SECTION 1

1.

2.

3.

4.

5.

A.

isothermal

B.

adiabatic

C.

isentropic

D.

none of these

Internal energy change of a system over one complete cycle in a

cyclic process is

7.

8.

9.

second

D.

third

10. For a spontaneous process, free energy

11.

A.

is zero

B.

increases

C.

decreases whereas the entropy increases

D.

and entropy both decrease

A refrigeration cycle is a reversed heat engine. Which of the following

has the maximum value of the co-efficient of performance (COP) for a
given refrigeration effect ?

A.

zero

A.

Vapor compression cycle using expansion valve.

B.

+ve

B.

Air refrigeration cycle.

C.

-ve

C.

Vapor compression cycle using expansion engine.

D.

dependent on the path

D.

Carnot refrigeration cycle.

Heating of water under atmospheric pressure is an __________

process.
A.

isochoric

B.

isobaric

C.

adiabatic

D.

isothermal

Van Laar equation deals with the activity co-efficients in

A.

binary solutions

B.

ternary solutions

C.

azeotropic mixture only

D.

none of these
specific heat

B.

latent heat of vaporisation

C.

viscosity

D.

specific vapor volume

12. In a working refrigerator, the value of COP is always

A.

B.

<0

C.

<1

D.

>1

13. __________ increases with increase in pressure.

High __________ is an undesirable property for a good refrigerant.

A.

6.

C.

Maximum work that could be secured by expanding the gas over a

given pressure range is the __________ work.

A.

The melting point of wax

B.

The boiling point of a liquid

C.

both (a) and (b)

D.

neither (a) nor (b)

14. A refrigerator may be termed as a

Solubility of a substance which dissolves with an increase in volume

and liberation of heat will be favoured by the

A.

heat pump

B.

heat engine

C.

Carnot engine

D.

none of these

A.

low pressure and high temperature.

B.

low pressure and low temperature.

C.

high pressure and low temperature.

A.

decreases

D.

high pressure and high temperature.

B.

increases

C.

remains same

D.

decreases linearly

Entropy is a measure of the __________ of a system.

15. For a stable phase at constant pressure and temperature, the fugacity
of each component in a binary system __________ as its mole
fraction increases.

A.

disorder

B.

orderly behaviour

C.

temperature changes only

A.

Chemical potential

D.

none of these

B.

Surface tension

C.

Heat capacity

D.

None of these

16. Which of the following is not an intensive property ?

A chemical reaction will occur spontaneously at constant pressure

and temperature, if the free energy is
A.

zero

B.

positive

C.

negative

A.

Air cycle

D.

none of these

B.

Carnot cycle

C.

Ordinary vapour compression cycle

D.

Vapour compression with a reversible expansion engine

17. Out of the following refrigration cycles, which one has the minimum
COP (Co-efficient of performance)?

Fundamental principle of refrigeration is based on the __________

law of thermodynamics.
A.

zeroth

B.

first

18. Measurement of thermodynamic property of temperature is facilitated

by __________ law of thermodynamics.

A.

contracts

A.

1st

B.

expands

B.

zeroth

C.

does not change in volume

C.

3rd

D.

either (a), (b) or (c)

D.

none of these

26.
"At the absolute zero temperature, the entropy of every perfectly
crystalline substance becomes zero". This follows from the

19. The theoretical minimum work required to separate one mole of a

liquid mixture at 1 atm, containing 50 mole % each of n- heptane and
n- octane into pure compounds each at 1 atm is
A.

-2 RT ln 0.5

A.

third law of thermodynamics

B.

-RT ln 0.5

B.

second law of thermodynamics

C.

0.5 RT

C.

Nernst heat theorem

D.

2 RT

D.

Maxwell's relations

20. Keeping the pressure constant, to double the volume of a given mass
of an ideal gas at 27C, the temperature should be raised to
__________ C.
A.

270

B.

327

C.

300

D.

540

27.
During Joule-Thomson expansion of gases

21.
Entropy of an ideal gas depends upon its
A.

pressure

B.

temperature

C.

both (a) & (b)

D.

neither (a) nor (b)

A.

temperature

B.

pressure

C.

volume

D.

entropy

23.

temperature

C.

pressure

D.

none of these

entropy remains constant.

C.

temperature remains constant.

D.

none of these.

B.

Clayperon-Claussius equation

C.

Van Laar equation

D.

Nernst Heat Theorem

B.

<1

C.

>1

D.

<3

A.

B.

C.

D.

30.
"Law of corresponding states" says that

If the vapour pressure at two temperatures of a solid phase in

equilibrium with its liquid phase are known, then the latent heat of
fusion can be calculated by the
Maxwell's equation

>2

Degress of freedom at triple point will be

24.

A.

A.

29.

No work is done by the system, when a reaction occurs at constant

B.

B.

The accentric factor of a materical, '', is defined as = -log10(Prsat)Tr1

= 0.7, where, Prsat = reduced vapor pressure, Tr = reduced
temperature. The value of accentric factor is always

Isobaric process means a constant process.

volume

enthalpy remains constant.

28.

22.

A.

A.

A.

two different gases behave similarly, if their reduced

properties (i.e. P, V and T) are same.

B.

the surface of separation (i. e. the meniscus) between

liquid and vapour phase disappears at the critical
temperature.

C.

no gas can be liquified above the critical temperature,

howsoever high the pressure may be.

D.

the molar heat of energy of gas at constant volume should

be nearly constant (about 3 calories).

31.
Linde gas liquefaction process employs cooling

25.
The freezing point of a liquid decreases when the pressure is
increased, if the liquid __________ while freezing.

A.

by throttling

B.

by expansion in an engine

C.

at constant pressure

D.

none of these

37.
Out of the following refrigeration cycles, which one has maximum
COP ?

32.
Pick out the wrong statement pertaining to the decomposition of

A.

Air cycle

PCl5 represented by, PCl5

PCl5 will

B.

Carnot cycle

C.

Ordinary vapor compression cycle

D.

Vapor compression with a reversible expansion engine

PCl3 + Cl2.Degree of dissociation of

A.

decrease on addition of Cl2.

B.

increase on addition of an inert gas at constant pressure.

C.

decrease on increasing the pressure of the system.

D.

none of these

38.
Pick out the correct statement:

A.

In an isothermal system, irreversible work is more than

reversible work.

B.

Under reversible conditions, the adiabatic work is less

than isothermal work.

C.

Heat, work, enthalpy and entropy are all 'state functions'.

D.

Matter and energy can not be exchanged with the

surroundings in a closed system.

33.
Joule-Thomson experiment is
A.

isobaric

B.

adiabatic

C.

isenthalpic

D.

both(b) & (c)

39.
In any spontaneous process,

34.
Boyle's law for gases states that

A.
, when temperature is constant.

A.

only F decreases

B.

only A decreases

C.

both F and A decreases

D.

both F and A increase

40.
B.

C.

Which of the following is a thermodynamic property of a system ?

, when temperature & mass of the gas

remain constant.
P V, at constant temperature & mass of the gas.

D.
= constant, for any gas.

A.

Concentration

B.

Mass

C.

Temperature

D.

Entropy

41.
Equilibrium constant decreases as the temperature

35.
1st law of thermodynamics is nothing but the law of conservation of
A.

momentum

B.

mass

C.

energy

D.

none of these

A.

increases, for an exothermic reaction.

B.

decreases, for an exothermic reaction.

C.

increases, for an endothermic reaction.

D.

none of these.

42.

36.
In a reversible chemical reaction (where, x = number of moles of
products-number of moles of reactants )

A.

addition of inert gas favours the forward reaction, when

x is positive.

B.

pressure has no effect on equilibrium, when n = 0.

C.

addition of inert gas has no effect on the equilibrium

constant at constant volume for any value of x (+ ve, ve) or zero).

D.

all 'a', 'b' & 'c'.

The expression,
change

, gives the free energy

A.

with pressure changes at constant temperature.

B.

under reversible isothermal volume change.

C.

during heating of an ideal gas.

D.

during cooling of an ideal gas.

43.
All gases during throttling process at atmospheric temperature and

C.

pressure show a cooling effect except

freon

D.

brine

49.

A.

CO2

B.

H2

C.

O2

D.

N2

Water on heating from 1 to 4C

44.
Compressibility factor for almost all the gases are approximately
same at the same
A.

pressure and temperature.

B.

reduced pressure and reduced temperature.

C.

critical pressure and critical temperature.

D.

none of these.

45.

A.

contracts

B.

expands

C.

has same volume

D.

may contract or expand

50.
Pick out the correct statement.

A.

Compression ratio of an Otto engine is comparatively

higher than a diesel engine.

B.

Efficiency of an Otto engine is higher than that of a

diesel engine for the same compression ratio.

Pick out the wrong statement.

A.

Activity co-efficient is dimensionless.

B.

In case of an ideal gas, the fagacity is equal to its

pressure.

C.

Otto engine efficiency decreases with the rise in

compression ratio, due to decrease in work produced per
quantity of heat.

C.

In a mixture of ideal gases, the fugacity of a component is

equal to the partial pressure of the component.

D.

Diesel engine normally operates at lower compression

ratio than an Otto engine for an equal output of work.

D.

The fugacity co-efficient is zero for an ideal gas.

46.
The co-efficient of performance (COP) of a refrigerating system,
which is its index of performance, is defined as the ratio of useful
refrigeration to the net work. The units of __________ and COP are
the same.
A.

kinematic viscosity

B.

work

C.

temperature

D.

none of these

47.
The chemical potential of a component (i) of a phase is the amount
by which its capacity for doing all work, barring work of expansion is
increased per unit amount of sustance added for an infinitesimal
addition at constant temperature and pressure. It is given by

A.

B.

C.

D.

all (a), (b) and (c)

48.
In jet refrigerators, the refrigerating fluid is practically always
A.

water

B.

ammonia

SECTION 2

D
none of these
.
8. At __________ point, all the three phases (i.e.solid, liquid and gas) coexist.
A.eutcetic
B.triple
C
plait
D.critical
.
9. Kopp's rule is used to calculate the heat capacity of
A
solids
.
B.liquids
C
gases
.
D
all (a), (b) & (c)
.

Section 3
1. Trouton's ratio of __________ liquids is calculated using Kistyakowsky
equation.
A.polar
B
non-polar
.
C
both (a) & (b)
.
D
neither (a) nor (b)
.
2. Activity co-efficient is a measure of the
A
departure from ideal solution behaviour.
.
B.departure of gas phase from idea] gas law.
C
vapour pressure of liquid.
.
D
none of these.
.
3. While dissolving a gas into a liquid at a constant temperature, the ratio of
the concentration of the gas in the solution phase and in the gaseous
phase is
A.infinity
B.unity
C
D
constant
negative
.
.
4. Which of the following units is not present in both the vapor compression
refrigeration system and absorption refrigeration system ?
A.Expansion valve
B.Condenser
C
Refrigerator
.
D
Compressor
.
5. For an isothermal reversible compression of an ideal gas
A.only E = 0
B.only H =0
C
E = H = 0
.
D
dQ = dE
.
6. Melting of ice exemplifies a/an
A.adiabatic process.
B
endothermic reaction.
.
C
exothermic reaction.
.
D
process involving a chemical reaction.
.
7. A refrigeration cycle is the same as a __________ cycle,
A.turbine
B.heat engine
C
reversed heat engine
.

10. __________ explains the equilibrium constant for any chemical

reaction.
A.Henry's law
B
Law of mass action
.
C
Hess's law
.
D
none of these
.
11. Which of the following is not a reversible process ?
A.Expansion of an ideal gas against constant pressure.
B.Atmospheric pressure vaporisation of water at 100C.
C
Solution of NaCl in water at 50C.
.
D
None of these.
.
12. Pick out the wrong statement.
A closed system does not permit exchange of mass with its
A.
surroundings but may permit exchange of energy.
An open system permits exchange of both mass and energy with its
B.
surroundings.
The term microstate is used to characterise an individual, whereas
C
macro-state is used to designate a group of micro-states with
.
common characteristics.
D
none of the above.
.
13. Which of the following exemplifies an adiabatic process ?
A.Melting of ice.
B.Condensation of alcohol vapor.
C
Sudden bursting of a cycle tube.
.
D
Evaporation of water.
.

