Outside Delhi - Set 2-15-03-14

Marking Scheme

Chemistry - 2014
Outside Delhi- SET (56 /2)
1
2
3
4
5
6.

In adsorption there is development of inter particle attractions between adsorbate & adsorbent.
Monds Process
NO2 contains odd number of electron and dimerises to become stable
Elastomer
2 molecules of Glucose

7.
1
1
1
1
1
1
8.
2Chlorobutane
Diazotization
or
or first molecule of the pair.
9.
(i) Ethylene glycol (Ethane1,2diol) and terephthalic acid (Benzene1,4dicarboxylic acid)
10
(ii) Hexamethylenediamine & adipic acid

(i) It acts as Flux to remove iron oxide as silicate (slag)
1
1
FeO + SiO2
FeSiO3 (Slag).
(ii) NaCN acts as the depressant. It selectively prevents ZnS from coming to the froth but allows
11
PbS to come with the froth.

(i) 2Ag + PCl5 2AgCl + PCl3
(ii) CaF2 + H2SO4
1
1
1
CaSO4 + 2HF (or H2F2)
12
1+1
13
(i) Antiferromagnetism
14
(ii) Frenkel defect

1
(i) Galvanic cells that are designed to convert the energy of combustion of fuels (methane, 1
methanol, etc.) directly into electrical energy are called fuel cells.
(ii) Molar conductivity of electrolyte at infinite dilution or when concentration approaches zero.
15
HBr H+ + Br
1
OR
( where R = -CH3)
16
(i) Zero order reaction
17
(ii) slope= -k
Given; d = 2.8g/cm3 ;
d=
1
1
Z=4
a = 4 x 10 cm
ZxM
a3 x N A
or
NA = 6.022 x 10
M=
23
per mol
d x a3 x N A
Z
M=
2.8 g /cm3 x ( 4 x 108 cm ) x 6.022 x 1023 per mol

4
18
M = 2.8 x 16 x 10 x 6.022 = 26.97 g/mol.

Reimer-Tiemann reaction
1
Williamson synthesis
1
19
(i) A linkage between two monosaccharide units through oxygen atom is called glycosidic 1
linkage.
(ii) Hydrolysis of sucrose brings about a change in the sign of rotation, from dextro (+) to laevo 1
() and the product is named as invert sugar.
(iii) Carbohydrates that yield two to ten monosaccharide units on hydrolysis, are called
20
oligosaccharides.
(i) (a) Dedicated towards work/ kind/ compassionate (any two).
1
1
(b) Dutiful / caring / humane in the large interest of public health in rural area.
(any other suitable value)
21
(ii) Narcotic analgesics
(iii) Aspartame / Saccharin / Alitame / Sucrolose.(any one)

(i) As primary amines form inter molecular H bond, but tertiary amines dont form H bonds.
1
1
(ii) Aniline forms salt with Lewis acid AlCl3.
(iii) This is because of the combined effect of hydration and inductive effect (+I effect).
Or
21
(i) C6H5NO2 Sn+HCl
H 2O H
(ii) CH3CN
; 273 K
C6H5NH2 Na NO 2+ HCl
C6H5N2+Cl
CH3CONH2 Br 2 +KOH
CH3NH2
CH3COOH
A
22
NH 3
H2O
C6H5OH
+
+
+
+
(a)
1
(b) (i) CH3I

23
(ii) CH3Cl
(a) Given EoCell = +2.71V &
F = 96500C mol-1 n = 2 (from the given reaction)
rGO = n x F x EoCell
rGO = 2 x 96500 C mol-1 x 2.71V
= -523030 J / mol or -523.030 kJ / mol
(b) Hydrogen oxygen fuel Cell / fuel cell

24
SO2 Cl2
At t = 0s
0.4 atm
At t = 100s
(0.4 x) atm
SO2
0 atm
x atm
Pt = 0.4 x + x + x
Pt = 0.4 + x
Cl2
0 atm
x atm
0.7 = 0.4 + x
x = 0.3
k=
2.303
t
k=
2.303
t
k=
2.303
100s
pi
2 pi pt
log
0.4
0.8-0.7
log
0.4
0.1
log
2.303
x 0.6021 = 1.39 x 10-2 s-1
100 s
These are liquid-liquid colloidal systems or the dispersion of one liquid in another liquid.
Types: (i) Oil dispersed in water (O/W type) Example; milk and vanishing cream
(ii) Water dispersed in oil (W/O type) Example; butter and cream.
k=
25
26
(Any one example of each type)

(i) As N cant form 5 covalent bonds / its maximum covalency is four.
(ii) This is due to very small size of Oxygen atom / repulsion between electrons is large in 1
relatively small 2p sub-shell.
27
(iii) In H3PO2 there are 2 PH bonds, whereas in H3PO3 there is 1 PH bond

(i) Tetraamminedichloridochromium (III) chloride.
1
1
(ii) Optical isomerism
(iii) In [NiCl4]2 ; Cl acts as weak ligand therefore does not cause forced pairing, thus electrons
will remain unpaired hence paramagnetic.
In [Ni(CO)4] ; CO acts as strong ligand therefore causes forced pairing, thus electrons will
become paired hence diamagnetic.
28
(a) (i)
1
(ii) CH3CH=NOH
(iii)
1
(b) (i) Add neutral FeCl3 in both the solutions, phenol forms violet colour but benzoic acid does
not.
(ii) Tollens reagent test: Add ammoniacal solution of silver nitrate (Tollens reagent) in both
the solutions propanal gives silver mirror whereas propanone does not.
(or any other correct test)
28
1
1
OR
(a) (i) As Cl acts as electron withdrawing group ( I effect) ,CH3 shows +I effect.
(ii) The carbonyl carbon atom in carboxylic acid is resonance stabilised.
(b) (i) Rosenmund reduction:
Or
RCOCl
H 2 PdBa SO 4 RCHO +HCl.
(ii) Cannizzaros Reaction:

