SAFETY DATA SHEET

Product Trade Name: QUIK-FOAM

Revision Date: 27-Jun-2016 Revision Number: 16

1. Identification
1.1. Product Identifier
Product Trade Name: QUIK-FOAM
Synonyms None
Chemical Family: Blend
Internal ID Code HM003746

1.2 Recommended use and restrictions on use

Application: Foaming Agent
Uses advised against No information available

1.3 Manufacturer's Name and Contact Details

Manufacturer/Supplier
Baroid Fluid Services
Product Service Line of Halliburton
P.O. Box 1675
Houston, TX 77251
Telephone: (281) 575-5000
Emergency Telephone: 1-866-519-4752 (US, Canada, Mexico) or 1-760-476-3962

Halliburton Energy Services

645 - 7th Ave SW Suite 1800
Calgary, AB
T2P 4G8
Canada

Prepared By Chemical Stewardship

Telephone: 1-281-871-6107
e-mail: [email protected]

1.4. Emergency telephone number

Emergency Telephone Number: 1-866-519-4752 or 1-760-476-3962

2. Hazard(s) Identification
2.1 Classification in accordance with paragraph (d) of 1910.1200

Skin Corrosion / Irritation Category 2 - H315

Serious Eye Damage/Irritation Category 1 - H318
Acute Aquatic Toxicity Category 2 - H401
Chronic Aquatic Toxicity Category 3 - H412
Flammable liquids. Category 3 - H226

2.2. Label Elements

Hazard pictograms

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Signal Word: Danger

Hazard Statements H226 - Flammable liquid and vapor

H315 - Causes skin irritation
H318 - Causes serious eye damage
H401 - Toxic to aquatic life
H412 - Harmful to aquatic life with long lasting effects

Precautionary Statements

Prevention P210 - Keep away from heat/sparks/open flames/hot surfaces. - No smoking

P233 - Keep container tightly closed
P240 - Ground/Bond container and receiving equipment
P241 - Use explosion-proof electrical/ventilating/lighting/equipment
P242 - Use only non-sparking tools
P243 - Take precautionary measures against static discharge
P264 - Wash face, hands and any exposed skin thoroughly after handling
P273 - Avoid release to the environment
P280 - Wear protective gloves/eye protection/face protection
Response P302 + P352 - IF ON SKIN: Wash with plenty of soap and water
P332 + P313 - If skin irritation occurs: Get medical advice/attention
P362 - Take off contaminated clothing and wash before reuse
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several
minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P310 - Immediately call a POISON CENTER or doctor/physician
P370 + P378 - In case of fire: Use water spray for extinction
Storage P403 + P235 - Store in a well-ventilated place. Keep cool
Disposal P501 - Dispose of contents/container in accordance with
local/regional/national/international regulations

2.3 Hazards not otherwise classified

None known

3. Composition/information on Ingredients
Substances CAS Number PERCENT (w/w) GHS Classification - US
Ethanol 64-17-5 5 - 10% Eye Irrit. 2A (H319)
Flam. Liq. 2 (H225)
Isopropanol 67-63-0 5 - 10% Eye Irrit. 2 (H319)
STOT SE 3 (H336)
Flam. Liq. 2 (H225)
Surfactant Proprietary 30 - 60% Skin Irrit. 2 (H315)
Eye Corr. 1 (H318)

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Aquatic Acute 2 (H401)
Aquatic Chronic 3 (H412)

The exact percentage (concentration) of the composition has been withheld as proprietary.

4. First-Aid Measures
4.1. Description of first aid measures
Inhalation If inhaled, move victim to fresh air and seek medical attention.
Eyes Immediately flush eyes with large amounts of water for at least 30 minutes. Seek
prompt medical attention.
Skin Wash off immediately with soap and plenty of water for at least 15 minutes while
removing all contaminated clothing and shoes. Get medical attention if irritation
persists.
Ingestion Do NOT induce vomiting. Give nothing by mouth. Obtain immediate medical
attention.