14. Entropy, which is a measure of the disorder of a system is

A.independent of pressure.
B.independent of temperature.
C zero at absolute zero temperature for a perfect crystalline
. substance.
D
all (a), (b) & (c)
.
15. Critical temperature is defined as the temperature above which a gas
will
A.not liquify (barring exceptions).
B.immediately liquify.
C
never liquify however high the pressure may be.
.
D
none of these.
.
16. The standard Gibbs free energy change of a reaction depends on the
equilibrium
A.pressure
B
temperature
.
C
composition
.
D all (a), (b) and (c)

.
17. Gibbs-Duhem equation relates composition in liquid phase and the
__________ at constant temperature & pressure.
A.fugacity
B.partial pressure
C
activity co-efficient
.
D
(a), (b), and
.
18. In an ideal solution, the activity of a component equals its
A
mole fraction.
.
B.fugacity at the same temperature and pressure.
C
partial pressure.
.
D
none of these.
.
19. A gas has a volume of 27.3 c.c. at 0C. Its volume at 10C (if pressure
remains unchanged) will be __________ c.c.
A.2.73
B.28.3
C
273
D.283
.
20. Clayperon equation deals with the
A
rate of change of vapour pressure with temperature.
.
B.effect of an inert gas on vapour pressure.
C
calculation of F for spontaneous phase change.
.
D
temperature dependence of heat of phase transition.
.
21. Gibbs free energy (G) is represented by, G = H - TS, whereas
Helmholtz free energy, (A) is given by, A = E - TS. Which of the
following is the Gibbs-Helmholtz equation
A.
B.
C
both (a) and (b)
.
D
neither (a) nor (b)
.
22. Which of the following is an undesirable characteristics of a
refrigerant ?
A.It should be non-explosive.
B It should have a sub-atmospheric vapor pressure at the
. temperature in refrigerator coils.
C
Its vapor pressure at the condenser temperature should be very high.
.
D
None of these.
.
23. "The rate at which a substance reacts is proportional to its active mass
and the rate of a chemical reaction is proportional to the product of
active masses of the reacting substances". This is the
A.Lewis-Randall rule.
B.statement of Vant-Hoff equation.
C
Le-Chatelier's principle.
.
D
none of these.
.
24. What is the ratio of adiabatic compressibility to isothermal
compressibility ?
A.1
B
<1
.
C
>1
.
D
>> 1
.
25. The absolute entropy for all crystalline substances at absolute zero
temperature is
A zero

.
B.negative
C
more than zero
.
D
indeterminate
.
26. Pick out the wrong statement.
A.Phase rule variables are intensive properties.
B
Heat and work are both state function.
.
C
The work done by expansion of a gas in vacuum is zero.
.
D
C and CV are state function.
. P
27. Compressibility factor of a gas is
A
not a function of its pressure.
.
B.not a function of its nature.
C
not a function of its temperature.
.
D
unity, if it follows PV = nRT.
.
28. Which of the following is not an extensive property ?
A.Free energy
B.Entropy
C
Refractive index
.
D
None of these
.
29. Forward reaction will be favoured for the exothermic reaction,
represented by CO + H2O
CO2 + H2, by
A
low temperature and high pressure.
.
B.low temperature and low pressure.
C
high temperature and high pressure.
.
D
high temperature and low pressure.
.
30. Enthalpy of a gas depends upon its
A
temperature
B.mass
.
C
volume
D.pressure
.
31. When dilute aqueous solutions of two salts are mixed, the process is
associated with
A.decrease in temperature.
B
increase in temperature.
.
C
no change in temperature.
.
D
change in temperature which is a function of composition.
.
32. Pick out the correct statement.
Like internal energy and enthalphy, the absolute value of standard
A.
entropy for elementary substances is zero.
Melting of ice involves increase in enthalpy and a decrease in
B.
randomness.
C
The internal energy of an ideal gas depends only on its pressure.
.
D
Maximum work is done under reversible conditions.
.
33. Chemical engineering thermodynamics is concerned with the
__________ in/of chemical processes.
A.reaction mechanism
B.calculation of rates
C
energy transformation from one form to the another
.
D
none of these
.
34. An isolated system can exchange __________ with its surroundings.
A.matter

B.energy
C
neither matter nor energy
.
D
both matter and energy
.
35. Requisites of a reversible process is that the
A.system and surroundings pressure be equal.
B
friction in the system should be absent.
.
C
system and surroundings temperature be equal.
.
D
none of these.
.
36. Fugacity is most helpful in
A
representing actual behaviour of real gases.
.
B.representing actual behaviour of ideal gases.
C the study of chemical equilibria involving gases at atmospheric
. pressure.
D
none of these
.
37. The energy of activation of exothermic reaction is
A.zero.
B.negative.
C
very large compared to that for en-dothermic reaction.
.
D
not possible to predict.
.
38. Pick out the wrong statement.
The chemical potential of a pure substance depends upon the
A.
temperature and pressure.
The chemical potential of a component in a system is directly
B.
proportional to the escaping tendency of that component.
The chemical potential of ith species (i) in an ideal gas mixture
C
approaches zero as the pressure or mole fraction (xi) tends to
.
be zero at constant temperature.
The chemical potential of species 'i' in the mixture (i) is
D
. mathematically represented as,
, where, n, ni and
nj respectively denote the total number of moles, moles of ith species
and all mole numbers except ith species. 'G' is Gibbs molar free
energy.
39.
In the reaction; N2 + O2
2NO, increasing the pressure will result
in
A.shifting the equilibrium towards right,
B.shifting the equilibrium towards left.
C
no change in equilibrium condition.
.
D
none of these.
.
40. A cyclic engine exchanges heat with two reservoirs maintained at 100
and 300C respectively. The maximum work (in J) that can be obtained
from 1000 J of heat extracted from the hot reservoir is
A
349
B.651
.
C
667
D.1000
.
41. Pick out the wrong statement.
Trouton's ratio of non-polar liquids is calculated using Kistyakowasky
A.
equation.
B.Thermal efficiency of a Carnot engine is always less than 1.
C An equation relating pressure, volume and temperature of a gas
. is called ideal gas equation.
D
none of these.
.
43. When a gas is subjected to adiabatic expansion, it gets cooled due to
A.decrease in velocity.
B.decrease in temperature.
C
decrease in kinetic energy.
.

D
energy spent in doing work.
.
44. Joule-Thomson effect i.e., a throttling process is a constant
__________ process.
A.entropy
B.temperature
C
internal energy
.
D
enthalpy
.
45. In the equation, PVn = Constant, if the value of n = 0, then it represents
a reversible __________ process.
A
isobaric
B.isothermal
.
C
isentropic
D.isometric
.
46. Work done in an adiabatic process between two states depends on the
A.rate of heat transmission
B.initial state only
C
end states only
.
D
none of these
.
47. The number of degree of freedom for an azeotropic mixture of ethanol
and water in vapour-liquid equilibrium, is
A.3
B.1
C
2
D.0
.
48. The internal energy of an ideal gas is a function of its __________ only.
A.molecular size
B.volume
C
pressure
.
D
temperature
.
49. At constant temperature and pressure, for one mole of a pure
substance, the ratio of the free energy to the chemical potential is
A.zero
B.one
C
infinity
D.negative
.
50. The change in __________ is equal to the reversible work for
compression in steady state flow process under isothermal condition.
A.internal energy
B.enthalpy
C
Gibbs free energy
.
D
Helmholtz free energy
.
Section 4
1. Work done is a
A.property of the system
B.path function
C
point function
.
D
state description of a system
.
2. Entropy of the system decreases, when
A.snow melts into water.
B.a gas expands spontaneously from high pressure to low pressure.
C
water is converted into ice.
.
D
both (b) & (c).
.
3. Extensive properties of a thermodynamic system depend upon the
__________ of the system.
A.specific volume
B.temperature
C
mass
.
D
pressure
.

4. The equation Tds = dE - PdV applies to

A.single phase fluid of varying composition.
B.single phase fluid of constant composition.
C
open as well as closed systems.
.
D
both (b) and (c)
.
5. If an ideal solution is formed by mixing two pure liquids in any proportion,
then the __________ of mixing is zero.
A.enthalpy
B.volume
C
both 'a' & 'b'
.
D
neither 'a' nor 'b'
.
6. Near their critical temperatures, all gases occupy volumes __________
that of the ideal gas.
A
less than
.
B.same as
C
more than
.
D
half
.
7. The free energy change for a chemical reaction is given by (where, K =
equilibrium constant)
A.RT lnK
B
-RT lnK
.
C
-R lnK
.
D
T lnK
.
8. Free energy, fugacity and activity co-efficient are all affected by change
in the temperature. The fugacity co-efficient of a gas at constant
pressure ____with the increase of reduced temperature.
A.decreases
B
increases
.
C
remains constant
.
D
decreases logarithmically
.
9.
In the reaction, H2 +I2
2HI, addition of an inert gas will
A.increase the partial pressure of H2.
B.increase the partial pressure of I2.
C increase the total pressure and hence shift the equilibrium towards the
. right.
D
not effect the equilibrium conditions
.
10. What is the number of degrees of freedom for liquid water in equilibrium
with a mixture of nitrogen and water vapor ?
A
2
B.0
.
C
3
D.1
.
11. The temperature at which a real gas obeys the ideal gas laws over a
wide range of pressure is called the __________ temperature.
A.critical
B.Boyle
C
inversion
D.reduced
.
12. If the molar heat capacities (Cp or Cv) of the reactants and products of a
chemical reaction are identical, then, with the increase in temperature,
the heat of reaction will
A.increase
B.decrease
C
remain unaltered
.
D
increase or decrease ; depends on the particular reaction
.

13. All gases above its inversion temperature, in a throttling process will
show
A
a heating effect.
.
B.no change in temperature.
C
a cooling effect.
.
D
either (a) or (c).
.
14. First law of thermodynamics is mathematically stated as
A
dQ = dE + dW
.
B.dQ = dE - dW
C
dE = dQ + dW
.
D
dW = dQ + dE
.
15. Pick out the wrong statement.
Surface tension of a substance vanishes at critical point, as there is
A.
no distinction between liquid and vapour phases at its critical point.
B.Entropy of a system decreases with the evolution of heat.
C
Change of internal energy is negative for exothermic reactions.
.
D
The accentric factor for all materials is always more than one.
.
16. Translational kinetic energy of molecules of an ideal gas is proportional
to (where, T = absolute temperature of the gas )

17. Equation which relates pressure, volume and temperature of a gas

is called the
A
equation of state
.
B.Gibbs Duhem equation
C
ideal gas equation
.
D
none of these
.
18. Claussius-Clayperon equation gives accurate result, when the
vapour pressure is relatively low and the temperature does not vary
A.
over wide limits.
vapour obeys the ideal gas law and the latent heat of vaporisation is
B.
constant.
C volume in the liquid state is negligible compared with that in the
. vapour state.
D
all (a), (b) and (c).
.
19. The temperature at which a real gas obeys the ideal gas laws over a
wide range of pressure is called __________ temperature.
A
Boyle
B.inversion
.
C
critical
D.reduced
.
20. The expression for entropy change, S = n Cp . ln (T2/T1), is valid for
the __________ of a substance.
A.simultaneous pressure & temperature change
B.heating
C
cooling
.
D
both (b) and (c)
.
21. For a single component two phase mixture, the number of independent
variable properties are
A.two
B.one
C
zero
D.three
.

22. __________ law of thermodynamics ascertains the direction of a

particular spontaneous process.
A.Zeroth
B.First
C
Second
D.Third
.

