Dithio carbamate

CHEMICAL NAME CAS NO. CAS NO. EINECS NO. WT%

Disodium Ethylene Bis Dithio
142-59-6 205-547-0 38-40
Carbamate
Water 7732-18-5 - 62-60

3. HAZARD IDENTIFICATION

Classification of the substance or mixture :

Classification according to EU R22. R37, R43, R50/53, Xn, Xi, N
directives 67/548/EEC or 1999/45/EC
REGULATION (EC) No. 1272/2008
Classification of the substance or Acute toxicity, oral:cat4; Sensitization, Skin:cat1; Hazardous
mixture to the aquatic environment, long-term hazard: cat1
Label elements :
Hazard Statements H302- Harmful if swallowed.
H317- May cause an allergic skin reaction.
H410-- Very toxic to aquatic life with long lasting effects.
Precautionary Statements Prevention P264 - Wash skin thoroughly after handling
P273 - Avoid release to the environment.
P280 - Wear protective gloves/protective clothing/eye
protection /face protection.
Precautionary Statements Response P363 - Wash contaminated clothing before reuse
P302+P352 - IF ON SKIN: wash with plenty of soap and water.
P333+P313 -IF SKIN irritation or rash occurs: Get medical
advice/attention.
Precautionary Statements - storage P403+P404+P235-- Store in a dry place.
Store in a closed container. Keep cool.
Precautionary Statements - Disposal P501 - Dispose of contents/container to an approved waste
disposal plant

4. FIRST AID MEASURES

General Advice: If symptoms persist, call a physician. Show this material

safety data sheet to the Doctor in attendance. Treat
symptomatically. In case of allergic reaction after exposure,
any future exposure must be avoided.
Inhalation If breathed in, move person in to fresh air. If not breathing,
give artificial Respiration. Consult a physician
Skin Contact : In case of contact, immediately wash with plenty of soap
and water Seek medical attention.
Eye Contact : Rinse immediately as long as a possible with plenty of water.
Seek medical advice if irritation persist
Ingestion : Never give anything by mouth to an unconscious person.
Rinse mouth with water. Consult a physician..
Most important symptoms and effects, Harmful if swallowed. May cause an allergic skin reaction.
both acute and delayed Very toxic to aquatic life with long lasting effects chemicals
structurally related to tetra ethyl thiuram and other
halogenated hydrocarbons properties have not been
thoroughly investigated.

5. FIRE FIGHTING MEASURES

Extinguishing Media: Use water spray, alcohol- resistant foam, dry chemical or
carbon dioxide.
Special hazards arising from the Carbon oxides, nitrogen oxides(NOx), Sulphur oxides,
substance or mixture: Sodium oxides
Protective Equipment and Precautions Fire fighters should wear NIOSH/MSHA approved
for Firefighters self-contained breathing apparatus and full protective
clothing.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective Use personal protective equipment. Avoid breathing vapors,
equipment and emergency procedures: mist or gas. Ensure adequate ventilation. Evacuate
personnel to safe areas
Environmental precautions: Prevent further leakage or spill age if safe to do so. Do not
let product enter drains. Discharge into the environment
must be avoided
Methods and material for containment Stop leakage if possible. Collect as much as possible in a
and cleaning up: clean container for (preferable) reuse or disposal.

7. HANDLING AND STORAGE

Precautions for safe handling: Avoid breathing vapors and mists. Avoid director prolonged
contact with skin and eyes. Use personal protective
equipment. The usual precautions for handling chemicals
should be observed

Conditions for safe storage, including Store in cool place. Keep container tightly closed in a dry and
any incompatibilities & Storage: well-ventilated place.

8. EXPOSURE CONTROL / PERSONAL PROTECTION

Control parameters Components with work place control parameters

Exposure controls
Engineering Controls: Handle in accordance with good industrial hygiene and
safety Wash hands before breaks and at the end of work
day.
Personal Protective Equipment:
Eye/face Protection : Face shield and safety glasses Use equipment for eye
protection Tested and approved under appropriate
government standards such As NIOSH(US) or EN166(EU).
Skin Protection : Skin contact should be minimized through use of gloves and
suitable long- sleeved clothing. Gloves must be inspected
prior to use. Use proper glove removal technique (with out
touching glove's outer surface) to avoid skin contact with
this product. Dispose of contaminated gloves after use in
accordance with applicable laws and Good laboratory
practices. Wash and dry hands.
Body Protection : Complete suit protecting against chemicals. The type of
protective Equipment must be selected according to the
concentration and Amount of the dangerous substance at
the specific workplace
Environmental exposure controls: Prevent further leakage or spillage if safe to do so. Do not let
product enter drains. Discharge into the environment must
be avoided.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance: Liquid
Colour: Light Yellow
Odour: Slight ammoniacal odour
pH-value: 9.0-11.0
Melting point/Melting range: No data available
Boiling point/Boiling range: 100 C