4.2 Most important symptoms/effects, acute and delayed

Causes severe eye irritation which may damage tissue. Causes skin irritation.

4.3. Indication of any immediate medical attention and special treatment needed
Notes to Physician Treat symptomatically.

5. Fire-fighting measures
5.1. Extinguishing media
Suitable Extinguishing Media
Water fog, carbon dioxide, foam, dry chemical.
Extinguishing media which must not be used for safety reasons
None known.

5.2 Specific hazards arising from the substance or mixture

Special exposure hazards in a fire
May be ignited by heat, sparks or flames Use water spray to cool fire exposed surfaces. Closed containers may explode in fire.
Decomposition in fire may produce harmful gases.

5.3 Special protective equipment and precautions for fire-fighters

Special protective equipment for firefighters
Full protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.

6. Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
Use appropriate protective equipment.
See Section 8 for additional information

6.2. Environmental precautions

Prevent from entering sewers, waterways, or low areas.

6.3. Methods and material for containment and cleaning up

Isolate spill and stop leak where safe. Remove ignition sources and work with non-sparking tools. Contain spill with
sand or other inert materials. Scoop up and remove.

7. Handling and storage

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7.1. Precautions for safe handling

Handling Precautions
Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after use. Launder contaminated
clothing before reuse. Ground and bond containers when transferring from one container to another.
Hygiene Measures
Handle in accordance with good industrial hygiene and safety practice.

7.2. Conditions for safe storage, including any incompatibilities

Storage Information
Store away from oxidizers. Store away from alkalis. Keep from heat, sparks, and open flames. Keep container closed
when not in use. Product has a shelf life of 24 months.

8. Exposure Controls/Personal Protection

8.1 Occupational Exposure Limits
Substances CAS Number OSHA PEL-TWA ACGIH TLV-TWA
Ethanol 64-17-5 1000 ppm STEL: 1000 ppm
Isopropanol 67-63-0 TWA: 400 ppm TWA: 200 ppm
STEL: 400 ppm
Surfactant Proprietary Not applicable Not applicable

8.2 Appropriate engineering controls

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas
without good cross ventilation.

8.3 Individual protection measures, such as personal protective equipment

Personal Protective Equipment If engineering controls and work practices cannot prevent excessive exposures,
the selection and proper use of personal protective equipment should be
determined by an industrial hygienist or other qualified professional based on the
specific application of this product.
Respiratory Protection Organic vapor respirator.

Hand Protection Impervious rubber gloves.

Skin Protection Rubber apron.
Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.
Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. Physical and Chemical Properties

9.1. Information on basic physical and chemical properties
Physical State: Liquid Color Light yellow
Odor: Alcohol Odor No information available
Threshold:

Property Values
Remarks/ - Method
pH: 7.3-7.8
Freezing Point / Range No data available
Melting Point / Range No data available
Boiling Point / Range No data available
Flash Point 23 C / 74 F PMCC
Flammability (solid, gas) No data available
Upper flammability limit 12%
Lower flammability limit 2%
Evaporation rate No data available
Vapor Pressure No data available

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Vapor Density No data available
Specific Gravity 1.02
Water Solubility Soluble in water
Solubility in other solvents No data available
Partition coefficient: n-octanol/water No data available
Autoignition Temperature 398 C / 750 F
Decomposition Temperature No data available
Viscosity No data available
Explosive Properties No information available
Oxidizing Properties No information available

9.2. Other information

VOC Content (%) No data available

10. Stability and Reactivity

10.1. Reactivity
Not expected to be reactive.

10.2. Chemical stability

Stable

10.3. Possibility of hazardous reactions

Will Not Occur

10.4. Conditions to avoid

Keep away from heat, sparks and flame.

10.5. Incompatible materials

Strong oxidizers. Strong alkalis.

10.6. Hazardous decomposition products

Oxides of sulfur. Oxides of nitrogen. Ammonia. Carbon monoxide and carbon dioxide.