.
D
enthalpy remains constant.
.

23. At normal boiling point, molar entropy of vaporisation is __________

Joule/K.mole.
A.72
B.92
C
142
D.192
.

32. A nozzle is a device, which

A
increases kinetic energy and decreases pressure.
.
B.reduces kinetic energy and increases pressure.
C
reduces both kinetic energy and pressure.
.
D
increases both kinetic energy and pressure.
.

24. For an ideal solution, the value of activity co-efficient is

A.0
B
1
.
C
<1
.
D
>1
.

33. Duringthe phase transition, __________ changes.

A.pressure
B
volume
.
C
temperature
.
D
all (a), (b) and (c)
.

25. The expression, nCv(T2 - T1), is for the __________ of an ideal gas.
A
work done under adiabatic condition
.
B.co-efficient of thermal expansion
C
compressibility
.
D
none of these
.

34. The work done in an adiabatic change in a particular gas depends upon
changes in the __________ only.
A
temperature
.
B.specific heat
C
volume
.
D
pressure
.

26. The number of degrees of freedom at the triple point of water is

A
0
B.1
.
C
2
D.3
.
27. Which of the following is a widely used refrigerant in vapour
compression refrigeration system (using large centrifugal compressor)?
A
Freon
.
B.Liquid sulphur dioxide
C
Methyl chloride
.
D
Ammonia
.
28. Internal energy is equal to the heat absorbed in case of a/an
__________ process.
A
constant volume
.
B.polytropic
C
adiabatic
.
D
constant pressure
.
29. The first law of thermodynamics is a restatement of the law of
conservation of
A.mass
B
energy
.
C
momentum
.
D
none of these
.
30. Joule-Thomson co-efficient for a perfect gas is
A
zero
.
B.positive
C
negative
.
D
none of these
.
31. In an adiabatic process, the
A
heat transfer is zero.
.
B.temperature change is zero.
C work done is a path function.

35. The value of gas constant 'R' is

A.1.987 cal/gm mole K
B.1.987 BTU/lb. mole R
C
both (a) and (b)
.
D
neither (a) nor (b)
.
36. In an isothermal process on an ideal gas, the pressure increases by 0.5
percent. The volume decreases by about __________ percent.
A.0.25
B.0.5
C
0.75
D.1
.
37. Which of the following is not a unit of the equilibrium constant Kp?
(where, x = number of moles of products number of moles of
reactants)
A.(atm)x, when x is negative
B.(atm)x, when x is positive
C
Dimensionless, when x = 0
.
D
(atm)x2, when x > 0
.
38. Pick out the correct statement.
The available energy in an isolated system for all irreversible (real)
A.
processes decreases.
The efficiency of a Carnot engine increases, if the sink temperature is
B.
decreased.
C The reversible work for compression in non-flow process under
. isothermal condition is the change in Helmholtz free energy.
D
all (a), (b) and (c)
.
39. Partial molal quantities are important in the study of
A.ideal gases
B.ideal solutions
C
non-ideal mixtures
.
D
a pure component
.
40. Number of degrees of freedom for a three phase system in equilibrium
comprising of three non-reacting chemical species is
A
2
B.0
.
C
1
D.3
.

41. Critical solution temperature (or the con-solute temperature) for partially
miscible liquids (e.g., phenol-water) is the minimum temperature at
which
A
a homogeneous solution (say of phenol water) is formed.
.
B.mutual solubility of the two liquids shows a decreasing trend.
C
two liquids are completely separated into two layers.
.
D
none of these.
.
42.

Which is not constant for an ideal gas ?

B.by throttling.
C
by expansion in an engine.
.
D
none of these.
.
SECTION 5
1. The heat capacities for the ideal gas state depend upon the
A.pressure
B
temperature
.
C
both (a) & (b)
.
D
neither (a) nor (b)
.
2. Which of the following will increase the volume of a real gas by four
times ?
A.Doubling the absolute temperature as well as pressure of the gas.
B
Reducing pressure to one fourth at constant temperature.
.
C
Reducing temperature to one fourth at constant pressure.
.
D
Reducing the temperature to half and doubling the pressure.
.

43. Enthalpy 'H' is defined as

A.H = E - PV
B.H = F - TS
C
H - E = PV
.
D
none of these
.
44. One ton of refrigeration is defined as the heat rate corresponding to
melting of one ton of ice in one
A.hour
B.day
C
minute
D.second
.
45. __________ functions are exemplified by heat and work.
A
Path
.
B.Point
C
State
.
D
none of these
.
46. In an irreversible process
A.Tds = dE - dW = 0
B.dE - dW - Tds = 0
C
Tds - dE + dW< 0
.
D
Tds - dT + dW< 0
.
47. What is the number of degree of freedom for a system of two miscible
non-reacting species in vapor-liquid equilibrium forming an azeotrope ?
A.3
B.2
C
1
D.0
.
48. The entropy change in a reversible isothermal process, when an ideal
gas expands to four times its initial volume is
A
R loge 4
.
B.R log10 4
C
C log10 4
. v
D
C loge 4
. v
49. PV = Constant (where, = Cp/Cv) is valid for a/an __________
process.
A.isothermal
B.isentropic
C
isobaric
D.adiabatic
.
50. Claude gas liquefaction process employs cooling
A.at constant pressure.

3. Pick out the wrong statement.

A
A refriferation cycle violates the second law of thermadynamics.
.
Refrigeration cycle is normally represented by a temperature vs.
B.
entropy plot.
C In a refrigerator, work required decreases as the temperature of the
. refrigerator and the temperature at which heat is rejected increases.
D One ton of refrigeration is equivalent to the rate of heat absorption
. equal to 3.53 kW.
4. The equation, PV = nRT, is best obeyed by gases at
A
low pressure & high temperature.
.
B.high pressure & low temperature.
C
low pressure & low temperature.
.
D
none of these.
.
5. Internal energy of an element at 1 atm and 25 C is __________
kcal/kg.mole.
A
0
.
B.273
C
25
.
D
none of these
.
6. Which of the following liquid metals has the highest thermal
conductivity ?
A
Molten sodium
.
B.Molten lead
C
Mercury
.
D
Molten potassium
.
7. Which of the following has the least thermal efficiency ?
A
Steam engine
.
B.Carnot engine
C
Diesel engine
.
D
Otto engine
.
8. If the internal energy of an ideal gas decreases by the same amount as
the work done by the system, then the
A.process must be isobaric.
B.temperature must decrease.
C
process must be adiabatic.
.
D both (b) and (c).

.
9. Joule-Thomson Co-efficient at any point on the inversion curve is
A.
B.+ ve
C
0
.
D
-ve
.
10. Pick out the wrong statement.

.
D
infinity
.
17. The ratio of equilibrium constants (Kp2/Kp1) at two different
temperatures is given by
A.

B
.

A.
The values of
are zero for a real gas
at its critical point.
Heat transferred is equal to the change in the enthalpy of the system,
B.
for a constant pressure, non-flow, mechanically reversible process.
Thermal efficiency of a Carnot engine depends upon the
C
properties of the working fluid besides the source & sink
.
temperatures.
D During a reversible adiabatic process, the entropy of a substance
. remains constant.
11. Number of components (C), phase (P) and degrees of freedom (F) are
related by Gibbs phase rule as
A
P+F-C=2
.
B.C = P - F + 2
C
F=C-P-2
.
D
P=F-C-2
.
12. The value of Cp & Cv respectively for monoatomic gases in Kcal/kg
Mole . K are
A
5&3
.
B.3.987 & 1.987
C
1.987 & 0.66
.
D
0.66 & 1.987
.
13.

is the mathematical expression for

A.specific heat at constant pressure (Cp).
B.specific heat at constant volume (Cv).
C
Joule-Thompson co-efficient.
.
D
none of these.
.
14. In case of a close thermodynamic system, there is __________ across
the boundaries.
A.no heat and mass transfer
B
no mass transfer but heat transfer
.
C
mass and energy transfer
.
D
none of these
.
15. During a reversible isothermal expansion of an ideal gas, the entropy
change is
A
+ve
B.0
.
C
-ve
D.
.
16. As the temperature is lowered towards the absolute zero, the value of

, then approaches
A.unity
B
zero
.
C that of the heat of reaction

C
.
D
.
18. Which of the following is not affected by temperature changes ?
A.Fugacity
B.Activity co-efficient
C
Free energy
.
D
None of these
.
19. For an ideal gas, the activity co-efficient is
A.directly proportional to pressure.
B.inversely proportional to pressure.
C
unity at all pressures.
.
D
none of these.
.
20. Those solutions in which there is no volume change upon mixing the
components in the liquid state and which, when diluted do not undergo
any heat change (i.e. heat of dilution is zero), are called __________
solutions.
A
ideal
.
B.real
C
isotonic
.
D
none of these
.
21. Generation of heat by friction is an example of a/an __________
change.
A.isothermal
B.irreversible
C
adiabatic
D.reversible
.
22. A domestic refrigerator has a/an __________ cooled condenser.
A.water
B.air
C
evaporative
D.gas
.
23. The extensive properties are
A.volume, mass and number of moles.
B.free energy, entropy and enthalpy.
C
both (a) and (b).
.
D
none of these.
.
24. The compressibility factor of a gas is given by (where, V1 = actual
volume of the gas V2 = gas volume predicted by ideal gas law )
A
V /V
B.V2/V1
. 1 2
C
V -V
D.V1.V2
. 1 2
25. If we increase the pressure on a substance (which is at its triple point),
then the triple point
A.increases
B.decreases

C
remains unchanged
.
D
may increase or decrease ; depends on the substance
.
26. In an ideal refrigeration cycle, the change in internal energy of the fluid
is
A.+ve
B.-ve
C
0
.
D
either of the above three ; depends on the nature of refrigerant.
.
27. Free energy
A.decreases in all spontaneous (or irreversible) processes.
B.change during a spontaneous process has a negative value.
C remains unchanged in reversible processes carried at constant
. temperature and pressure.
D
all (a), (b) and (c).
.
28. "If different processes are used to bring about the same chemical
reaction, the enthalpy change is same for all of them". This is
__________ law.
A
Hess's
.
B.Kirchoff's
C
Lavoisier and Laplace
.
D
none of these
.
29. Fugacity is a measure of the
A escaping tendencies of the same substance in different phases
. of a system.
B.relative volatility of a mixture of two miscible liquids.
C
behaviour of ideal gases.
.
D
none of these.
.
30. The quantitative effect of temperature on chemical equilibrium is given
by the
A
Vant-Hoff equation.
.
B.Le-Chatelier's principle.
C
Arhenius equation.
.
D
none of these.
.
31. For an irreversible process involving only pressure-volume work
A
(dF)T, p <0
.
B.(dF)T, p = 0
C
(dF)T, p > 0
.
D
(dA)T, v >0
.
32. Ideal refrigeration cycle is
A.same as Carnot cycle.
B
same as reverse Carnot cycle.
.
C
dependent on the refrigerant's properties.
.
D
the least efficient of all refrigeration processes.
.
33. The following heat engine produces power of 100000 kW. The heat
engine operates between 800 K and 300 K. It has a thermal efficiency
equal to 50% of that of the Carnot engine for the same temperature.
The rate at which heat is absorbed from the hot reservoir is
A.100, 000 kW
B.160, 000 kW
C
200, 000 kW
.
D
320, 000 kW
.

