VDM® Alloy 800 H/HP

Nicrofer 3220 H/HP

Data Sheet No. 4129 Revision 01

September 2017
September 2017 VDM® Alloy 800 H/HP 2

VDM® Alloy 800 H/HP

Nicrofer 3220 H/HP

VDM® Alloy 800 H is an austenitic, heat resistant iron- VDM® Alloy 800 HP is an austenitic nickel-iron-
nickel -chromium alloy with controlled levels of carbon, chromium alloy with increased content of (Al + Ti),
aluminum and titanium. compared to VDM® Alloy 800 H.

The analysis of VDM® Alloy 800 H is identical to that of A special solution annealing results in a grain sizes ≥
VDM® Alloy 800. A special solution annealing results in 90 µm (ASTM No. 4) and highest creep rupture
a grain sizes ≥ 90 µm (ASTM No. 4), which increases strength above 700 °C (1,290 °F) due to titanium car-
the creep rupture strength above 600 °C (1,112 °F) bide precipitation. Below 700 °C (1,290 °F), γ´ precipi-
significantly. tates combined with a loss of ductility.

VDM® Alloy 800 H is characterized by: VDM® Alloy 800 HP is characterized by:
 good creep rupture strength at temperatures  excellent creep rupture strength at tempera-
above 600 °C (1,112 °F) tures above 700 °C (1,290 °F)
 good resistance in oxidizing, nitriding and  good resistance to reducing, oxidizing and ni-
carburizing conditions triding atmospheres and to atmospheres
 metallurgical stability in long-term use at high which alternate between reducing and oxidiz-
temperatures ing conditions
 metallurgical stability in long-term use at high
temperatures

If the repeated lowering of operating temperatures below 700 °C (1,290 °F) cannot be ruled out, or the operating tem-
perature is permanently below 700 °C (1,290 °F), the use of VDM® Alloy 800 H is recommended. At temperatures be-
low 600 °C (1,112 °F), soft annealed VDM® Alloy 800 is generally used.

Designations and standards

Standard Material designation

VDM® Alloy 800 H VDM® Alloy 800 HP

1)
EN 1.4876 - X10NiCrAlTi32-20 1.4959 - X8NiCrAlTi32-212)
1.4958 - X5NiCrAlTi31-202)
ISO FeNi32Cr21AlTi-HC FeNi32Cr21AlTi-HT
UNS N08810 N08811
AFNOR Fe-Ni29Cr17
NA 15 (H)
1)
VdTÜV data sheet 412, version 01.84 with old W.-No. 1.4876
2)
W.-No. according to DIN EN 10302
Table 1a – Designations and standards
September 2017 VDM® Alloy 800 H/HP 3

Designations and standards

Product form DIN DIN EN ISO ASTM ASME VdTÜV SEW Others
Sheet, plate 10028-7 A 240 SA 240 412 ASME Code Case 13251)
100951) B 409 SB 409 4341) NACE MR 0175/ISO 15156
10302
Strip 10028-7 6208 A 240 SA 240 412 470 SAE AMS 58712)
10088-1 B 409 SB 409 4341)
10095
10302
Rod, bar 100951) B 408 SB 408 412 470
10302 B 564 SB 564 4341)
1)
only valid for VDM® Alloy 800 H
2)
only valid for VDM® Alloy 800 HP

Tabelle 1b – Designations and standards

Chemical
composition

VDM® Alloy 800 H

Ni Cr Fe C Mn Si Cu Al Ti P S (Al + Ti)
Min. 30 19 43 0,06 0,5 0,2 0,2 0,2
Max. 32 21 50 0,1 1 0,6 0,5 0,6 0,6 0,015 0,01 0,7
Table 2b – Chemical composition (wt.-%) of VDM® Alloy 800 H

VDM® Alloy 800 HP

Ni Cr Fe C Mn Si Cu Al Ti P S (Al + Ti)
Min. 30 19 43 0,06 0,5 0,2 0,2 0,3 0,85
Max. 32 22 50 0,1 1 0,6 0,5 0,6 0,6 0,015 0,01 1,2
Table 2b – Chemical composition (wt.-%) of VDM® Alloy 800 HP
September 2017 VDM® Alloy 800 H/HP 4

