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2.1 Pinner, S. H. Chemistry and Technology of the Organic Isocyanates; Plastics (London) 1947, 11, Apr./May, 206211, 215.
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2.2 Cooper, W.; Pearson, R. W.; Darke, S. Isocyanate Reactions and the Structure of Polyurethanes; The Industrial
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2.21 Simons, D. M.; Verbanc, J. J. The Polymerization of Propylene Oxide; J. Polym. Sci. 1960, 44, 303-311.
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Anhydrous Potassium Hydroxide; J. Amer. Chem. Soc. 1964, 86, 4678-4686.
2.23 Fogiel, A. W. Effective Functionality and Intramolecular Reactions of Polyisocyanates and Polyols; Macromol.1969,
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2.24 Livigni, R. A.; Herold, R. J.; Elmer, O. C.; Aggarwal, S. L. Poly (Propylene Ether) Polyols Prepared With a Zinc
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2.25 Stanford, J. L.; Stepto, R. F. T. A Study of Intramolecular Reaction and Geletion during Non-Linear Polyurethane
Formation; Brit. Polym. J. 1977, 6, 124-132.
2.26 Miller, D. R.; Valles, E. M.; Macosko, C. W. Calculation of Molecular Parameters for Stepwise Polyfuncional
Polymerization; Polym. Eng. Sci. 1979, 19/4, 272-283.
2.27 Barksby, N.; Allen, G. L. Low Monol Polyols and Their Effects in Urethane Systems; Proceedings of the
Polyurethane World Congress 1993; Technomic: Lancaster, Pa., 1993, 445-450.
2.28 Carr, R. H.; Hernalsteen, J.; Devos, J. Determination of Functionality and Functionality Distribution of Polyether
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2.29 David, D. J.; Staley, H. B. Analytical Chemistry Of The Polyurethanes, Vol 16, Part III; Wiley-Interscience: New York,
1969, 291-292.
2.30 Patent U.S. 3,271,462, M. H. Earing to Wyandotte Chemical Company, September 6, 1966.
2.31 Patent U.S. 3,278,457, to General Tire Corporation, October 11, 1966.
2.32 Patent U.S. 3,393,243, M. Cuscurida to Jefferson Chemical Corporation, July 16,1968.
2.33 Patent U.S. 3,485,861, R. L. McKellar and M. C. Musolf to Dow Corning Corporation, December 23, 1969.
2.34 Herold, R. J.; Linigim, R. A. Polymerization Kinetics and Technology, Advances in Chemistry Series No. 128;
American Chemical Society: Washington, 1973.
2.35 Bleijenberg, K. C. Novel polyols via new manufacturing routes; Conference Papers, UTECH 88; Crain
Communications: London, 1988; 185-187.
2.36 Schuchardt, J. L.; Harper, S. D. Preparation of High Molecular Weight Polyols Using Double Metal Cyanide
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2.37 Patent U.S. 5,010,187, A. J. Heuvelsland to Dow Chemical Company, April 23, 1991.
2.38 Hinz, W. A New Synthetic Approach to High Molecular Weight Polyetherpolyols; Proceedings of the SPI/ISOPA
Polyurethanes World Congress 1991; Technomic: Lancaster, Pa., 1991, 519-523.
2.39 Penati, A.; Maffezzoni, C.; Moretti, E. Practical and Theoretical Molecular Weights in Polyaddition Reactions of
Ethylene and Propylene Oxide; J. Appl. Polym. Sci. 1981, 26, 1059-1071.
2.40 Baize, T. H. Polymerization of Ethylene Oxide; Ind. Eng. Chem. 1961, 53/11, 903-906.
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1972, 8/2, 90-99.
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2.47 Yost, C. W.; Plank, C. A.; Gerhand, E. R. Oxypropylation Of Glycerol, A Studyof Variables; Ind. Eng. Chem. Prod.
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2.48 Yen, Y. C. Polyols from Ethylene Oxide and Propylene Oxide; Process Economics Program Report No. 45;
Stanford Research Institute: Menlo Park, California, 1968.
