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. 1998 Aug;190(2):341-52.
doi: 10.1006/jmsp.1998.7582.

Fourier Transform Emission Spectroscopy of the A2Delta-X2Pi Transition of SiH and SiD

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Fourier Transform Emission Spectroscopy of the A2Delta-X2Pi Transition of SiH and SiD

RS Ram et al. J Mol Spectrosc. 1998 Aug.

Abstract

The emission spectra of the A2Delta-X2Pi transition of SiH and SiD have been observed at high resolution using a Fourier transform spectrometer. The molecules were excited in a Si hollow cathode lamp by passing a discharge through a mixture of Ne and a trace of H2 or D2. The present data, combined with the previous infrared vibration-rotation measurements, have been used to determine improved molecular constants for the ground and excited states of SiH and SiD. Copyright 1998 Academic Press.

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