34. Refrigeration cycle

A.violates second law of thermodynamics.
B involves transfer of heat from low temperature to high
. temperature.
C
both (a) and (b).
.
D
neither (a) nor (b).
.
35. The enthalpy change when ammonia gas is dissolved in water is called
the heat of
A
solution
B.formation
.
C
dilution
D.combustion
.
36. The value of Joule-Thomson co-efficient, in case where cooling occurs
after the throttling process is
A.0
B.
C
+ve
D.-ve
.
37. Adiabatic compression of a saturated water vapour makes it
A.supersaturated
B
superheated
.
C
both (a) and (b)
.
D
neither (a) nor (b)
.
38. The specific heat of saturated water vapour at 100C is
A.
B.-ve
C
0
D.+ve
.
39. For a multicomponent system, the term chemical potential is equivalent
to the
A.molal concentration difference.
B.molar free energy.
C
partial molar free energy.
.
D
molar free energy change.
.
40. The change in Gibbs freee energy for vaporisation of a pure substance
is
A.positive
B.negative
C
zero
.
D
may be positive or negative
.
41. Critical compressibility factor for all substances
A
are more or less constant (vary from 0.2 to 0.3).
.
B.vary as square of the absolute temperature.
C
vary as square of the absolute pressure.
.
D
none of these.
.
42. What is the degree of freedom for two mis-cible (non-reacting)
substances in vapor-liquid equilibrium forming an azeotrope ?
A.0
B.1
C
2
D.3
.
43. For a given substance at a specified temperature, activity is
__________ to fugacity.
A
directly proportional
.
B.inversely proportional
C
equal
.
D
none of these
.
44. In case of vapour compression refrigeration system, elevating the

evaporator temperature (keeping the condenser temperature constant)

results in
A
enhanced COP.
.
B.decreased COP.
C
no change in the value of COP.
.
D increased or decreased COP ; depending upon the type of
. refrigerant.
45. For water at 300C, it has a vapour pressure 8592.7 kPa and fugacity
6738.9 kPa Under these conditions, one mole of water in liquid phase
has a volume of 25.28 cm3 and that in vapour phase in 391.1
cm3.Fugacity of water (in kPa) at 9000 kPa will be
A.6738.9
B.6753.5
C
7058.3
D.9000
.
46. __________ equation predicts the activity co-efficient from
experimental data.
A.Lewis-Randall
B.Margules
C
Van Laar
.
D
both(b)&(c)
.
47. As the temperature is lowered towards the absolute zero, the value of

the quantity
A
zero
.
B.unity
C
infinity
.
D
none of these
.

approaches

48. An ideal liquid refrigerant should

not have a subatmospheric vapour pressure at the temperature in the
A.
refrigerator coils.
B.not have unduly high vapour pressure at the condenser temperature.
C
both (a) and (b).
.
D
have low specific heat.
.
49. If the heat of solution of an ideal gas in a liquid is negative, then its
solubility at a given partial pressure varies with the temperature as
A.solubility increases as temperature increases.
B
solubility increases as temperature decreases.
.
C
solubility is independent of temperature.
.
D solubility increases or decreases with temperature depending on the
. Gibbs free energy change of solution.
50. In case of a reversible process (following pvn = constant), work
obtained for trebling the volume (v1 = 1 m3 and v2 3 m3 ) is max imum,
when the value of 'n' is
A
0
.
B.1
C
y = 1.44
.
D
1.66
.
SECTION 6
1. The Carnot co-efficient of performance (COP) of a domestic air
conditioner compared to a household refrigerator is
A
less
.
B.more
C
same
.
D
dependent on climatic conditions
.

2. The unit of fugacity is the same as that of the

A
pressure
.
B.temperature
C
volume
.
D
molar concentration
.
3. Filling of gas from a high pressure cylinder into small bottles is an
example of a/an __________ process.
A.equilibrium
B.adiabatic
C
steady
D.unsteady
.
4. A large iceberg melts at the base, but not at the top, because of the
reason that
A.ice at the base contains impurities which lowers its melting point.
B
due to the high pressure at the base, its melting point reduces.
.
C
the iceberg remains in a warmer condition at the base.
.
D
all (a), (b) and (c).
.
5. At the critical point of a substance
A.the surface tension vanishes.
B.liquid and vapour have the same density.
C
there is no distinction between liquid and vapour phases.
.
D
all (a), (b) and (c).
.
6. A system undergoes a change from a given initial state to a given final
state either by an irreversible process or by a reversible process,
then(where, S1 and SR are the entropy changes of the system for the
irreversible and reversible processes respectively)
A. S1 is always < SR
B. S1 is sometimes > SR
C
S1 is always > SR
.
D
S1 is always = SR
.
7. What is the value of Joule-Thomson co-efficient for an ideal gas ?
A.+ve
B.-ve
C
0
D.
.
8. A two stage compressor is used to compress an ideal gas. The gas is
cooled to the initial temperature after each stage. The intermediate
pressure for the minimum total work requirement should be equal to the
__________ mean of P1 and P2.(where, P1 and P2 are initial and final
pressures respectively)
A.logarithmic
B.arithmetic
C
geometric
D.harmonic
.
9. y = specific heat ratio of an ideal gas is equal to
A.Cp/Cv
B.Cp/(CP-R)
C
1 + (R/CV)
.
D
all (a), (b) and (c)
.
10. Consider the process A & B shown in the figure given below

upper consolute temperature.

Systems, in which the mutual solubility increases with decrease in
B.
temperature, are said to possess lower consolute temperature.
Nicotine-water system shows both an upper as well as a lower
C
consolute temperature, implying that they are partially miscible
.
between these two limiting temperatures.
D
none of these
.

In this case, it is possilbe that

A.both the processes are adiabatic.
B.both the processes are isothermal.
C
process A is isothermal while B is adiabatic.
.
D
process A is adiabatic while B is isothermal.
.
11. Gibbs free energy of a pure fluid approaches __________ as the
pressure tends to zero at constant temperature.
A.infinity
B
minus infinity
.
C
zero
.
D
none of these
.
12. As the entropy of the universe is increasing, day by day, the work
producing capacity of a heat engine is
A.not changed
B
decreasing
.
C
increasing
.
D
data sufficient, can't be predicted
.
13. An irreversible process
A.is the analog of linear frictionless motion in machines.
B.is an idealised visualisation of behaviour of a system.
C
yields the maximum amount of work.
.
D
yields an amount of work less than that of a reversible process.
.
14. The expression for the work done for a reversible polytropic process
can be used to obtain the expression for work done for all processes,
except reversible __________ process.
A.isobaric
B
isothermal
.
C
adiabatic
.
D
none of these
.
15. Joule-Thomson co-efficient depends on the
A.pressure.
B.temperature.
C
both (a) & (b).
.
D
neither (a) nor (b).
.
16. Free energy change of mixing two liquid substances is a function of the
A.concentration of the constituents only.
B.quantities of the constituents only.
C
temperature only.
.
D
all (a), (b) and (c).
.
17. Pick out the wrong statement.
A.System (of partially miscible liquid pairs), in which the mutual
solubility increases with rise in temperature, are said to possess an

18. The total change in the enthalpy of a system is independent of the

A
number of intermediate chemical reactions involved.
.
B.pressure and temperature.
C state of combination and aggregation in the beginning and at the end
. of the reaction.
D
none of these.
.
19. Number of phases in a colloidal system are
A.1
B.2
C
3
D.4
.
20. Free energy changes for two reaction mechanism 'X' and 'Y are
respectively - 15 and - 5 units. It implies that X is
A.slower than Y
B
faster than Y
.
C
three times slower than Y
.
D
three times faster than Y
.
21. Vapour which is at a pressure smaller than the saturation pressure for
the temperature involved is called a __________ vapour.
A
superheated
.
B.desuperheated
C
non-condensable
.
D
none of these
.
22. At equilibrium condition, the chemical potential of a material in different
phases in contact with each other is equal. The chemical potential for a
real gas () is given by(where, = standard chemical potential at unit
fugacity (f = 1 atm.) and the gas behaves ideally.)
A
+ RT ln f
.
B.+ R lnf
C
+ T lnf
.
D
+ R/T lnf
.
23. The kinetic energy of gas molecule is zero at
A.0C
B.273C
C
100C
D.-273C
.
24. Which of the following is not an intensive property ?
A
Volume
B.Density
.
C
Temperature
D.Pressure
.
25. The necessary and sufficient condition for equilibrium between two
phases is
the concentration of each component should be same in the two
A.
phases.
B.the temperature of each phase should be same.
C
the pressure should be same in the two phases.
.
D the chemical potential of each component should be same in the
. two phases.
26. Specific volume of an ideal gas is
A.equal to its density.
B
the reciprocal of its density.
.
C proportional to pressure.

.
D
none of these.
.

A.Bucket
B.Throttling
C
Separating
.
D
A combination of separating & throttling
.

27. Pick out the extensive property out of the following.

A.Surface tension
B
Free energy
.
C
Specific heat
.
D
Refractive index
.
28. Entropy change of the reaction, H2O(liquid)

termed as the enthalpy of

A.solution
C
formation
.

H2O(gas), is

B.vaporisation
D.formation

29. Which law of the thermodynamics provids basis for measuring the
thermodynamic property ?
A.First law
B
Zeroth law
.
C
Third law
.
D
Second law
.
30. Gibbs free energy per mole for a pure substance is equal to the
A.latent heat of vaporisation
B
chemical potential
.
C
molal boiling point
.
D
heat capacity
.
31. Gibbs free energy at constant pressure and temperature under
equilibrium conditions is
A.
B.0
C
maximum
D.minimum
.
32. With increase in pressure (above atmospheric pressure), the Cp of a
gas
A
increases
.
B.decreases
C
remains unchanged
.
D
first decreases and then increases
.
33. A change in state involving a decrease in entropy can be spontaneous,
only if
A
it is exothermic.
.
B.it is isenthalpic.
C
it takes place isothermally.
.
D
it takes place at constant volume.
.
34. Joule-Thomson co-efficient which is defined as,

, changes sign at a temperature known

as inversion temperature. The value of Joule-Thomson co-efficient at
inversion temperature is
A
0
B.
.
C
+ve
D.-ve
.
35. __________ calorimeter is normally used for measuring the dryness
fraction of steam, when it is very low.

36. The amount of heat required to decompose a compound into its

elements is __________ the heat of formation of that compound from
its elements.
A.less than
B.more than
C
same as
.
D
not related to
.
37. For a constant volume process
A.dE = CvdT
B
dE = CvdT
.
C
dQ = dE + pdV
.
D
dW = pdV
.
38. In case of the decomposition of hydroiodic acid (2HI

H2 +

I2), addition of H2 (at equilibrium condition) will

A.increase the partial pressure of I2.
B.decrease the partial pressure of HI.
C
diminish the degree of dissociation of HI.
.
D
none of these.
.
39. In any spontaneous process, the __________ free energy decreases.
A.Helmholtz
B.Gibbs
C
both a & b
.
D
neither 'a' nor 'b'
.
40. The gas law (PV = RT) is true for an __________ change.
A.isothermal
B.adiabatic
C
both (a) & (b)
.
D
neither (a) nor (b)
.
41. The equation DU = Tds - PdV is applicable to infinitesimal changes
occuring in
A.an open system of constant composition.
B.a closed system of constant composition.
C
an open system with changes in composition.
.
D
a closed system with changes in composition.
.
42. Heat is added at constant temperature in an ideal __________ cycle.
A
Stirling
.
B.Brayton
C
Rankine
.
D
none of these
.
43. Pick out the correct equation relating 'F' and 'A'.
A
F = A + PV
.
B.F = E + A
C
F = A - TS
.
D
F = A + TS
.
44. In a reversible process

A
Tds = dE + dW
.
B.dE - dW = Tds
C
dW - dE = Tds
.
D
Tds - dW + dE >0
.
45. Cv for an ideal gas
A.does not depend upon temperature.
B.is independent of pressure only.
C
is independent of volume only.
.
D
is independent of both pressure and volume.
.
46. The equation, Cp - Cv = R, is true for __________ gas.
A.no
B.any real
C
only ideal
.
D
both (b) and (c)
.

3.