Physical
properties

Density Melting range Relative magnetic

permeability at 20 °C (68 °F)
8.4 g/cm3 (0.30 lb/in3) 1,350-1,400 °C (2,462-2,552 °F) 1.01
at 20 °C (68 °F)

Temperature Specific heat Thermal conductivity Electrical Modulus of elasticity Coefficient of thermal
resistivity expansion
K Btu W Btu ∙ in 10-6 10-6
°C °F Kg · K lb ∙ °F m∙K sq. ft ∙ h ∙ °F μΩ · cm GPa 103 ksi K °F
20 68 443 0.106 12.4 86 101 194 28.1 14 7.78
100 212 457 0.109 13.7 95.1 104 189 27.4 14.08 7.82
200 392 474 0.113 15.3 106.2 108 183 26.5 14.6 8.11
300 572 492 0.118 17 117.9 112 177 25.7 14.92 8.28
400 762 512 0.122 18.9 131.1 115 170 24.7 15.2 8.44
500 932 548 0.131 21.4 148.5 118 163 23.6 15.49 8.61
600 1,112 578 0.138 23.6 163.7 120 156 22.6 15.87 8.82
700 1,292 588 0.140 24.7 171.4 122 149 21.6 16.42 9.12
800 1,472 598 0.143 25.8 179 124 141 20.5 16.98 9.43
900 1,652 602 0.144 26.7 185.2 126 134 19.4 17.36 9.64
1,000 1,832 613 0.146 28 194.3 127 127 18.4 17.76 9.87
1,100 2,012 628 0.150 29.6 205.4 128 120 17.4 18.27 10.15
1,200 2,192 634 0.151 30.6 212.3 129 113 16.4 18.74 10.41

Table 3 – Typical physical properties of VDM Alloy 800 Hat room temperature and elevated temperatures
®

Microstructural
properties
VDM® Alloy 800, VDM® Alloy 800 H and VDM® Alloy 800 HP are austenitic solid solution alloys which precipitate car-
bides and γ' phase during high temperature ageing.
September 2017 VDM® Alloy 800 H/HP 5

Mechanical
properties
The following properties are applicable to VDM® Alloy 800 H and VDM® Alloy 800 HP in the annealed condition in the
following size ranges:
 Sheet, plate up to 50 mm (1.97 in)
 Strip up to 3 mm (0.12 in)
 Rod, bar and forgings up to 250 mm (9.84 in)
For larger dimensions, the properties are to be agreed separately. The values are valid for longitudinal and transverse
samples.

Temperature Yield strength Tensile strength Elongation

Rp 0.2 Rm A
°C °F MPa ksi MPa ksi %
20 68 170 24.7 450-700 65.3-101.5 Longit. 35
Transverse 30
100 212 140 20.3 4251) 61.6
200 392 115 16.7 4001) 58
300 572 95 13.8 3901) 56.6
400 762 85 12.3 3801) 55.1
500 932 80 11.6 3601) 52.2
600 1,112 75 10.9 3001) 43.5
1)
Average, for information only

Table 4 – Mechanical short-time properties of solution annealed VDM® Alloy 800 H and VDM® Alloy 800 HP at room temperature and elevated tempera-
tures; min. values according to VdTÜV data sheet 412

Product form Dimensions Yield strength Tensile strength Elongation

Rp 0.2 Rm A
mm MPa MPa %
Sheet, plate, strip ≤ 50 ≥ 170 450-700 ≥ 30
Rod, bar ≤ 160 ≥ 170 450-700 ≥ 30
Forging ≤ 250 ≥ 170 450-700 ≥ 30

Table 5 – Mechanical properties at room temperature according to according to VdTÜV data sheet 412

ISO V-notch impact toughness

Average values at room temperature, longit.: 150 J/cm 2
Average values at room temperature, transverse: 100 J/cm 2
September 2017 VDM® Alloy 800 H/HP 6