2.49 Wright, P.; Cumming, A. P. C. Solid Polyurethane Elastomers; Gordon and Breach: New York, 1969, 66-68.
2.50 Guibert, R. M.; Plank, C. A.; Gerhard, E. R. Kinetics of the Propylene Oxide-Oxypropylated Glycerol Reaction; Ind.
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2.51 Christianson, L. R.; Dheming, M.; Ochoa, E.L. The Economics of a PolyetherPlant; J. Cell Plast. 1977, 13/2, 111117.
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2.53 Sparrow, D. J.; Thorpe, D. Polyols for Polyurethane Production; In Telechelic Polymers, Vol. 2, Synthesis and
Application; Goethals, E. J., Ed., CRC Press: Boca Raton, Florida, 1989, 181-228.
2.54 Barrett, K. E. T. Dispersion Polymerization in Organic Media: John Wiley and Sons: London, 1975.\
2.55 Napper, D. H. Polymeric Stabilization of Colloidal Particles; Academic Press: London, 1983.
2.56 Kuryla, W. C.; Critchfield, F. E.; Platt, L. W.; Stamberger, P. Polymer/ Polyols, a New Class of Polyurethane
Intermediates; J. Cell. Plast.1966, 2/2, 84-96.
2.57 Bamford, C. H.; Tipper, C. F. H. Free Radical Polymerization; Elsevier: New York, 1976.
2.58 Kahrs, K. H.; Zimmermann, J. W. Die Pfropfcopolymerisation von Vinylesternauf Polyalkylenoxyde; Makromol.
Chem.1962, 58, 75-103.
2.59 Critchfield, F. E.; Koleske, J. V.; Priest, D. C. Poly (Styrene co acrylonitrile) polyols. Modulus enhancing polyols for
urethane polymers; Rubber Chem. Tech. 1972, 45, 1467-1484.
2.60 Cloetens, R.; Lidy, W. A.; Phillips, B. D.; Thomas, D. B. Polymer Polyols Properties and Applications; Proceedings
of the SPI/FSK Polyurethanes World Congress; Technomic: Lancaster, Pa., 1987; 480-489.
2.61Ramlow, G. G.; Heyman, D. A.; Grace, O. M. New Graft Polyols for High Load-Bearing Foams; J. Cell Plast. 1983,
19/4, 237-242.
2.62 Shears, J. H.; Dam, C. G.; Vandichel, J. C.; Verstraete, H. POSTECH Polyols: A New Generation of Polymer
Polyols for Enhanced Load Bearing and High Resilience Foams; Proceedings of the 1996 SPI Polyurethanes
Conference; Technomic: Lancaster, Pa., 1996, 150-155.
2.63 Yen, Y. C.; Tsao, T. S. Polyols For Polyurethanes; Process Economics Program Report No. 45A; Stanford
Research Institute: Menlo Park, California, 1982, 119-152.
2.64 Spitler, K. G.; Lindsey, J. J. PHD Polyols, A New Class of PUR Raw Materials; J. Cell Plast. 1981, 17/1, 43-50.
2.65 Vehlewald, P.; Volland, R. PHD Polyethers-Key Products For The Manufacture Of All-Foam Cushioning; Kunstoffe
1983, 73/8, 439-443.
2.66 Koshute, M. A.; Freitag, H. A. Second Generation PHD Polyol for Automotive Flexible Molding; Proceedings of The
SPI/FSK Polyurethanes World Congress; Technomic: Lancaster, Pa., 1987; 502-507.