47. In a homogeneous solution, the activity co-efficient of a component

depends upon the
A.pressure
B.composition
C
temperature
.
D
all (a), (b) and (c)
.
48. Pick out the wrong statement:
A.The expansion of a gas in vacuum is an irreversible process.
B
An isometric process is a constant pressure process.
.
C
Entropy change for a reversible adiabatic process is zero.
.
D
Free energy change for a spontaneous process is negative.
.
49. With increase in compression ratio, the efficiency of the otto engine
A
increases
.
B.decreases
C
remains constant
.
D
increases linearly
.

4.

5.

50. The chemical potential of any constituent of an ideal solution depends

on the __________ of the solution.
A.temperature
B.pressure
C
composition
.
D
all (a), (b) and (c)
.

A.

in standard state

B.

at high pressure

C.

at low temperature

D.

in ideal state

Refrigerants commonly used for domestic refrigerators are

A.

ethyl chloride or methyle chloride

B.

freon-12

C.

propane

D.

NH3 or CO2.

Solid and liquid phases of a substance are in equilibrium at the

A.

critical temperature

B.

melting point.

C.

freezing point.

D.

both (b) and (c).

Absolute zero temperature signifies the

A.

minimum temperature attainable.

B.

temperature of the heat reservoir to which a Carnot engine

rejects all the heat that is taken in.

C.

temperature of the heat reservoir to which a Carnot

engine rejects no heat.

D.

none of these.

SECTION 7
1.

2.

Third law of thermodynamics is helpful in

A.

prediction of the extent of a chemical reaction.

B.

calculating absolute entropies of substances at different

temperature.

C.

evaluating entropy changes of chemical reaction.

D.

both (b) and (c)

Fugacity and pressure are numerically equal, when the gas is

6.

Specific __________ does not change during a phase change (e.g.

sublimation, melting, vaporisation etc.).
A.

entropy

B.

internal energy

C.

enthalpy

D.

Gibbs free energy

7.

Heat of formation of an element in its standard state is

12. For an isothermal process, the internal energy of a gas

A.

A.

increases

B.

<0

B.

decreases

C.

>0

C.

remains unchanged

D.

data insufficient, can't be predicted

D.

a function of pressure
13. In the equation, PVn = constant, if the value of n = 1, then it
represents a reversible __________ process.

8.

The equation relating E, P, V and T which is true for all substanes

under all conditions is given by

equation is called the

A.

isothermal

B.

isobaric

C.

polytropic

D.

adiabatic

.This
14. For the gaseous phase chemical reaction, C2H4(g) + H2O(g)
C2H5OH(g), the equilibrium conversion does not depend on the

A.

Maxwell's equation.

B.

thermodynamic equation of state.

C.

equation of state.

D.

Redlich-Kwong equation of state.

A.

steam to ethylene ratio.

B.

temperature.

C.

pressure.

D.

none of these.

15. The first law of thermodynamics is a statement of conservation of

9.

For an exothremic reaction

A.

only enthalpy change (H) is negative.

B.

only internal energy change (E) is negative.

C.

both H and E are negative.

D.

enthalpy change is zero.

A.

heat

B.

momentum

C.

energy

D.

work

16. "Dry ice" is

A.

moisture free ice

B.

solid helium

C.

solid carbon dioxide

D.

none of these

10. Pick out the wrong statement.

17. Cv is given by

11.

A.

An ideal liquid or solid solution is defined as one in which each

component obeys Raoult's law.
If Raoult's law is applied to one component of a binary
mixture ; Henry's law or Raoult's law is applied to the other
component also.

A.

B.

C.

Henry's law is rigorously correct in the limit of infinite dilution.

B.

D.

none of these.

The shape of T-S diagram for Carnot Cycle is a

A.

rectangle

B.

rhombus

C.

trapezoid

D.

circle

C.

mixture of composition Z, at a temperature T and pressure P, is a

function only of
D.

18. Which of the following non-flow reversible compression processes

require maximum work ?
A.

Adiabatic process

B.

Isothermal process

C.

Isobaric process

D.

All require same work

19. Pick out the correct statement.

A.

A real gas on expansion in vacuum gets heated up.

B.

An ideal gas on expansion in vacuum gets cooled.

C.

An ideal gas on expansion in vacuum gets heated up.

D.

A real gas on expansion in vacuum cools down whereas

ideal gas remains unaffected.

20. "When a system in equilibrium is subjected to a change in temperature,

pressure or concentration, the equilibrium is displaced in a direction
which tends to undo the effect of the change." This is called the

A.

Le-Chatelier principle.

B.

Kopp's rule.

C.

law of corresponding state.

D.

Arrehenius hypothesis.

21. Sound waves propagation in air exemplifies an __________

process.
A.

adiabatic

B.

isothermal

C.

isometric

D.

none of these

A.

B.

T and P

C.

T, P and Z

D.

T and Z

24. With increase in reduced temperature, the fugacity co-efficient of a

gas at constant reduced pressure
A.

increases

B.

decreases

C.

remains same

D.

decreases linearly

25. For an ideal gas, the enthalpy

A.

increases with rise in pressure.

B.

decreases with rise in pressure.

C.

is independent of pressure.

D.

is a path function.

26. Efficiency of a heat engine working on Carnot cycle between two

temperature levels depends upon the
A.

two temperatures only.

B.

pressure of working fluid.

C.

mass of the working fluid.

D.

mass and pressure both of the working fluid.

27. In Joule-Thomson porous plug experiment, the

22. For equilibrium process (i.e. reversible) in an isolated system

A.

ds = 0

B.

ds < 0

C.

ds > 0

D.

ds = Constant

23. The partial molar enthalpy of a component in an ideal binary gas

A.

enthalpy does not remain constant.

B.

entire apparatus is exposed to surroundings.

C.

temperature remains constant.

D.

none of these.

28. The root mean square speed of molecules of a gas is equal to

(where, m = mass of the molecule K = Boltzman's constant, T =
absolute temperature)

A.

D.

distillation

B.
34. Pick out the correct statement.
A.

Entropy and enthalpy are path functions.

B.

In a closed system, the energy can be exchanged with the

surrounding, while. matter can not be exchanged.

C.

All the natural processes are reversible in nature.

D.

Work is a state function.

C.

D.

29. The intensive properties are

35. Air-refrigeration cycle

A.

molar volume, density, viscosity and boiling point.

A.

is the most efficient of all refrigeration cycles.

B.

refractive index and surface tension.

B.

has very low efficiency.

C.

both (a) and (b).

C.

requires relatively large quantities of air to achieve a

significant amount of refrigeration.

D.

none of these.
D.

both (b) and (c).

30. A Carnot cycle consists of the following steps :

A.

Two isothermals and two isentropics.

B.

Two isobarics and two isothermals.

C.

Two isochorics and two isobarics.

D.

Two isothermals and two isochorics.

31. For a cyclic process, a fixed ratio between heat and work
A.

always exists

B.

may exist

C.

never exists

D.

is difficult to predict

32. Which of the following is not a common refrigerant ?

A.

Freon-12

B.

Ethylene

C.

Ammonia

D.

Carbon dioxide

33. The most important application of distribution law is in

A.

evaporation

B.

liquid extraction

C.

drying

36. In vapour compression refrigeration system, if the evaporator

temperature and the condenser temperatures are -13C and 37C
respetively, the Carnot COP will be
A.

5.2

B.

6.2

C.

0.168

D.

data insufficient, can't be found out

37. Gibbs free energy of mixing at constant pressure and temperature is

always
A.

B.

C.

+ ve

D.

- ve

38. The compressibility factor for an ideal gas is 1. Its value for any other
real gas is
A.

B.

<1

C.

>1

D.

either (b) or (c), depends on the nature of the gas

39. If two gases have same reduced temperature and reduced pressure,
then they will have the same

A.

volume

B.

mass

C.

critical temperature

D.

none of these

45. Efficiency of a Carnot engine working between

temperatures T1 and T2 (T1 < T) is

A.

40. Which of the following is an extensive property of a system ?

B.
A.

Heat capacity

B.

Molal heat capacity

C.

Pressure

D.

Concentration

C.

41. The reaction A (l)

R(g) is allowed to reach equilibrium

conditions in an autoclave. At equilibrium, there are two phases, one a

pure liquid phase of A and the other a vapor phase of A, R and S.
Initially A alone is present. The number of degrees of freedom are

D.

46. Melting of wax is accompanied with __________ in entropy.

A.

increase

A.

B.

B.

decrease

C.

D.

C.

no change

D.

none of these

42. Cp - Cv = R is valid for __________ gases.

A.

ideal

B.

all

C.

very high pressure

D.

very low temperature

47. A thermodynamic system is taken from state A to B along ACB and is

brought back toA along BDA as shown below in the P-V diagram.

43. At a given temperature, the volume of a gas dissolved in a solvent

__________ with increase in pressure.
A.

increases

B.

decreases

C.

remains unchanged

D.

may increase or decrease; depends on the gas

44. Which is an example of closed system ?

A.

Air compressor

B.

Lquid cooling system of an automobile

C.

Boiler

D.

None of these

The net work done during the complete cycle is given by the area
covered by
A.

P1ACBP2P1

B.

ACBB1A1A

C.

ACBDA

D.

ADBB1A1A

48. Work done in case of free expansion is

A.

indeterminate

B.

zero

C.

negative

D.

none of these

49. Chemical potential (an intensive property) of a substance is a force

that drives the chemical system to equilibrium and is equal to its
partial molar properties. The reatio of chemical potential to free
energy of a pure substance at oconstant temperature and pressure is
A.

B.

C.

D.

none of these

5.

50. During adiabatic expansion of gas

A.

pressure remains constant.

B.

pressure is increased.

C.

temperature remains constant.

D.

none of these.

6.

A.

Minimum number of degree of freedom of a system

is zero.

B.

Degree of freedom of a system containing a gaseous

mixture of helium, carbon dioxide and hydrogen is 4.

C.

For a two phase system in equilibrium made up of

four non-reacting chemical species, the number of
degrees of freedom is 4.

D.

Enthalpy and internal energy change is zero

during phase change processes like melting,
vaporisation and sublimation.

Tea kept in a thermos flask is vigorously shaken. If the tea is

considered as a system, then its temperature will
A.

increase

B.

decrease

C.

remain unchanged

D.

first fall and then rise.

Change of heat content when one mole of compound is burnt in

oxygen at constant pressure is called the

SECTION 8:
A.

calorific value

B.

heat of reaction

C.

heat of combustion

D.

heat of formation

1.
For the reversible exothermic reaction, N2 + 3H2
increase of pressure would

2.

3.

4.

A.

shift the equilibrium towards right.

B.

give higher yield of NH3.

C.

both (b) and (c).

D.

neither (a) nor (b).

2NH3,

7.

Which of the following has the minimum value of COP for a

given refrigeration effect?
A.

Reverse Carnot cycle.

B.

Ordinary vapour-compression cycle.

C.

Vapour-compression process with a reversible

expansion engine.

D.

Air refrigeration cycle.

8.

Clausius - Clayperon equation is applicable to __________

equilibrium processes.
A.

solid-vapor

B.

solid-liquid

C.

liquid-vapor

D.

all (a), (b) and (c)

In which of the following reaction equilibria, the value of

equilibrium constant Kp will be more than is Kc ?

A.

__________ decreases during adiabatic throttling of a perfect

gas.

B.

A.

Entropy

B.

Temperature

C.

C.

Enthalpy

D.

Pressure

D.

Pick out the wrong statement.

9.

2HI

N2O4

H2 + I 2

2NO2

2SO2 + O2

2SO3

none of these

After throttling, gas temperature

refrigeration cycle.

A.

decreases

B.

increases

C.

remains same

D.

may increase or decrease ; depends on the nature of

the gas

A.

Carnot

B.

air

C.

absorption

D.

vapour-ejection

10. The chemical potential for a pure substance is __________ its

partial molal free energy.
A.

more than

B.

less than

C.

equal to

D.

16. Gibbs-Duhem equation

A.

states that n1d1 + n2d2 + ....njdj = 0, for a

system of definite composition at constant
temperature and pressure.