11. Toxicological Information

11.1 Information on likely routes of exposure
Principle Route of Exposure Eye or skin contact, inhalation.

11.2 Symptoms related to the physical, chemical and toxicological characteristics

Acute Toxicity
Inhalation May cause mild respiratory irritation. May cause central nervous system
depression including headache, dizziness, drowsiness, incoordination, slowed
reaction time, slurred speech, giddiness and unconsciousness.
Eye Contact Causes severe eye irritation which may damage tissue.
Skin Contact Causes skin irritation.
Ingestion Irritation of the mouth, throat, and stomach. May cause central nervous system
depression including headache, dizziness, drowsiness, muscular weakness,
incoordination, slowed reaction time, fatigue blurred vision, slurred speech,
giddiness, tremors and convulsions.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 0.1%
are chronic health hazards.

11.3 Toxicity data

Toxicology data for the components

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Substances CAS Number LD50 Oral LD50 Dermal LC50 Inhalation
Ethanol 64-17-5 7060 mg/kg (Rat) > 15,800 mg/kg (Rabbit) 124.7 mg/L (Rat) 4h
10,470 mg/kg (Rat) 17,100 mg/kg (Rabbit)
Isopropanol 67-63-0 5840 mg/kg-bw (rat) 12870 mg/kg-bw (rabbit) 72.6 mg/L (Rat, 4h, vapor)
Surfactant Proprietary > 2000 mg/kg (Rat) (similar > 2000 mg/kg (Rabbit) (similar No data available
substance) substance)

Substances CAS Number Skin corrosion/irritation

Ethanol 64-17-5 Not irritating to skin in rabbits.
Isopropanol 67-63-0 Non-irritating to the skin (Rabbit)
Surfactant Skin, rabbit: Causes moderate skin irritation. (similar substances)

Substances CAS Number Serious eye damage/irritation

Ethanol 64-17-5 Causes moderate eye irritation (Rabbit)
Isopropanol 67-63-0 Causes moderate eye irritation (Rabbit)
Surfactant May cause moderate to severe eye irritation.

Substances CAS Number Skin Sensitization

Ethanol 64-17-5 Did not cause sensitization on laboratory animals
Isopropanol 67-63-0 Did not cause sensitization on laboratory animals (guinea pig)
Surfactant Did not cause sensitization on laboratory animals (similar substances)

Substances CAS Number Respiratory Sensitization

Ethanol 64-17-5 Did not cause sensitization on laboratory animals
Isopropanol 67-63-0 No information available
Surfactant No information available

Substances CAS Number Mutagenic Effects

Ethanol 64-17-5 Not regarded as mutagenic.
Isopropanol 67-63-0 In vitro tests did not show mutagenic effects. In vivo tests did not show mutagenic effects.
Surfactant In vitro tests did not show mutagenic effects In vivo tests did not show mutagenic effects. (similar
substances)

Substances CAS Number Carcinogenic Effects

Ethanol 64-17-5 Did not show carcinogenic effects in animal experiments
Isopropanol 67-63-0 Did not show carcinogenic effects in animal experiments
Surfactant Did not show carcinogenic effects in animal experiments (similar substances)

Substances CAS Number Reproductive toxicity

Ethanol 64-17-5 Animal testing did not show any effects on fertility.
Isopropanol 67-63-0 No significant toxicity observed in animal studies at concentration requiring classification. Animal
testing did not show any effects on fertility.
Surfactant Did not show teratogenic effects in animal experiments. Not a confirmed reproductive toxicant. (similar
substances)

Substances CAS Number STOT - single exposure

Ethanol 64-17-5 No significant toxicity observed in animal studies at concentration requiring classification.
Isopropanol 67-63-0 May cause headache, dizziness, and other central nervous system effects.
Surfactant No data of sufficient quality are available.