Temperature Creep strength Rm/105 h

UNS N088101) UNS N088111) VdTÜV 412 VdTÜV 434

°C °F MPa MPa MPa MPa
600 1,112 114 114 77
650 1,202 75 73 53
700 1,292 50 57 47 36
750 1,382 33 37 30 24
800 1,472 22 26 19 16
850 1,562 15 18 10 10.5
900 1,652 10 11 4 7
950 1,742 7
1)
VDM Metals calculation, based on ASME Code Case 1987; for 950 °C (1,742 °F) based on ASME Code Case 1988
Table 6 – Rm/105 h creep rupture strength

Corrosion resistance
The high nickel and chromium contents in VDM® Alloy 800 H and VDM® Alloy 800 HP ensure excellent resistance to
oxidation. The alloys are also highly resistant to carburizing, nitriding and oxidation in sulphurous atmospheres. The
protective oxide layer is adherent under static and cyclic thermal stress. Both materials are particularly resistant to
carburization if a thin oxide film was formed by pre-oxidation.

The resistance to hydrogen embrittlement of VDM® Alloy 800 H and 800 HP is excellent, so that the alloys can be used
in the production of hydrogen and steam/hydrocarbon reformers.

Applications
VDM® Alloy 800H and Alloy 800 HP have a wide range of applications in areas of elevated temperatures in furnace
construction, in the chemical industry, in environmental protection equipment, in the automotive industry and in power
plants. Typical applications include furnace muffles, containers, bins, holders in various heat treatment plants and
burner components.

Because of their resistance to carburization and nitriding, the alloys are furthermore used in the areas of:
 steam/hydrocarbon reformers
 ethylene pyrolysis
 Equipment for acetic anhydride and ketone production.
September 2017 VDM® Alloy 800 H/HP 7

Fabrication and
heat treatment
VDM® Alloy 800 H and Alloy 800 HP can readily be hot- and cold-worked and machined.

Heating
Workpieces must be clean and free of any contaminants before and during heat treatment. Sulfur, phosphor, lead and
other low-melting-point metals can lead to damages when heat treating VDM® Alloy 800 H and Alloy 800 HP. Sources
of such contaminants include marking and temperature-indicating paints and crayons, lubricating grease and fluids, and
fuels. Heat treatments can be carried out in gas fired, oil fired or electric furnaces in air, under vacuum or inert gas
atmosphere. Fuels should contain as little sulfur as possible. Natural gas should contain less than 0.1 wt.-% of sulfur.
Heating oil with a sulfur content of maximum 0.5 wt.-% is also suitable with a slightly oxidizing atmosphere. Reducing or
changing furnace atmosphere should be avoided, as well as direct flame impingement. The temperature should be
precisely controlled.

Hot working
VDM® Alloy 800 H and Alloy 800 HP may be hot-worked in the temperature range 1,200 to 900 °C (2,192 to 1,650 °F)
with subsequent rapid cooling down in water or by using air. In particular the temperature range from 760 to 540 °C
(1,400 to 1,004 °F) must be passed quickly. Hot bending is carried out at 1,150 to 1,000 °C (2,102 to 1,832 °F). The
furnace should be heated up to maximum working temperature (1,200 °C/2,192 °F) before workpieces are inserted into
the preheated furnace. The holding time is about 60 minutes per 100 mm thickness. After the hot forming a solution
heat treatment is recommended in order to achieve optimum creep strength.

Cold working
Cold working should be carried out on annealed material. VDM® Alloy 800 H and Alloy 800 HP have a higher work
hardening rate than austenitic stainless steels. This must be taken into account during design and selection of forming
tools and equipment and during the planning of the forming processes. Intermediate annealing may be necessary at
high degrees of cold working deformation.

After cold working with more than 10 % deformation the material should be solution annealed.

Heat treatment
Solution heat treatment should be carried out at the following temperatures:
 VDM® Alloy 800 H: 1,150 °C (2,102 °F)
 VDM® Alloy 800 HP: 1,150 bis 1,200 °C (2,102 to 2,192 °F)

The retention time during annealing depends on the workpiece thickness and can be calculated as follows:
 For thicknesses d ≤ 10 mm (0.4 in) the retention time is t = d • 3 min/mm
 For thicknesses d = 10 to 20 mm (0.4 to 0.8 in) the retention time is t = 30 min + (d - 10 mm) • 2 min/mm
 For thicknesses d > 20 mm (0.8 in) the retention time is t = 50 min + (d - 20 mm) • 1 min/mm
The retention time starts when the annealing temperature is reached. Longer retention times are less critical than too
short retention times.