B.

applies only to binary systems.

C.

finds no application in gas-liquid equilibria involved in

distillation.

D.

none of these

not related to

11. When liquid and vapour phase of multicomponent system are in equilibrium (at a given
temperature and pressure), then chemical
potential of each component is
A.

same in both the phases.

B.

zero in both the phases.

C.

more in vapour phase.

D.

more in liquid phase.

17. Minimum number of phases that exists in a system is 1. Number

of chemical species in a colloidal system is

12. COP of a refrigerator drawing 1 kW of power per ton of

refrigeration is about
A.

0.5

B.

3.5

C.

4.5

D.

8.5

13. The number of degrees of freedom for a mixture of ice and

water (liquid) are
A.

B.

C.

D.

14. On opening the door of an operating refrigerator kept in a

closed room, the temperature of the room will
A.

increase

B.

decrease

C.

remain same

D.

increase in summer and will decrease in winter

A.

B.

C.

D.

18. The internal energy of a gas obeying P (V - b) RT (where, b is a

positive constant and has a constant Cv), depends upon its
A.

pressure

B.

volume

C.

temperature

D.

all (a), (b) & (c).

19. "When a gas is expanded from high pressure region to low

pressure region ; temper -ature change occurs". This
phenomenon is related to the
A.

Gibbs-Duhem equation

B.

Gibbs-Helmholtz equation

C.

Third law of thermodynamics

D.

Joule-Thomson effect

20. The internal energy of an ideal gas does not change in a

15. Domestic refrigerator usually works on the __________

reversible __________ process.

A.

high temperature.

A.

isothermal

B.

adiabatic

B.

low pressure.

C.

isobaric

D.

isometric

C.

low temperature only.

D.

both low temperature and high pressure.

26. Entropy change for an irreversible isolated system is

21. A/an __________ system is exemplified by a vessel containing a

volatile liquid in contact with its vapor.
A.

isolated

B.

closed

C.

open

D.

none of these

A.

B.

C.

<0

D.

>0

27. Maxwell's relation corresponding to the identity, dH = dS = Vdp +

i dni is

A.

22. In a P-V diagram (for an ideal gas), an isothermal curve will coincide
withan adiabatic curve (through a point), when
B.
A.

Cp < Cv

B.

Cp = Cv

C.

Cp > Cv

D.

C Cv

C.

D.
23. For an ideal gas, the chemical potential is given by
A.

RT dlnP

B.

R dlnP

C.

R dlnf

D.

none of these

28. Heat requirement for decomposition of a compound into its elements

is __________ that is evolved during the formation of that compound
from its elements.

24. Two substances are in equilibrium in a reversible chemical reaction. If

the concentration of each substance is doubled, then the value of the
equilibrium constant will be

A.

the same

B.

less than

C.

greater than

D.

different than

A.

same

B.

doubled

C.

halved

A.

molar concentration

D.

one fourth of its original value

B.

temperature

C.

internal energy

D.

none of these

29. The unit of equilibrium constant of a chemical reaction is the same as

that of

25.
In the ammonia synthesis reaction, N2 + 3H2
the formation of NH3 will be favoured by

2NH3 + 22.4 kcal,

30. Which of the following equations is obtained on combining 1st and

2nd law of thermodynamics, for a system of constant mass?
A.

dE = Tds - PdV

B.

dQ = CvdT + PdV

C.

dQ = CpdT + Vdp

D.

Tds = dE - PdV

D.

more or less ; depending on the system.

36. 4 kg moles of an ideal gas expands in vacuum spontaneously. The

work done is

31. The Joule-Thomson co-efficient is defined as (T/P)H. Its value at the

inversion point is
A.

B.

C.

D.

-ve

A.

4J

B.

C.

D.

8J

32. Fugacity of a component in an ideal gas mixture is euqal to the partial

pressure of that component in the mixture. The fugacity of each
component in a stable homogeneous solution at contant pressure and
temperature __________ as its mole fraction increases.
A.

decreases

B.

decreases exponentially

C.

increases

D.

remains constant

37. Compressibility factor (i.e., the ratio of actual volume of gas to the
volume predicted by ideal gas law) for all gases are

33. Entropy is a/an

A.

state function

B.

macroscopic property

C.

extensive property

D.

none of these

A.

low temperature

B.

high pressure

C.

both (a) and (b)

D.

neither (a) nor (b)

2SO3; H = - 42

35. At triple point (for one component system), vapour pressure of solid
as compared to that of liquid will be
A.

more

B.

less

C.

same

always greater than one.

B.

same at the same reduced temperature.

C.

same at the same reduced pressure.

D.

both(b) & (c).

38. Which of the following is not correct for a reversible adiabatic

process ?

34.
In the reaction, represented by, 2SO2 + O2
kcal; the forward reaction will be favoured by

A.

A.

TV-1 = constant

B.

p1-.TY = constant

C.

PV = constant

D.

none of these

39. The efficiency of a Carnot heat engine operating between absolute

temperatures T1and T2 (when, T1 > T2) is given by (T1 - T2)/T1. The coefficient of performance (C.O.P.) of a Carnot heat pump operating
between T1 and T2 is given by
A.

T1/(T1-T2)

B.

T2/(T1-T2)

C.

T1/T2

D.

T2/R1

40. Throttling (Joule-Thomson effect) process is a constant __________

process.

A.

enthalpy

B.

entropy

C.

pressure

D.

none of these

46. The expression for

entropy change given by,
S = - nR ln (P2/P1),
holds good for

A.

expansion of
a real gas.

B.

reversible
isothermal
volume
change.

C.

heating of an
ideal gas.

D.

cooling of a
real gas.

41. Boiling of liquid is accompanied with increase in the

A.

vapor pressure.

B.

specific Gibbs free energy.

C.

specific entropy.

D.

all (a), (b) and (c).

42. Change of state namely evaportation condensation, freezing and

melting is an __________ process.
A.

isothermal

B.

adiabatic

C.

isobaric

D.

isochoric

43. Which of the following is not an equation of state?

A.

Bertholet equation

B.

Clausius Clayperon equation

C.

Beattie-Bridgeman equation

D.

None of these

low pressure and high temperature.

B.

low pressure and low temperature.

C.

low temperature and high pressure.

D.

high temperature and high pressure.

A.

increases

B.

decreases

C.

remains
unchanged

D.

may
increase or
decrease;
depends on
the
substance

48. It is desired to bring about

a certain change in the
state of a system by
performing work on the
system under adiabatic
conditions.

44. A gas shows deviation from ideal behaviour at

A.

47. With increase in

temperature, the internal
energy of a substance

45. The difference between isothermal compressibility and adiabatic

compressibility for an ideal gas is
A.

B.

+ve

C.

-ve

D.

A.

The amount
of work
needed is
path
dependent.

B.

Work alone
can not bring
out such a
change of
state.

C.

The amount
of work
needed is
independent
of path.

D.

More
information is
needed to
conclude
anything
about the
path
dependence

constant temperature and pressure.

or otherwise
of the work
needed.

49. For a constant pressure

reversible process, the
enthalpy change (H) of
the system is
A.

Cv.dT

B.

Cp.dT

5.

C.

D.

SECTION 9
1.

2.

The work done in isothermal compression compared to that in

adiabatic compression will be

6.

B.

Gibbs energy

C.

internal energy

D.

enthalpy

When liquid and vapour phases of one component system are in

equilibrium (at a given temperature and pressure), the molar free
energy is
A.

more in vapour phase.

B.

more in liquid phase.

C.

same in both the phases.

D.

replaced by chemical potential which is more in vapour

phase.

Heat evolved/absorbed during conversion of a substance from one

allotropic form to another is termed as the heat of

less

A.

fusion

B.

more

B.

vaporisation

C.

same

C.

transition

D.

more or less depending upon the extent of work done

D.

none of these

Pick out the Claussius-Clayperon equation from the following:

7.

B.

C.

D.

8.

none of these

What happens in a reversible adiabatic compression ?

A.

Heating occurs

B.

Cooling occurs

C.

Pressure is constant

D.

Temperature is constant

Sublimation temperature of dry ice (solid CO2) is __________ C.

A.

-273

B.

C.

-78

D.

For organic compounds, group contribution method can be used for

the estimation of
9.

4.

entropy

A.

A.

3.

A.

If atmospheric temperature and dew point are nearly equal, then the
relative humidity is

A.

critical properties.

B.

specific gravity.

A.

zero

C.

specific volume.

B.

50%

D.

thermal conductivity.

C.

almost 100%

D.

unpredictable

Specific __________ does not change during phase change at

10. The internal energy of an incompressible fluid depends upon its

of a given substances is given by the __________ equation.

A.

pressure

A.

Gibbs-Duhem

B.

temperature

B.

Maxwell's

C.

both (a) & (b)

C.

Clayperon

D.

neither (a) nor (b)

D.

none of these

11. Entropy change in case of reversible adiabatic process is

17. Pick out the undesirable property for a good refrigerant.
A.

minimum

B.

zero

C.

maximum

D.

indeterminate

12. In reactions involving solids and liquids (where change in volume is

negligible), the heat of reaction at constant pressure as compared to
that at constant volume is
A.

more

B.

less

C.

same

D.

unpredictable; depends on the particular reaction

13. For multicomponent multiple phases to be in equilibrium at the same

pressure and temperature, the __________ of each component must
be same in all phases.
A.

chemical potential

B.

fugacity

C.

both (a) and (b)

D.

neither (a) nor (b)

14. The efficiency of an Otto engine compared to that of a diesel engine,

for the same compression ratio will be
A.

more

B.

less

C.

same

D.

data insufficient to predict

A.

high thermal conductivity

B.

low freezing point

C.

large latent heat of vaporisation

D.

high viscosity

18. Isotherm on an enthalpy-concentration diagram, for an ideal solution

will be a
A.

straight line

B.

sine curve

C.

parabola

D.

hyperbola

19. The fusion of a crystalline solid at its melting point to form a liquid at
the same temperature is accompanied by
A.

decrease in enthalpy corresponding to evolution of heat.

B.

decrease of entropy.

C.

increase in enthalpy corresponding to absorption of

heat.

D.

no change in enthalpy.

20. Melting of ice is an example of an __________ process.

15. Mollier chart is a __________ plot.

A.

adiabatic

B.

isothermal

C.

isometric

D.

none of these

21. A cylinder contains 640 gm of liquid oxygen. The volume occupied (in
litres) by the oxygen, when it is released and brought to standard
conditions (0C, 760 mm Hg) will be __________ litres.

A.

pressure vs enthalpy

B.

pressure vs volume

C.

enthalpy vs entropy

A.

448

D.

temperature vs entropy

B.

224

16. Variation of equilibrium pressure with temperature for any two phases

C.

22.4

D.

D.

data insufficient; can't be computed

(P/V)S = 1/y(P/V)T

28. Gibbs-Helmholtz equation is

22. Rotary lime kiln is an example of a/an __________ system.
A.

closed

B.

open

C.

isolated

D.

non-thermodynamic

A.

23. Heat of reaction is

A.

dependent on pressure only.

B.

dependent on temperature only.

C.

dependent on both pressure and temperature.

D.

independent of temperature changes.

B.

F = H - TT

C.

d(E - TS) T, V < 0

D.

29. Pick out the wrong statement.

A.

The net change in entropy in any reversible cycle is

always zero.

B.

The entropy of the system as a whole in an irreversible

process increases.

C.

The entropy of the universe tends to a maximum.

D.

The entropy of a substance does not remain constant

during a reversible adiabatie change.

24.
The expression,
A.

, is for the____of an ideal gas.

compressibility

B.

work done under adiabatic contition

C.

work done under isothermal condition

D.

co-efficient of thermal expansion

30.

Fugacity co-efficient of a substance is the ratio of its fugacity to

A
.

mole fraction

B
.

activity

C
.

pressure

D
.

activity co-efficient

25. What happens in a reversible adiabatic expansion process ?

A.