1
Or With bezaldehyde
(c) CH3CH2CH2COCH3.
29
(a)
(i) Molarity is defined as number of moles of solute dissolved in one litre of solution.
5
(ii) It is equal to elevation in boiling point of 1 molal solution.
(b)
For isotonic solutions:
urea = glucose
W urea
M urea x V s
W urea
M urea
W Glucose
M Glucose
W Glucose
M Glucose x V s
(As volume of solution is same)
15 g
60 g mol1
or
W Glucose
180 g mol
1
1
1
W Glucose =
29
15 g x 180 g mol
60 g mol1
OR
= 45g
(a) It shows positive deviation.
It is due to weaker interaction between acetone and ethanol than ethanol-ethanol interactions.
(b) Given: WB = 10g WS = 100g, WA = 90g MB = 180g/mol
& d = 1.2g/mL
Wt x density x 10
Mol . wt .
10 x 1.2 x 10
180
= 0.66 M
or
0.66 mol/L
W B x 1000
m
M B x W A ( g)
10 x 1000
180 x 90
= 0.61m or 0.61mol/kg
(or any other suitable method)
30
(a) (i) Cr2O72 + 2 OH
(ii) MnO4 + 4H+ + 3e
2CrO42 + H2O
MnO2 + 2H2O
2+
(b) (i) Zn / Zn has fully filled d orbitals.
(ii) This is due to smaller ionic sizes / higher ionic charge and availability of d orbitals.
(iii) because Mn
+2
3+
+3
1
3
is more stable(3d ) than Mn (3d ). Cr is more stable due to t 2g / d
configuration.
OR
30
(i)
Lanthanoids
Actinoids
Atomic / ionic radii does not show much Atomic / ionic radii show much variation /
variation / +3 is the most common oxidation Besides
state, in few cases +2 & +4
They are quite reactive
(Any two Points)
+3 oxidation state they exibit
+4,+5,+6,+7 also.
Highly reactive in finely divided state
(ii) Cerium (Ce4+)

(iii) MnO4 + 8H+ + 5e
Mn2+ + 4H2O
(iv) Mn3+ is more paramgnetic

because Mn3+ has 4 unpaired electrons (3d4) therefore more paramagnetic whereas Cr 3+ has 3
unpaired electrons (3d3).
Sr. No.
Name
Name
Dr. (Mrs.) Sangeeta Bhatia
Sr.
No
.
9
1
2
Dr. K.N. Uppadhya
10
Mr. K.M. Abdul Raheem
Prof. R.D. Shukla
11
Mr. Akileswar Mishra
Sh. S.K. Munjal
12
Mrs. Maya George
Sh. Rakesh Dhawan
13
Sh. Virendra Singh Phogat
Sh. D.A. Mishra
14
Sh. Deshbir Singh
15
Dr. (Mrs.) Sunita

Ramrakhiani
Ms. Garima Bhutani
Ms. Neeru Sofat
Sh. Partha Sarathi Sarkar

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Marking Scheme

or first molecule of the pair.

(i) Ethylene glycol (Ethane1,2diol) and terephthalic acid (Benzene1,4dicarboxylic acid)

(ii) Hexamethylenediamine & adipic acid

PbS to come with the froth.

CaSO4 + 2HF (or H2F2)

(ii) Frenkel defect

(i) Zero order reaction

2.8 g /cm3 x ( 4 x 108 cm ) x 6.022 x 1023 per mol

M = 2.8 x 16 x 10 x 6.022 = 26.97 g/mol.

(any other suitable value)

(ii) Narcotic analgesics

(iii) Aspartame / Saccharin / Alitame / Sucrolose.(any one)

(ii) Aniline forms salt with Lewis acid AlCl3.

(b) (i) CH3I

F = 96500C mol-1 n = 2 (from the given reaction)

rGO = 2 x 96500 C mol-1 x 2.71V

= -523030 J / mol or -523.030 kJ / mol

(b) Hydrogen oxygen fuel Cell / fuel cell

(Any one example of each type)

(iii) In H3PO2 there are 2 PH bonds, whereas in H3PO3 there is 1 PH bond

(ii) Optical isomerism

(ii) The carbonyl carbon atom in carboxylic acid is resonance stabilised.

(b) (i) Rosenmund reduction:

H 2 PdBa SO 4 RCHO +HCl.

(ii) Cannizzaros Reaction:

(ii) It is equal to elevation in boiling point of 1 molal solution.

For isotonic solutions:

(As volume of solution is same)

(a) It shows positive deviation.

(b) Given: WB = 10g WS = 100g, WA = 90g MB = 180g/mol

(or any other suitable method)

(a) (i) Cr2O72 + 2 OH

(ii) MnO4 + 4H+ + 3e

(b) (i) Zn / Zn has fully filled d orbitals.

is more stable(3d ) than Mn (3d ). Cr is more stable due to t 2g / d

+3 oxidation state they exibit

(ii) Cerium (Ce4+)

(iv) Mn3+ is more paramgnetic

Dr. (Mrs.) Sangeeta Bhatia

Dr. K.N. Uppadhya

Mr. K.M. Abdul Raheem

Prof. R.D. Shukla

Mr. Akileswar Mishra

Sh. S.K. Munjal

Mrs. Maya George

Sh. Rakesh Dhawan

Sh. Virendra Singh Phogat

Sh. D.A. Mishra

Sh. Deshbir Singh

Dr. (Mrs.) Sunita

Ms. Neeru Sofat

Sh. Partha Sarathi Sarkar

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