Water quenching should be carried out rapidly if the material should be further fabricated after solution annealing.
Workpieces of less than 3 mm (0.12 in) thickness can be cooled down using air nozzles. If the solution annealing is the
last fabrication step, the material can be cooled down more slowly in order to avoid material distortion.

Solution annealed VDM® Alloy 800 H and 800 HP are prone to stress relaxation cracks in the temperature range of 550
and 750 °C and should therefore be subjected to stabilizing annealing when a continuous operation (> 100 h) in the
mentioned temperature range is intended. The stabilizing annealing temperature depends on the welding material and
September 2017 VDM® Alloy 800 H/HP 8

should be determined with VDM Metals’ Technical Customer Support. If possible, the stabilizing annealing should be
carried out when all welding work is completed, because the heat-affected zones of the welds are particularly suscepti-
ble to cracking. Heating rates are critical and should not be too high to avoid disortion.

The cleanliness requirements listed under ‘Heating’ must be complied with.

Descaling and pickling

High temperature alloys develop a protective oxide layer in service. Therefore the necessity of descaling should be
checked during the order process. Oxides of VDM® Alloy 800 H and 800 HP and discoloration adjacent to welds are
more adherent than on stainless steels. Grinding with very fine abrasive belts or discs is recommended. Care should be
taken to prevent tarnishing.

Before pickling, which should preferably carried out in nitric hydrofluoric acid, oxide and scale layers have to be disrupt-
ed by blasting or treated in oxidizing salt melts. The pickling baths used must carefully be monitored regarding the con-
centration and temperatures; through too long pickling times, the material surface may be damaged by intergranular
corrosion.

Machining
VDM® Alloy 800 H and 800 HP should be machined in the solution annealed condition. As the alloys are prone to work-
hardening, low cutting speeds and appropriate feed rates should be used and the tool should be engaged at all times.
Sufficient chip depths are important to get below the work-hardened surface layer.

Due to the high temperature loads on the cutting edge during machining, large amounts of cooling lubricants should be
used. Water-based emulsions, as they are also used for construction and stainless steels, are suitable for instance.

Welding
When welding nickel-base alloys and special stainless steels, the following instructions should be adhered to:

Workplace
A separately-located workplace, which is specifically separated from areas in which carbon steels are being processed,
should be used. Maximum cleanliness is required, and draughts should be avoided during inert gas welding.

Auxiliary equipment and clothing

Clean fine leather gloves and clean working clothes should be used.

Tools and machines

Tools used for other materials must not be used for nickel-base alloys and stainless steels. Brushes should be made of
stainless materials. Processing and machining equipment such as shears, punches or rollers must be fitted with means
(felt, cardboard, films) in order to avoid material contamination with ferrous particles, which can be pressed into the
surface of the material and thus lead to corrosion.
September 2017 VDM® Alloy 800 H/HP 9

Welding edge preparation

Welding edge preparation should preferably be carried out using mechanical methods such as lathing, milling or plan-
ing. Abrasive waterjet cutting or plasma cutting is also suitable. In the latter case, however, the cut edge (seam flank)
must be cleanly re-worked. Careful grinding without overheating is also acceptable.

Ignition
The arc may only be struck in the weld area, e.g. along the seam flanks or outlets, and should not be carried out on the
workpiece surface. Arc striking areas are prone to corrosion.

Included angle
The different physical characteristics of nickel alloys and special stainless steels are generally reflected through lower
thermal conductivity and higher thermal expansion in comparison with carbon steel. This should be allowed for by
means of, among other things, wider root gaps or openings (1-3 mm; 0.04-1.2 in), while larger included angles (60-70°),
as shown in Fig. 1, should be used for individual butt joints owing to the viscous nature of the molten weld metal and to
counteract the pronounced shrinkage tendency.