Heating takes place.

B.

Cooling takes place.

C.

Pressure is constant.

D.

Temperature is constant.

26. Degree of freedom of a system consisting of a gaseous mixture of

H2 and NH3 will be
A.

B.

C.

D.

27. On a P-V diagram of an ideal gas, suppose a reversible adiabatic line

intersects a reversible isothermal line at point A. Then at a point A, the
slope of the reversible adiabatic line (P/V)s and the slope of the
reversible isothermal line (P/V)T are related as (where, y = Cp/Cv)
A.

(P/V)S = (P/V)T

B.

(P/V)S = [(P/V)T]Y

C.

(P/V)S = y(P/V)T

31. Dryness fraction of wet steam is defined as the ratio of mass of

vapour in the mixture to the mass of mixture __________
calorimeter is not used for measuring the dryness fraction of
steam.

A.

Bomb

B.

Separating

C.

Bucket

D.

Throttling

32.As the time is passing, entropy of the universe

A
.

is increasing

B
.

is decreasing

remains constant

.
D
.

data insufficient, can't be predicted

33.Which of the following processes can not be made reversible

even under ideal condition of operation?
A
.

Free expansion of a gas.

B
.

Compression of air in a compressor.

C
.

Expansion of steam in a turbine.

D
.

all (a), (b) & (c).

A
.

endothermic

B
.

exothermic

C
.

isothermal

D
.

adiabatic

38.With increase in temperature, the atomic heat capacities of all

solid elements

34.The relation connecting the fugacities of various components in a

solution with one another and to composition at constant
temperature and pressure is called the __________ equation.

A
.

increases

B
.

decreases

C
.

remains unchanged

D
.

decreases linearly

39.The temperature at the eutectic point of the system is the

__________ temperature that can be attained in the system.

A
.

Gibbs-Duhem

A
.

lowest

B
.

Van Laar

B
.

highest

C
.

Gibbs-Helmholtz

C
.

average

D
.

Margules

D
.

none of these

35.Which of the following identities can be most easily used to verify

steam table data for superheated steam.
A
.

(T/V)S = (p/S)V

B
.

(T/P)S = (V/S)P

C
.

(P/T)V = (S/V)T

D
.

(V/T)P = -(S/P)T

40.The effect of changing the evaporator temperature on COP as

compared to that of changing the condenser temperature (in
vapour compression refrigeration system) is

36. In the equation PV = constant, if the value of n = y = Cp/Cv,

then it represents a reversible __________ process.
A
.

isothermal

B
.

adiabatic

C
.

isentropic

D
.

polytropic

37. The ammonia synthesis reaction represented by N2 +

3H2

2NH3 ; H = - 22.4 kcal, is

A
.

less pronounced

B
.

more pronounced

C
.

equal

D
.

data insufficient, can't be predicted.

41. Steam undergoes isentropic expansion in a turbine from 5000 kPa and
400C (entropy = 6.65 kJ/kg K) to 150 kPa) (entropy of saturated liquid =
1.4336 kJ/kg . K, entropy of saturated vapour = 7.2234 kJ/kg. K) The exit
condition of steam is
A.

superheated vapour.

B.

partially condensed vapour with quality of 0.9.

C.

saturated vapour.

D.

partially condensed vapour with quality of 0.1

42. An isentropic process is carried out at constant

A.

volume

B.

pressure

C.

temperature

D.

all (a), (b) and (c)

A.

oxygen

B.

nitrogen

C.

air

D.

hydrogen

High pressure steam is expanded adiabati-cally and reversibly

through a well insulated turbine, which produces some shaft
work. If the enthalpy change and entropy change across the
turbine are represented by H and S respectively for this
process:
A.

H = 0 and S = 0.

B.

H 0 and S = 0.

C.

H 0 and S 0.

D.

H = 0 and S 0.

Viscosity

D.

None of these

48. Pick out the wrong statement.

43. All gases except __________ shows a cooling effect during throttling
process at atmospheric temperature and pressure.

44.

C.

A.

At constant pressure, solubility of a gas in a liquid

diminishes with rise in temperature.

B.

Normally, the gases which are easily liquified, are more

soluble in common solvents.

C.

The gases which are capable of forming ions in aqueous

solution, are much more soluble in water than in other
solvents.

D.

At constant pressure, solubility of a gas in a liquid

increases with rise in temperature.

49. Gibbs phase rule finds application, when heat transfer occurs by
A.

conduction

B.

convection

C.

radiation

D.

condensation

50. Absorption/evolution of heat during conversion of a substance from

one allotropic form to another is termed as the heat of

The necessary condition for phase equilibrium in a multiphase system of N

components is that the

A.

sublimation

B.

fusion

C.

transition

D.

vaporisation

A.

chemical potentials of a given component should be

equal in all phases.

B.

chemical potentials of all components should be same in a

particular phase.

A.

low T, low P

C.

sum of the chemical potentials of any given component in all

the phases should be the same.

B.

high T, high P

D.

none of these.

C.

low T, high P

D.

high T, low P

SECTION 10
1.

46. Compressibility factor-reduced pressure plot on reduced co-ordinates

facilitates
A.

use of only one graph for all gases.

B.

covering of wide range.

C.

easier plotting.

D.

more accurate plotting.

47. Which of the following is not an intensive property ?

A.

Molar heat capacity

B.

Internal energy

2.

3.

Ideal gas law is applicable at

Reduced pressure of a gas is the ratio of its

A.

pressure to critical pressure.

B.

critical pressure to pressure.

C.

pressure to pseudocritical pressure.

D.

pseudocritical pressure to pressure.

For a reversible process involving only pressure-volume work

A.

(dF)T, p < 0

B.

(dF)T, p > 0

of

4.

5.

6.

C.

(dF)T, p = 0

A.

50 k cal/hr

D.

(dA)T, v < 0

B.

200 BTU/hr

C.

200 BTU/minute

D.

200 BTU/day

Air enters an adiabatic compressor at 300K. The exit temperature for

a compression ratio of 3, assuming air to be an ideal gas (Y = Cp/Cv =
7/5) and the process to be reversible, is
A.

300(32/7)

B.

300(33/5)

C.

300(333/7)

D.

300(35/7)

Entropy change for an irreversible process taking system and

surrounding together is
A.

B.

>0

C.

<0

D.

none of these

10. What is the degree of freedom for a system comprising liquid water
equilibrium with its vapour ?

11.

A.

B.

C.

D.

Equilibrium constant of a reaction varies with the

A.

initial concentration of the reactant.

B.

pressure.

C.

temperature.

D.

none of these.

In a homogeneous solution, the fugacity of a component depends

upon the
12. Third law of thermodynamics is concerned with the

7.

8.

A.

pressure

B.

composition

C.

temperature

D.

all (a), (b) and (c)

For an incompressible fluid, the __________ is a function of both

pressure as well as temperature.

A.

value of absolute entropy.

B.

energy transfer.

C.

direction of energy transfer.

D.

none of these.

13. Claude's liquefaction process employs the cooling of gases by

A.

internal energy

A.

expansion in an engine

B.

enthalpy

B.

following a constant pressure cycle

C.

entropy

C.

throttling

D.

all (a), (b) & (c)

D.

none of these

An ideal monoatomic gas is taken round the cycle ABCDA as shown

below in the P-Vdiagram

14. Gibbs free energy (F) is defined as

A.

F = E - TS

B.

F = H - TS

C.

F = H + TS

D.

F = E + TS

The work done during the cycle is

9.

A.

PV

B.

2PV

C.

PV/2

D.

One ton of refrigeration capacity is equivalent to the heat removal rate

15. The expression for entropy change given by, S = nR ln (V2/V1)

+ nCv ln (T2/T1) is valid for

A.

reversible isothermal volume change.

B.

heating of a substance.

C.

cooling of a substance.

D.

simultaneous heating and expansion of an ideal gas.

in internal energy.
D.

21. Which of the following is affected by the temperature ?

16. The second law of thermodynamics states that

A.

the energy change of a system undergoing any reversible

process is zero.

B.

it is not possible to transfer heat from a lower temperature

to a higher temperature.

C.

the total energy of system and surrounding remains the

same.

D.

none of the above.

A.

increases with increase in pressure.

B.

decreases with increase in temperature.

C.

is independent of temperature.

D.

none of these.

18. A refrigerator works on the principle of __________ law of

thermodynamics.

C.

zeroth
second

A.

Fugacity

B.

Activity co-efficient

C.

Free energy

D.

All (a), (b) & (c)

22.
Work done may be calculated by the expression
__________ processes.

17. Internal energy of an ideal gas

A.

Claussius-clayperon equation is not applicable to

melting process.

B.
D.

A.

non-flow reversible

B.

adiabatic

C.

both (a) and (b)

D.

neither (a) nor (b)

for

23. The molar excess Gibbs free energy, gE, for a binary liquid mixture
at T and P is given by, (gE/RT) = A . x1. x2, where A is a constant. The
corresponding equation for ln y1, where y1 is the activity co-efficient of
component 1, is
A.

A . x22

B.

Ax1

C.

Ax2

D.

Ax12

first
third

19. Pick out the wrong statement.

A.

The conversion for a gas phase reaction increases with

decrease in pressure, if there is an increase in volume
accompanying the reaction.

B.

With increase in temperature, the equilibrium constant

increases for an exothermic reaction.

C.

The equilibrium constant of a reaction depends upon

temperature only.

D.

The conversion for a gas phase reaction increases with

increase in pressure, if there is a decrease in volume
accompanying the reaction.

24. The adiabatic throttling process of a perfect gas is one of constant

enthalpy
A.

in which there is a temperature drop.

B.

which is exemplified by a non-steady flow expansion.

C.

which can be performed in a pipe with a constriction.

D.

in which there is an increase in temperature.

25. For spontaneous changes in an isolated system (S = entropy)

20. Pick out the wrong statement.

A.

Enthalpies of all elements in their standard states are

assumed to be zero.

B.

Combustion reactions are never en-dothermic in nature.

C.

Heat of reaction at constant volume is equal to the change

A.

ds = 0

B.

solubility

B.

ds <0

C.

temperature

C.

ds > 0

D.

none of these

D.

ds = Constant
32. Fugacity and pressure are numerically not equal for the gases

26 A gas performs the maximum work, when

. it expands
A
.

nonuniformly

B
.

adiabatica
lly

C
.

isobarical
ly

D
.

isothermal
ly

27. There is a change in __________ during the phase transition.

A.

volume

B.

pressure

C.

temperature

D.

all a, b & c

28. Which of the following is Virial equation of state?

A.

(p + a/V2)(V - b) = nRT

B.

PV = nRT

C.

PV = A + B/V + C/V2 + D/V3 + ...

at low temperature and high pressure.

B.

at standard state.

C.

both (a) and (b).

D.

in ideal state.

33. A solute distributes itself between two non-miscible solvents in contact

with each other in such a way that, at a constant temperature, the
ratio of its concentrations in two layers is constant, irrespective of its
total amount". This is
A.

the distribution law.

B.

followed from Margule's equation.

C.

a corollary of Henry's law.

D.

none of these.

34. A solid is transformed into vapour without going to the liquid phase at

D.

29. Pressure-enthalpy chart is useful in refrigeration. The change in

internal energy of an ideal fluid used in ideal refrigeration cycle is
A.

positive

B.

negative

C.

zero

D.

infinity

30. First law of thermodynamics deals with the

A.

direction of energy transfer.

B.

reversible processes only.

C.

irreversible processes only.

D.

none of these.

31. Henry's law is closely obeyed by a gas, when its __________ is

extremely high.
A.

A.

A.

triple point

B.

boiling point

C.

below triple point

D.

always

35. A gas mixture of three components is brought in contact with a

dispersion of an organic phase in water. The degree of freedom of the
system are
A.

B.

C.

D.