Substances CAS Number STOT - repeated exposure

Ethanol 64-17-5 No significant toxicity observed in animal studies at concentration requiring classification.
Isopropanol 67-63-0 No significant toxicity observed in animal studies at concentration requiring classification. (similar
substances)
Surfactant No significant toxicity observed in animal studies at concentration requiring classification. (similar
substances)

Substances CAS Number Aspiration hazard

Ethanol 64-17-5 Not applicable
Isopropanol 67-63-0 Not applicable
Surfactant Not applicable

12. Ecological Information

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12.1. Toxicity
Ecotoxicity effects
Product is not classified as hazardous to the environment.
Product Ecotoxicity Data
No data available

Substance Ecotoxicity Data

Substances CAS Number Toxicity to Algae Toxicity to Fish Toxicity to Toxicity to Invertebrates
Microorganisms
Ethanol 64-17-5 No information available LC50 > 100 mg/L No information available LC50 9268 - 14,221 mg/L
(Pimephales promelas) (Daphnia magna)
LC50 5012 mg/L
(Ceridaphnia dubia)
NOEC 9.6 mg/L (Daphnia
magna)
Isopropanol 67-63-0 EC50 (72h) > 1000 mg/L LC50 (96h) 9640 mg/L TT (16h) 1050 mg/L EC50 (48h) 13,299 mg/L
(Desmodesmus (Pimephales promelas) (Pseudomonas putida) (Daphnia magna)
subspicatus) LC50 (7d) 7060 mg/L EC50 (24h) > 10,000
EC50 (7d) 1800 mg/L (Poecilia reticulata) mg/L (Daphnia magna)
(Scenedesmus
quadricauda)
Surfactant Proprietary EC50 (5d) 101 mg/L NOEC (28d) 0.12 mg/L EC50 (3h) > 1600 mg/L EC50 (48h) 3.43 mg/L
(Selenastrum (Oncorhynchus mykiss) (similar substance) (Ceriodaphnia dubia)
capricornutum) (similar (similar substance) (similar substance)
substance) EC50 (24h) 21 mg/L
(Daphnia magna) (similar
substance)
EC50 (96h) 5.7 mg/L
(Daphnia magna) (similar
substance)
NOEC (7d) 0.34 mg/L
(Ceriodaphnia dubia)
(similar substance)
NOEC (21d) 16.5 mg/L
(Daphnia magna) (similar
substance)
NOEC (7d) 6.3 mg/L
(Ceriodaphnia dubia)
(similar substance)

12.2. Persistence and degradability

Substances CAS Number Persistence and Degradability

Ethanol 64-17-5 No information available
Isopropanol 67-63-0 Readily biodegradable (53% @ 5d)
Surfactant Proprietary Readily biodegradable (similar substances)

12.3. Bioaccumulative potential

Substances CAS Number Log Pow

Ethanol 64-17-5 -0.32
Isopropanol 67-63-0 LogKow < 4.5
Surfactant Proprietary No information available

12.4. Mobility in soil

Substances CAS Number Mobility

Ethanol 64-17-5 No information available
Isopropanol 67-63-0 KOC = 1.5
Surfactant Proprietary No information available

12.5 Other adverse effects

No information available

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13. Disposal Considerations
13.1. Waste treatment methods
Disposal methods Disposal should be made in accordance with federal, state, and local regulations.
Contaminated Packaging Follow all applicable national or local regulations.

14. Transport Information

US DOT
UN Number UN1993
UN proper shipping name: Flammable Liquid, N.O.S. (Contains Ethanol, Isopropanol)
Transport Hazard Class(es): 3
Packing Group: III
Environmental Hazards: Not applicable
NAERG: NAERG 128
Not Restricted when shipped in containers less than 119 gallons as authorized by 49 CFR 173.150(e)(1)
and 49 CFR 173.150(f)(2).

Canadian TDG
UN Number UN1993
UN proper shipping name: Flammable Liquid, N.O.S. (Contains Ethanol, Isopropanol)
Transport Hazard Class(es): 3
Packing Group: III
Environmental Hazards: Not applicable

IMDG/IMO
UN Number UN1993
UN proper shipping name: Flammable Liquid, N.O.S. (Contains Ethanol, Isopropanol)
Transport Hazard Class(es): 3
Packing Group: III
Environmental Hazards: Not applicable
EMS: EmS F-E, S-E

IATA/ICAO
UN Number UN1993
UN proper shipping name: Flammable Liquid, N.O.S. (Contains Ethanol, Isopropanol)
Transport Hazard Class(es): 3
Packing Group: III
Environmental Hazards: Not applicable

Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable
Special Precautions for User None

15. Regulatory Information

US Regulations
US TSCA Inventory All components listed on inventory or are exempt.