Figure 1 – Edge preparation for welding nickel alloys

and special stainless steels
September 2017 VDM® Alloy 800 H/HP 10

Cleaning
Cleaning of the base material in the seam area (both sides) and the filler material (e.g. welding rod) should be carried
out using Acetone.

Welding process
For welding, VDM® Alloy 800 H and 800 HP should be in the annealed condition and be free from scale, grease and
markings. VDM® Alloy 800 H and 800 HP can be welded using the following procedures: GTAW (TIG), GTAW (TIG)
hot wire, plasma, SMAW (MMA), GMAW (MIG/MAG) and submerged arc welding.

Filler metal
The following filler materials are recommended:

VDM® FM 82 (W.-Nr. 2.4806)

DIN EN ISO 18274: S Ni 6082 (SG/UP-NiCr 20 Nb)
AWS A 5.14: ERNiCr-3

The use of covered electrodes is possible.

Welding parameters and influences

Care should be taken that the work is performed with a deliberately chosen, low heat input as indicated in Table 7 by
way of example. The stringer bead technique is recommended. In this context attention should also be drawn to the
correct selection of wire and electrode diameters. The corresponding section energies are exemplified in Table 7 below.
The interpass temperature should not exceed 120 °C (248 °F). The welding parameters should be monitored as a mat-
ter of principle.

The heat input Q may be calculated as follows:

U · I · 60 kJ
Q= ( )
v · 1.000 cm

U = arc voltage, volts

I = welding current, amps
v = welding speed, cm/min.

Post-weld treatment
Brushing with a stainless steel wire brush immediately after welding, i.e. while the metal is still hot generally results in
removal of heat tint and produces the desired surface condition without additional pickling. Pickling, if required or pre-
scribed, however, would generally be the last operation performed on the weldment. Please also refer to the infor-
mation on ‘Descaling and pickling’. Neither pre- nor postweld heat treatments are required.
September 2017 VDM® Alloy 800 H/HP 11

Thickness Welding Filler material Root pass1) Intermediate Welding Shielding gas
technique and final passes speed

Diameter Speed Rate

(mm) (mm) (m/min) I in (A) U in (V) I in (A) U in (V) (cm/min) Type (l/min)
3 manual TIG 2 – 90 10 110-120 11 10-15 I1, R1 mit max. 3% 8-10
N2

6 manual TIG 2-2,4 – 100-110 10 120-130 12 10-15 I1, R1 mit max. 3% 8-10
N2

8 manual TIG 2,4 – 110-120 11 130-140 12 10-15 I1, R1 mit max. 2% 8-10
N2

3 autom. TIG 0,8-1,2 1-2,5 - - 150 10 25 I1, R1 mit max. 2% 15-20

HD2) N2

5 autom. TIG 0,8-1,2 1-2,5 - – 150 10 25 I1, R1 mit max. 2% 15-20

HD2) N2

6 Plasma3) 1,0-1,2 1 165 25 - – 25 I1, R1 mit max. 2% 30

N2

8 Plasma3) 1,0-1,2 1 190-200 25 - – 30 I1, R1 mit max. 2% 30

N2

8 GMAW 4) 1 8 - - 140-160 25-28 25-30 I1, R1 mit max. 2% 18-20

N2

≥ 10 GMAW 4) 1,2 5 – – 150 23-27 I1, R1 mit max. 2% 18-20

N2

≥ 12 Submerged 1,6 - – – 250 28 44-55 - -

arc welding

1)
It must be ensured that there is sufficient root protection, for example using Ar 4.6, for all inert gas welding processes.
2)
The root pass should be welded manually (see manual TIG).
3)
Recommended plasma gas Ar 4.6 / rate 3.0 to 3.5 l/min
4)
For MAG welding the use of multicomponent inert gases is recommended.
Section energy kJ/cm:
autom. TIG HD max. 6, TIG, GMAW manual, autom. max. 8; Plasma max. 10
Figures are for guidance only and are intended to facilitate setting of the welding machines.