2.67 Patent U.S. 4,260,530, A. Reischl, H. Muller and K. Wagner to Bayer, April 7, 1981.
2.68 Patent U.S. 4,374,209, J. P. Rowlands to Interchem International S. A., February 15, 1983.
2.69 Pickin, K. PIPA-Process For The Future; Urethanes Tech.1984, June, 23-24.
2.70 Patent U.S., 4,452,923, W. G. Carroll and P. Farley to Imperial Chemical Industries, June 5, 1984.
2.71 Patent U.S. 4,554,306, W. G. Carroll to Imperial Chemical Industries, November 19, 1985.
2.72 Patent U.S. 5,068,280, J. M. Pal, J. P. Cosman and K. Tan to Dow Chemical Company, November 26, 1991.
2.73 Patent U.S. 5,179,131, S. E. Wujcik, D. L. Christman and O. M. Grace to BASF Corporation, January 12, 1993.
2.74 Patent U.S. 5,292,778, K. J. Van Veen and G. R. Blair to Woodbridge Foam Corporation, March 8, 1994.
2.75 Patent U.S. 4,785,026, E. L. Yeakey and M. Cuscurida to Arco Chemical Company, November 15, 1988.
2.76 Knight, J. E. Polyols For Higher Load Bearing Foam; Proceedings of The SPI-27th Annual Technical/Marketing
Conference; Technomic: Lancaster, Pa., 1982; 225-227.
2.77 van der Wal, H. R. Epoxy Dispersion Polyols: A Novel Polymer-Modified Polyol for Improved Loadbearing and
Resiliency; Proceedings of The SPI/FSK Polyurethanes World Congress; Technomic: Lancaster, Pa., 1987; 493-497.
2.78 Patent U.S. 4,326,043, T. Narayan and J. T. Patton to BASF Wyandotte Corporation, April 20, 1982.
2.79 Sam, F. O.; Stefani, D.; Gallo, B. High Performance Flexible Polyurethane Foams with Improved Fire Behavior;
Proceedings of the Polyurethane World Conference 1993; Technomic: Lancaster, Pa., 1995, 62-69.
2.80 Kageoka, M.; Tairaka, Y.; Kodama, K. Effects of Melamine Particle Size on Flexible Polyurethane Foam Properties;
Proceedings of the 1995 SPI Polyurethanes Conference; Technomic: Lancaster, Pa., 1995, 62-69.
2.81 Carey, M. A.; Wellons, S. L.; Elder, D. K. Rapid Method For Measuring The Hydroxyl Content of Polyurethane
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2.82 Turley, P. A.; Pietrantonio, A. Rapid Hydroxyl Number Determination by Near Infrared Reflectance Analysis; J. Cell
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2.83 Standard Test Methods for Testing Polyurethane Raw Materials: Determination of Hydroxyl Numbers of Polyols;
American Society for Testing and Materials, D 4274-88; ASTM Philadelphia, 1990.
2.84 Hanna, J. G.; Siggia, S. Primary and Secondary Hydroxyl Group Content of Polypropylene Glycols; J. Polym. Sci.
1962, 56, 297-304.
2.85 Crummett, W. B. Determination of the Primary Hydroxyl Group Content of Polypropylene Glycols; Anal. Chem.
1962, 34/9, 1147-1150.
2.86 Hendrickson, J. G. The Determination of Primary Alcohol Groups in Polyglycols Using Triphenylchloromethane;
Anal. Chem. 1964, 36/1, 126-128.
2.87 Mathias, A.; Mellor, N. Analysis of Alkylene Oxide Polymers by Nuclear Magnetic Resonance Spectrometry and by
Gas-Liquid Chromatography; Anal. Chem.1966, 38/3. 472-477.
2.88 Manatt, S. L.; Lawson, D. D.; Ingham, J. D.; Rapp, N. S.; Hardy, J. P. A Trifluoroacetylation-Fluorine-19 Nuclear
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2.89 van Leuwen, B. G.; Powell, D. G.; Puig, J. E.; Natoli, F. S. Physical And Chemical Approaches To Ideal Cushioning
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2.90 Groom, T.; Babiec, J. S.; van Leuwen, B. G. End Group Analysis of Polyether Polyols by Nuclear Magnetic
Resonance (NMR) Spectroscopy; J. Cell Plast. 1974, 10/1, 43-46.
2.91 Williams. D. A. R.; Dyke, R.; Malcomson, S.; Massey, S. Analysis of Primary Hydroxyl Content of Polyether Polyols.
A Comparative Study; J. Cell. Plast. 1983, 19/2, 121-124.
2.92 LeBas, C. L.; Turley, P. A. Primary Hydroxyl Content in Polyols Evaluation of Two Nuclear Magnetic Resonance
(NMR) Methods; J. Cell. Plast. 1984, 20/3,194-199.