TSCA Significant New Use Rules - S5A2

Substances CAS Number TSCA Significant New Use Rules - S5A2
Ethanol 64-17-5 Not applicable
Isopropanol 67-63-0 Not applicable
Surfactant Proprietary Not applicable

EPA SARA Title III Extremely Hazardous Substances

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Substances CAS Number EPA SARA Title III Extremely Hazardous
Substances
Ethanol 64-17-5 Not applicable
Isopropanol 67-63-0 Not applicable
Surfactant Proprietary Not applicable

EPA SARA (311,312) Hazard Class

Acute Health Hazard
Fire Hazard

EPA SARA (313) Chemicals

Substances CAS Number Toxic Release Inventory (TRI) - Toxic Release Inventory (TRI) -
Group I Group II
Ethanol 64-17-5 Not applicable Not applicable
Isopropanol 67-63-0 1.0% Not applicable
Surfactant Proprietary Not applicable Not applicable

EPA CERCLA/Superfund Reportable Spill Quantity

Substances CAS Number CERCLA RQ
Ethanol 64-17-5 Not applicable
Isopropanol 67-63-0 Not applicable
Surfactant Proprietary Not applicable

EPA RCRA Hazardous Waste Classification

If product becomes a waste, it does meet the criteria of a hazardous waste as defined by the US EPA, because of:

Ignitability D001

California Proposition 65 The California Proposition 65 regulations apply to this product.

MA Right-to-Know Law One or more components listed.

NJ Right-to-Know Law One or more components listed.

PA Right-to-Know Law One or more components listed.

NFPA Ratings: Health 1, Flammability 3, Reactivity 0

HMIS Ratings: Health 1, Flammability 3, Physical Hazard 0 , PPE: H

Canadian Regulations
Canadian Domestic Substances All components listed on inventory or are exempt.
List (DSL)

16. Other information

Preparation Information
Prepared By Chemical Stewardship
Telephone: 1-281-871-6107
e-mail: [email protected]

Revision Date: 27-Jun-2016

Reason for Revision SDS sections updated:

2

Additional information

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For additional information on the use of this product, contact your local Halliburton representative.

For questions about the Safety Data Sheet for this or other Halliburton products, contact Chemical Stewardship at
1-580-251-4335.

Key or legend to abbreviations and acronyms used in the safety data sheet
bwbodywei ght
CASChemi calAbst ractsSer vi
ce
d - day
EC50Ef fectiveConcent ration50%
ErC50Ef fectiveConcent rationgrowt
hrate50%
h - hour
LC50Let halConcent r
ati
on50%
LD50Let halDose50%
LL50Let halLoadi ng50%
mg/ kgmi lli
gram/ kilogram
mg/ Lmi ll
igram/ li
ter
mg/m3 - milligram/cubic meter
mm - millimeter
mmHg - millimeter mercury
NIOSHNat i
onalI nstitut
ef orOccupationalSaf
etyandHeal
th
NTPNat i
onalTox i
cologyPr ogram
OELOccupat ionalEx posur eLimit
PELPer mi ssibleEx posur eLi mit
ppm par tspermi l
li
on
STELShor tTer m Ex posur eLi mit
TWATi me- Wei ghtedAver age
UNUni tedNat ions
w/w - weight/weight

Key literature references and sources for data

www.ChemADVISOR.com/

Disclaimer Statement
This information is furnished without warranty, expressed or implied, as to accuracy or completeness. The
information is obtained from various sources including the manufacturer and other third party sources. The
information may not be valid under all conditions nor if this material is used in combination with other materials or in
any process. Final determination of suitability of any material is the sole responsibility of the user.

End of Safety Data Sheet

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