Table 7 – Welding parameters

September 2017 VDM® Alloy 800 H/HP 12

Availability
VDM® Alloy 800 H and HP are available in the following standard semi-finished product forms:

Sheet and plate

Delivery conditions: hot or cold rolled, heat treated, descaled resp. pickled

Condition Thickness Width Length Piece weight

mm (in) mm (in) mm (in) kg
Cold rolled 1-7 (0.04-0.28) 1,000-2,500 (39.37-98.43) ≤ 5,500 (216.54) –
Hot rolled* 3-80 (0.12-3.15) ≤ 2,500 (39.37-98.43) ≤ 12,000 (472.44) ≤ 2,250
* 2 mm thickness on request

Strip
Delivery conditions: cold rolled, heat treated, pickled or bright annealed

Thickness Width Coil - inside diameter

mm (in) mm (in) mm
0.02-0.15 4-230 300 400 500 –
(0.0008-0.0059) (0.16-9.06)
0.15-0.25 4-720 300 400 500 –
(0.0059-0.01) (0.16-28.34)
0.25-0.6 6-750 – 400 500 600
(0.01-0.024) (0.24-29.5)
0.6-1 8-750 – 400 500 600
(0.024-0.04) (0.32-29.5)
1-2 15-750 – 400 500 600
(0.04-0.08) (0.6-29.5)
2-3 25-750 – 400 500 600
(0.08-0.12) (0.98-29.5)

Rod and bar

Delivery conditions: forged, rolled, drawn, heat treated, oxidised, descaled resp. pickled, machined, peeled, ground or
polished

Dimensions* Outside diameter Length

mm (in) mm (in)
General dimensions 6-800 (0.24-31.5) 1,500-12,000 (59.06-472.44)
Material specific dimensions 12-500 (0.47-19.69) 1,500-12,000 (59.06-472.44)
* Further dimensions on request

Wire
Delivery conditions: bright drawn, ¼ hard to hard, bright annealed in rings, containers, on spools and spiders

Drawn Hot rolled

mm (in) mm (in)
0.16-10 (0.006-0.4) 5.5-19 (0.22-0.75)

Other shapes and dimensions such as circular blanks, rings, seamless or longitudinal welded tubes and pipes
or forgings are subject to special enquiry.
September 2017 VDM® Alloy 800 H/HP 13

Technical
publications
K. Drefahl, K. H. Matucha, F. Hofmann: Determination and Valuation of Extrapolation Parameters for Creep-Stressed
Nickel-Based High Temperature Materials, CORROSION 86, Paper No. 376, NACE International Houston, Texas,
1986.

V. Coppolecchia, J. Bryant, F. Hofmann, K. Drefahl: Loss of Creep Ductility in Alloy 800 H with High Levels of Titanium
and Aluminium, in Performance of High Temperature Materials, ASM International,1987, S. 201 – 208.

U. Brill, U. Heubner, K. Drefahl, H.-J. Henrich:

Zeitstandwerte von Hochtemperaturwerkstoffen,Ingenieur-Werkstoffe 3 (1991) No. 4, S. 59 – 62.
U. Heubner, J. Klöwer et al.: "Nickelwerkstoffe und hochlegierte Sonderedelstähle", 5. Auflage, Expert Verlag, Rennin-
gen-Malmsheim, 2012.
September 2017 VDM® Alloy 800 H/HP 14

Imprint

Date of publication
7 September 2017

Publisher
VDM Metals GmbH
Plettenberger Straße 2
58791 Werdohl
Germany

Disclaimer
All information contained in this data sheet are based on the results of research and development work carried out by
VDM Metals GmbH, and the data contained in the specifications and standards listed available at the time of printing.
The information does not represent a guarantee of specific properties. VDM Metals reserves the right to change infor-
mation without notice. All information contained in this data sheet is compiled to the best of our knowledge and is pro-
vided without liability. Deliveries and services are subject exclusively to the relevant contractual conditions and the
General Terms and Conditions issued by VDM Metals GmbH. Use of the latest version of this data sheet is the respon-
sibility of the customer.

VDM Metals GmbH

Plettenberger Straße 2
58791 Werdohl
Germany

Tel +49 (0)2392 55 0

Fax +49 (0)2392 55 22 17

[email protected]
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