36. 1m3 of an ideal gas at 500 K and 1000 kPa expands reversibly to 5
times its initial volume in an insulated container. If the specific heat
capacity (at constant pressure) of the gas is 21 J/mole . K, the final
temperature will be
A.

35 K

B.

174 K

C.

274 K

D.

154 K

pressure
37. For a thermodynamic system containing 'x' chemical species, the

maximum number of phases that can co-exist at equilibrium is

A.

B.

x+1

C.

x+2

D.

x+3

43. 'The fugacity of a gas in a mixture is equal to the product of its mole
fraction and its fugacity in the pure state at the total pressure of the
mixture". This is

38. A reasonably general expression for vapour-liquid phase equilibrium

at low to moderate pressure is i yi P = Yi xi fi where, is a vapor
fugacity component, Yi is the liquid activity co-efficient and fi is the
fugacity of the pure component i. the Kivalue (Yi = Ki xi) is therefore, in
general a function of
A.

temperature only.

B.

temperature and pressure only.

C.

temperature, pressure and liquid composition xi only.

D.

temperature, pressure, liquid composition xi and vapour

composition yi.

39. Standard temperature and pressure (S.T.P.) is

A.

0C and 760 mm Hg

B.

15C and 760 mm Hg

C.

0C and 1 kgf/cm2

D.

15C and 1 kgf/cm2

A.

the statement as per Gibbs-Helmholtz

B.

called Lewis-Randall rule

C.

Henry's law

D.

none of these

44. __________ does not change during phase transformation processes

like sublimation, melting & vaporisation.
A.

Entropy

B.

Gibbs free energy

C.

Internal energy

D.

all (a), (b) & (c)

40. Normal temperature and pressure (N.T.P.) corresponds to

45. Which one is true for a throttling process ?
A.

0C and 760 mm Hg.

B.

15C and 760 mm Hg.

C.

25C and 760 mm Hg.

D.

0C and 1 kgf/cm2.

41. The minimum number of phases that can exist in a system is

A.

B.

C.

D.

42. Enthalpy changes over a constant pressure path are always zero for
__________ gas.
A.

any

B.

a perfect

C.

an easily liquefiable

D.

a real

A.

A gas may have more than one inversion

temperatures.

B.

The inversion temperature is different

for different gases.

C.

The inversion temperature is same for all

gases.

D.

The inversion temperature is the

temperature at which Joule-Thomson coefficient is infinity.

46. Choose the condition that must be specified in

order to liquify CO2 (triple point for CO2 is - 57C
and 5.2 atm).

A.

Pressure must be kept below

5.2 atm.

B.

Temperature must be kept

above - 57C.

C.

Pressure must be kept below

5.2 atm. and temperature must
be kept above 57C.

Pressure and temperature

must be kept below 5.2 atm.
and - 57C respectively.

D.

C.

2.
47. If two pure liquid constituents are mixed in any proportion to give
an ideal solution, there is no change in
A.

volume

B.

enthalpy

C.

both (a) & (b)

D.

neither (a) nor (b)

3.

Chemical potential of ith component of a system is given by

A.

B.

4.

isentropic

D.

isobaric

Throttling process is a/an __________ process.

A.

reversible and isothermal

B.

irreversible and constant enthalpy

C.

reversible and constant entropy

D.

reversible and constant enthalpy

The main feature of Carnot refrigeration cycle is that, it

A.

does not need the addition of external work for its

functioning.

B.

transfers heat from high temperature to low temperature.

C.

accomplishes the reverse effect of the heat engine.

D.

none of these.

Heat of reaction at constant volume is identified with __________

change.
A.

enthalpy

B.

internal energy

C.

either (a) or (b)

D.

neither (a) nor (b)

C.

D.

49. One mole of nitrogen at 8 bar and 600 K is contained in a pistoncylinder arrangement. It is brought to 1 bar isothermally against a
resisting pressure of 1 bar. The work done (in Joules) by the gas
is

5.

Charles' law for gases states that

A.
= Constant

A.

30554

B.

10373

C.

4988.4

D.

4364.9

B.

50. Lenz's law results from the law of conservation of

A.

mass

B.

momentum

C.

energy

D.

none of these

C.

D.
= Constant
6.

If heat contents of CH4, C2H4 and C3H8 are -17.9, 12.5 and -24.8
kcal/mole respectively, than H for the reaction CH4(g) +
C2H4(g)

C3H8(g) will be __________ Kcal.

SECTION 11
In the equation, PVn = constant, if the value of n is in between 1 and y
(i.e. Cp/Cv), then it represents a reversible __________ process.
A.

isometric

B.

A.

-19.4

B.

-30.2

C.

55.2

D.

-55.2

polytropic
7.

Helmholtz free energy (A) is defined as

8.

9.

A.

A = H - TS

B.

A = E - TS

C.

A = H + TS

D.

none of these

Van Laar equation

B.

Margules equation

C.

Wilson's equation

D.

all (a), (b) and (c)

14.

As pressure approaches zero, the ratio of fugacity to pressure (f/P) for

a gas approaches

The equation,
, applicable to a binary
solution of components. A and B in equilibrium with their vapors at
constant temperature and pressure is called the __________
equation.

A.

zero

B.

unity

A.

Van Laar

C.

infinity

B.

Margules

D.

an indeterminate value

C.

Gibbs-Duhem

D.

Gibbs-Duhem-Margules

For any system, what is the minimum number of degrees of freedom?

A.

B.

C.

D.

10. At 60 C, vapour pressure of methanol and water are 84.562 kPa and
19.953 kPa respectively. An aqueous solution of methanol at 60 C
exerts a pressure of 39.223 kPa; the liquid phase and vapour phase
mole fractions of methanol are 0.1686 and 0.5714 respectively.
Activity co-efficient of methanol is

11.

A.

A.

1.572

B.

1.9398

C.

3.389

D.

4.238

The variation of heat of reaction with temperature at constant

pressure is given by the __________ law.

15. Entropy of a substance remains constant during a/an __________

change.
A.

reversible isothermal

B.

irreversible isothermal

C.

reversible adiabatic

D.

none of these

16. Gases are cooled in Joule-Thomson expansion, when it is

__________ inversion temperature.
A.

below

B.

at

A.

Kelvin's

C.

above

B.

Antonie's

D.

either 'b' or 'c'

C.

Kirchoffs

D.

none of these

12. At absolute zero temperature, the __________ of the gas is zero.

17. PVy = constant, holds good for an isentropic process, which is

A.

reversible and isothermal.

B.

isothermal and irreversible.

A.

pressure

C.

reversible and adiabatic.

B.

volume

D.

adiabatic and irreversible.

C.

mass

D.

none of these

13. Which of the following equations is used for the prediction of activity
co-efficient from experiments ?

18. Which of the following represents the Virial equation of state ?

A.

A.

<0

B.

>0

C.

=0

D.

none of these

B.

C.

D.

n1u2 + 21 = 0

24. A system is said to be at equilibrium, if the entropy of the system has

reached __________ value.

19. The equilibrium constant for a chemical reaction at two different

temperatures is given by

A.

A.

minimum

B.

zero

C.

maximum

D.

none of these

B.
25. In the equation, PVn = constant, if the value of n = , then it
represents a reversible __________ process.

C.

A.

adiabatic

B.

isometric

C.

isentropic

D.

isothermal

26. Degree of freedom of the system ice-water-vapour will be

D.

20. Which of the following behaves most closely like an ideal gas ?
A.

He

B.

N2

C.

O2

D.

H2

21. In the reaction, C + O2

content (enthalpy)of O2?
A.

-94 kcal

B.

> -94 kcal

C.

< - 94 kcal

D.

zero

CO2 ; H = - 94 kcal. What is the heat

22. For a constant volume process __________ by the system is used

only to increase the internal energy.

A.

B.

C.

D.

27. A system in which there is exchange of energy but not of mass, is

called a/an __________ system.
A.

isolated

B.

open

C.

insulated

D.

closed

28. The point at which all the three (solid, liquid and gas) phases co-exist,
is known as the __________ point.
A.

freezing

B.

triple

C.

boiling

D.

Boyle

29. In an ideal gas mixture, fugacity of a species is equal to its

A.

heat absorbed

A.

vapor pressure

B.

work done

B.

partial pressure

C.

both (a) & (b)

C.

chemical potential

D.

neither (a) nor (b)

D.

none of these

23. When a system is in equilibrium for all possible processes, the

differential or finite change of entropy is

30. Joule-Thomson co-efficient is defined as

35.

A.

In the decomposition of PCl5 represented by, PCl5

PCl3 + Cl2,
decrease in the pressure of the system will __________ the degree of
dissociation of PCl5.

B.

C.

D.

A
.

increase

B
.

decrease

C
.

not alter

D
.

none of these

36.To obtain integrated form of Clausius-Clayperon

31. The third law of thermodynamics states that the

A.

heat capacity of a crystalline solid is zero at absolute

zero temperature.

B.

heat transfer from low temperature to high temperature

source is not possible without external work.

C.

gases having same reduced properties behave similarly.

D.

none of these.

equation,
, from the
exact Clayperon equafion, it is assumed that the

A.

volume of the liquid phase is negligible

compared to that of vapour phase.

B.

vapour phase behaves as an ideal gas.

C.

heat of vaporisation is independent of

temperature.

D.

all (a), (b) & (c).

32.
Consider the reaction, C + O2
CO2 ;H = - 94 kcal. What will
be the value of H for the reaction CO2
C + O2 ?
A.

-94 kcal

B.

+ 94 kcal

C.

> 94 kcal

D.

< -94 kcal

37. In case of an __________ process, the temperature of the

system increases.
A.

isothermal compression

B.

isothermal expansion

C.

adiabatic expansion

D.

adiabatic compression

33. Which is a state function ?

38. The standard state of a gas (at a given temperature) is the state
in which fugacity is equal to

A.

Specific volume

B.

Work

A.

unity

C.

Pressure

B.

activity

D.

Temperature

C.

both (a) & (b)

D.

neither (a) nor (b)

34. For an ideal liquid solution, which of the following is unity ?

39. Cp of a gas at its critical temperature and pressure

A.

Activity

B.

Fugacity

A.

becomes zero.

C.

Activity co-efficient

B.

becomes infinity.

D.

Fugacity co-efficient

C.

equals 1 kcal/kmol K.

D.

equals 0.24 kcal/kmol K.

40. Trouton's ratio is given by (where b, = molal heat of vaporisation

of a substance at its normal boiling point, kcal/kmol Tb = normal
boiling point, K )
A.

b/Tb

B.

Tb/b

C.

b/Tb

D.

Tb/b

A.

cold reservoir approaches zero.

B.

hot reservoir approaches infinity.

C.

either (a) or (b).

D.

neither (a) nor (b).

45. For an ideal gas, the internal energy depends upon its __________
only.

41. Which of the following is true for Virial equation of state ?

A.

Virial co-efficients are universal constants.

B.

Virial co-efficients 'B' represents three body interactions.

C.

Virial co-efficients are function of temperature only.

D.

For some gases, Virial equations and ideal gas equations

are the same.

42. Molar heat capacity of water in equilibrium with ice at constant

pressure is __________ Kcal/kg mole . K
A.

B.

C.

50

D.

100

43. A gas can be liquified by pressure alone only, when its temperature is
__________ its critical temperature.

A.

molecular size

B.

temperature

C.

volume

D.

pressure

46. Compound having large heat of formation is

A.

more stable.

B.

less stable.

C.

not at all stable (like nascent O2).

D.

either more or less stable ; depends on the compound.

47. Second law of thermodynamics is concerned with the

A.

less than

A.

amount of energy transferred.

B.

more than

B.

direction of energy transfer.

C.

equal to or higher than

C.

irreversible processes only.

D.

less than or equal to

D.

non-cyclic processes only.

44. Thermal efficiency of a Carnot engine can approach 100%, only when
the temperature of the