Flash point : No data available

Explosive propertive : No data available
Flammability (solid, gas) : No data available
Explosion Limits : No data available
Vapour pressure : approx. 2.2 kPa (20 °C)
Specific gravity : 1.12 (approx.)
Vapour Density : No data available
Solubility : Soluble in water
Partition coefficient : No data available
Auto-ignition temperature : No data available
Viscosity @25°C : Not determined
Oxidizing properties : No data available

10. STABILITY AND REACTIVITY

Reactivity See incompatible material

Chemical stability Stable when stored at NTP in closed containers.
Stable under normal conditions of handling, use
&transportation
Possibility of hazardous reactions No data available
Conditions to avoid Keep away from heat, sparks and flame. Avoid contact with
strong oxidants.
Incompatible materials: Oxidising agents, acids and alkalis.
Hazardous decomposition products : Carbon oxides, nitrogen oxides(NOx), Sulphur oxides,
Sodium oxides, Hydrogen sulphide

11. TOXICOLOGICAL INFORMATION

Acute toxicity:
(LD50/oral/rat) 395 mg/kg
Inhalation : Limited possibility of over-exposure.
Skin irritation / sensitisation May cause skin irritation./ Not sensitizing
Respiratory or skin sensitization May cause allergic skin reaction.
Eye Irritation May cause irritation or damage.
Ingestion Moderate oral Toxicity ; may cause nausea, vomiting
Mutagenic Effects No data available
Reproductive toxicity : No data available
Target Organ Effects: No data available
Carcinogenicity : No component of this product present at levels greater
thanorequalto0.1%isidentifiedas probable, possible or
confirmed human carcinogen by IARC.
12. ECOLOGICAL INFORMATION

Eco toxicity :
Toxicity to fish LC50 : Cyprinodonvariegatus(sheep she admin now) - 0,14mg/l -
96,0h
Toxicity to daphnia and other aquatic EC50 - Daphnia magna(Water flea) -0,14 - 5,60mg/l -48h
invertebrates:
Toxicity to algae Growth inhibition : EC50 - Chlorella pyrenoidosa - 2,4mg/l - 96h
Mobility in soil No data available
Persistence and degradability: No data available
Bio accumulative potential: No data available
Results of PBT and vPvB assessment : No data available

13. DISPOSAL CONSIDERATIONS

Waste Disposal methods

Product: Offer surplus and non-recyclable solutions to a licensed
disposal company. Contact a licensed professional waste
disposal service to dispose of this material.
Dissolve or mix the material with a combustible solvent and
burn in a chemical incinerator equipped
With an after burner and scrubber.
Contaminated Packing Clean and Dispose of a sun used product

14. TRANSPORT INFORMATION

Road transport (ADR/RID/ADN)

ADR/RID Class 9
UN-No 3077
Packing Group III
Hazard Label Hazardous for the environment
Proper Shipping Name Environmentally hazardous substance, liquid, N.O.S
(Disodium ethylene bis dithio carbamate)
Sea transport (IMDG)
ADR/RID Class 9
UN-No 3077
Packing Group III
Marine pollutant Yes
Hazard Label Hazardous for the environment
Proper Shipping Name Environmentally hazardous substance, liquid, N.O.S
(Disodium ethylene bis dithio carbamate)
Air transport (ICAO‐TI/IATA)
ADR/RID Class 9
UN-No 3077
Packing Group III
Proper Shipping Name Environmentally hazardous substance, liquid, N.O.S
(Disodium ethylene bis dithio carbamate)

15. REGULATORY INFORMATION

Safety, health and environmental Regulation1907/2006REGULATION(EC)No1272/2008

regulations/legislation specific for the ClassificationaccordingtoEUdirectives67/548/EECor1999/45/EC
substance or mixture
Chemical safety assessment: No data available

16. OTHER INFORMATION

Emergency seek Medical Aids