2.93 Noshiro, M.; Jitsugiri, Y.; Kozawa, S.; Shimada, T. Analysis of EO/PO Polyether Polyols by NMR; In International
Progress In Urethanes, Vol.5; Ashida, K.; Frisch, K.C., Eds.; Technomic: Lancaster, Pa., 1988, 28-44.
2.94 Standard Test Methods for Polyurethane Raw Materials: Determination of Primary Hydroxyl Content of Polyether
Polyols; American Society for Testing and Materials, D 4273-83; ASTM: Philadelpia, 1990.
2.95 Deily, J. R. The Polarographic Determination of Secondary Hydroxyl Groups in Urethane Polyols; J. Cell. Plast.
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2.96 Lowe, A. J.; Chandley, E. F.; Leigh, H. W.; Molinario, L. Some Effects of Molecular Structure on the Production of
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2.97 Williams, J. L.; Stein, N. J. Determination of Cloud Points of Nonionic Surfactants; J. Am. Oil Chem. Soc. 1965, 42,
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2.98 Standard Test Method for Cloud Point of Nonionic Surfactants; American Society for Testing and Materials, D
2024-65; ASTM: Philidelpia, 1992.
2.99 Scholten, H. G.; Schuhmann, J. G.; Ten Hoor, R. E. Urethane Polyether Prepolymers and Foams - Influence of
Chemical and Physical Variables on Reaction Behavior; J. Chem. Eng. Data 1960, 5/3, 395-400.
2.100 Influence Of Catalysts On The Chemistry Of One-Shot Polyether Urethane Foams; The Dow Chemical Company;
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2.101 Ferrigno, T. H. Rigid Plastic Foams; Reinhold: New York, 1963, 27-34.
2.102 Ryall, B.; Griffiths, P. G. Some Developments in One-Shot, Semi-Rigid Polyurethane Foam Moulding; J. Cell.
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2.103 Controlled polymerization is only half of it; Merck and Company, J. Cell. Plast.1970, 6/6, 257.
2.104 Willoughby, B. G. Use of instrumental techniques for troubleshooting, control and development with adhesives,
sealants and binders; Rub. World 1982, 187/3, 26-33.
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2.106 Burchell, D. J.; Porter, J. R. Rheological Analysis of Modulus Growth: A Probe for Determining the Strength of
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2.108 Webb, D. D. Urethane Systems Reactivity Measurement; Proceedings of The SPI-28th Annual
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2.112 Sittig, M. Amines, Nitriles and Isocyanates, Processes and Products, 1969; Noyes Development Corporation: Park
Ridge, New Jersey, 1969.
2.113 Ozaki, S. Recent Advances In Isocyanate Chemistry; Chem. Rev. 1972, 72/5,457-496.
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2.125 Smith, C. H.; Petersen, C. A. Effect of Diisocyanate Structure on Load-Bearing Properties of Flexible Urethane
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2.128 Vargas, J. B.; Loefgren, B. C.; Kato, H. Urethane Foams In Latin America - A Study In Contrasts; Proceedings of
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2.161 Boudreau, R. J. How Silicone Surfactants Affect Polyurethane Foams; Mod. Plast.1967, Jan., 133-147.
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1995 SPI Polyurethanes Conference; Technomic: Lancaster, Pa., 1995, 224-229.
2.163 Snow, S. A.; Fenton, W. N.; Owen, M. J. The addition of Polyoxyethylene/polyoxypropylene block copolymers to
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2.164 Burkhart, G.; Schlons, H.-H.; Zellmer, V. New Silicone Surfactant Technology for Flexible Polyester Polyurethane
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2.165 Burkhart, G.; Klietsch, J.; Zellmer, V. New Surfactant for High Resiliency Moulded Polyurethane Foam Improves
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2.166 Grabowski, W.; Desnier, M.C. L-2100, a New Silicone Surfactant for Use in High Resilience Slabstock Foam;
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2.167 Brune-Fischer, A.; Burkhart, G.; Zellmer, V. New Concepts in Designing Silicone Surfactants for HR-Molded
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